Objectif Molecular imprinting, an important methodology for the straightforward prepared of antibody-like polymers, is recently one of focuses in chemistry because of its importance in catalysis, separation and sensing. Described usually as a ‘from-key-to-lock’ process, the molecular imprinting recognizes and interacts with substrates basing on a specifically complementary framework. The present proposal aims to design ‘smart’ imprinted polymers capable of showing tunable catalysis. Inspired by recent advances in the ‘Smart’ technology, a unique hydrophilic/hydrophobic transition is created within the binding framework. The design of this transition will cause an opening/closing-tunable mechanism within the binding framework, thereby allowing/refusing the substrates in water accessible to the interior. In the opening state, the substrate in water can be freely accessible to the binding framework, thus making possible efficient interaction. Above the transition the blockage of access to the inner largely restricts the diffusion of substrates. In this way, such recognition and catalysis are comparable to an on/off-switchable process, which thus allows one to manipulate the activity by controlling the phase behaviours of prepared materials. Champ scientifique natural scienceschemical sciencespolymer sciencesnatural scienceschemical sciencescatalysis Programme(s) FP7-PEOPLE - Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013) Thème(s) FP7-PEOPLE-IIF-2008 - Marie Curie Action: "International Incoming Fellowships" Appel à propositions FP7-PEOPLE-IIF-2008 Voir d’autres projets de cet appel Régime de financement MC-IIF - International Incoming Fellowships (IIF) Coordinateur CRANFIELD UNIVERSITY Contribution de l’UE € 181 350,76 Adresse College Road MK43 0AL Cranfield - Bedfordshire Royaume-Uni Voir sur la carte Région East of England Bedfordshire and Hertfordshire Central Bedfordshire Type d’activité Higher or Secondary Education Establishments Contact administratif Anthony Turner (Prof.) Liens Contacter l’organisation Opens in new window Site web Opens in new window Coût total Aucune donnée
