Objective
Considerable progress has been made over the past thirty years in the synthesis and preparation of 0D, 1D, and 2D sp2-hybridized carbon materials, as well as for their smaller discrete nanosized polycyclic aromatic hydrocarbon (PAH) counterparts. However, 3D sp2-hybridized carbon networks, called schwarzite carbons or Mackay-Terrones crystals – first proposed in the early 1990s – remain elusive, despite exciting electronic properties and important applications being predicted for these porous crystalline all-carbon solids by theoreticians. Little activity has been devoted to this new class of carbon materials due to the enormous challenges foreseen for their synthesis. Even research towards 7- and 8-membered rings, whose saddle-shaped structures are the prerequisite for schwarzite-type molecular carbon materials, has only recently become a research focus for a still small number of chemists.
Based on an efficient synthetic method for heptagon-containing PAHs recently developed by our laboratory and the subsequent demonstration of the perfect schwarzite-like organization of four of such molecules around a C60-fullerene template, we herein propose rational strategies for both schwarzite-inspired saddle-shaped nanostructures as well as 3D schwarzite-like porous pi-conjugated solid-state materials. Thus, in this project, novel saddle-shaped PAHs bearing schwarzite-inspired sequences of hexagons and heptagons will be synthesized and self-assembled around fullerenes and other spherical template molecules, and characterized by supramolecular binding studies and single-crystal X-ray diffraction. Various synthetic approaches will be pursued for the post-functionalization of these complexes to afford pi-conjugated cage molecules and schwarzite-type pi-conjugated 3D materials. The functional properties of these novel materials will be explored with a broad repertoire of available techniques in our laboratory.
Fields of science (EuroSciVoc)
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
- natural sciences chemical sciences organic chemistry hydrocarbons
- engineering and technology nanotechnology nano-materials two-dimensional nanostructures
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Keywords
Project’s keywords as indicated by the project coordinator. Not to be confused with the EuroSciVoc taxonomy (Fields of science)
Project’s keywords as indicated by the project coordinator. Not to be confused with the EuroSciVoc taxonomy (Fields of science)
Programme(s)
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
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HORIZON.1.1 - European Research Council (ERC)
MAIN PROGRAMME
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Topic(s)
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Funding Scheme
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
HORIZON-ERC - HORIZON ERC Grants
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Call for proposal
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
(opens in new window) ERC-2024-ADG
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Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.
97070 Wuerzburg
Germany
The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.