Objectif
Recent breakthroughs in the field of s-block metal amide chemistry have unveiled a novel new class of compounds for which the term "inverse crowns" has been coined. These compounds are the product oaf remarkable synergy, which is switched on by the co-operative action of mixing two different s-block metal atoms within the same molecular environment. Removing one of the metal atoms switches off the synergy. As featured on a recent front cover of Angewandte Chemise, this synergy can bring about unprecedented regioselective deprotonative mutilations, such as the transformation of kerosene to previously unknown 1, G, 3, 3'-tetra form. This project will develop and extend this synergistic chemistry on three main fronts, as follows: first, it will introduce different metal-metal pairings to the host rings, placing special emphasis on redo-active metals; second, it will investigate the electrophilicreactivity of existing inverse crowns in attempts to prepare new functionalised fierceness and related compounds, and third, the synthesis of new inverse crowns incorporating other important metalloceneand p-arena complexes will be undertaken. The results emanating from the project should be of considerable interest to a diverse range of chemists including main group, transition metal, and organic synthetic and supramolecular ones. The research project will provide an excellent training vehicle forth Spanish applicant, giving her a rare opportunity for pushing forward the frontiers of an exciting, emerging new topic unique to the research group based in Scotland.'
Champ scientifique (EuroSciVoc)
CORDIS classe les projets avec EuroSciVoc, une taxonomie multilingue des domaines scientifiques, grâce à un processus semi-automatique basé sur des techniques TLN.
CORDIS classe les projets avec EuroSciVoc, une taxonomie multilingue des domaines scientifiques, grâce à un processus semi-automatique basé sur des techniques TLN.
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Mots‑clés
Appel à propositions
FP6-2002-MOBILITY-5
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Régime de financement
EIF - Marie Curie actions-Intra-European FellowshipsCoordinateur
GLASGOW
Royaume-Uni