Entangled pincer ligand architectures and their application in the transition-metal-mediated activation of alkanes

Project Information

ENTANGLED-TM-ALKANE

Grant agreement ID: 637313

DOI 10.3030/637313

Project closed

EC signature date 17 February 2015

Start date 1 April 2015

End date 30 September 2020

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 521 137,33

EU contribution € 1 521 137,33

Coordinated by

UNIVERSITY OF WARWICK
United Kingdom

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (21)

Terminal Alkyne Coupling Reactions Through a Ring: Effect of Ring Size on Rate and Regioselectivity

Author(s): Caroline M. Storey, Matthew R. Gyton, Rhiann E. Andrew, Adrian B. Chaplin
Published in: Chemistry—A European Journal, Issue 26/64, 2020, Page(s) 14715-14723, ISSN 1521-3765
Publisher: Wiley-VCH
DOI: 10.1002/chem.202002962

Reactions of Rh(PNP) pincer complexes with terminal alkynes: homocoupling through a ring or not at all

Author(s): Thomas M. Hood, Adrian B. Chaplin
Published in: Dalton Transactions, 2020, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0dt03550e

Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand.

Author(s): J. Emerson-King, S. Pan, M. R. Gyton, R. Tonner-Zech and A. B. Chaplin
Published in: Chemical Communications, 2023, Page(s) 2150 – 2152, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2cc06837k

Synthesis and rhodium complexes of macrocyclic PNP and PONOP pincer ligands

Author(s): Thomas M. Hood, Matthew R. Gyton, Adrian B. Chaplin
Published in: Dalton Transactions, Issue 49/7, 2020, Page(s) 2077-2086, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/C9DT04474D

Modulation of Metal Carbonyl Stretching Frequencies in the Second Coordination Sphere through the Internal Stark Effect

Author(s): Gemma L. Parker; Ruben Van Lommel; Nil Roig; Mercedes Alonso; Adrian B. Chaplin
Published in: Chemistry—A European Journal, 2022, Page(s) e202202283, ISSN 1521-3765
Publisher: Wiley-VCH
DOI: 10.1002/chem.202202283

Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex

Author(s): Amy E. Kynman, Samantha Lau, Sean O. Dowd, Tobias Krämer, Adrian B. Chaplin
Published in: European Journal of Inorganic Chemistry, Issue 2020/41, 2020, Page(s) 3899-3906, ISSN 1099-0682
Publisher: Wiley-VCH
DOI: 10.1002/ejic.202000780

Synthesis and group 9 complexes of macrocyclic PCP and POCOP pincer ligands

Author(s): Baptiste Leforestier, Matthew R. Gyton, Adrian B. Chaplin
Published in: Dalton Transactions, Issue 49/7, 2020, Page(s) 2087-2101, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9dt04835a

Iridium complexes of an ortho-trifluoromethylphenyl substituted PONOP pincer ligand.

Author(s): W. Poole, I. Bustos, T. M. Hood, J. E. Smart and A. B. Chaplin
Published in: Dalton Transactions, 2022, Page(s) 1096 – 1104, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2dt03608h

Oxidative Addition of a Mechanically Entrapped C(sp)–C(sp) Bond to a Rhodium(I) Pincer Complex

Author(s): Baptiste Leforestier, Matthew R. Gyton, Adrian B. Chaplin
Published in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202009546

Divergent stereoisomers of molybdenum carbonyl complexes of NHC-based pincer ligands

Author(s): Samantha L. Apps, Rhiannon E. Alflatt, Baptiste Leforestier, Caroline M. Storey, Adrian B. Chaplin
Published in: Polyhedron, Issue 143, 2018, Page(s) 57-61, ISSN 0277-5387
Publisher: Pergamon Press
DOI: 10.1016/j.poly.2017.08.001

Terminal Alkyne Coupling Reactions through a Ring: Mechanistic Insights and Regiochemical Switching

Author(s): Caroline M. Storey, Matthew R. Gyton, Rhiann E. Andrew, Adrian B. Chaplin
Published in: Angewandte Chemie International Edition, Issue 57/37, 2018, Page(s) 12003-12006, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201807028

Rotaxane synthesis exploiting the M( i )/M( iii ) redox couple

Author(s): Jack Emerson-King, Richard C. Knighton, Matthew R. Gyton, Adrian B. Chaplin
Published in: Dalton Transactions, Issue 46/35, 2017, Page(s) 11645-11655, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7dt02648j

Rhodium(III) and Iridium(III) Complexes of a NHC-Based Macrocycle: Persistent Weak Agostic Interactions and Reactions with Dihydrogen

Author(s): Matthew R. Gyton, Baptiste Leforestier, Adrian B. Chaplin
Published in: Organometallics, Issue 37/21, 2018, Page(s) 3963-3971, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.8b00595

A convenient method for the generation of {Rh(PNP)} + and {Rh(PONOP)} + fragments: reversible formation of vinylidene derivatives

Author(s): Matthew R. Gyton, Thomas M. Hood, Adrian B. Chaplin
Published in: Dalton Transactions, Issue 48/9, 2019, Page(s) 2877-2880, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8dt05049j

Synthesis and Structural Dynamics of Five-Coordinate Rh(III) and Ir(III) PNP and PONOP Pincer Complexes

Author(s): Thomas M. Hood, Baptiste Leforestier, Matthew R. Gyton, Adrian B. Chaplin
Published in: Inorganic Chemistry, Issue 58/11, 2019, Page(s) 7593-7601, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b00957

Rhodium(I) Pincer Complexes of Nitrous Oxide

Author(s): Matthew R. Gyton, Baptiste Leforestier, Adrian B. Chaplin
Published in: Angewandte Chemie International Edition, Issue 58/43, 2019, Page(s) 15295-15298, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201908333

Probing the Donor Properties of Pincer Ligands Using Rhodium Carbonyl Fragments: An Experimental and Computational Case Study

Author(s): Gemma L. Parker, Samantha Lau, Baptiste Leforestier, Adrian B. Chaplin
Published in: European Journal of Inorganic Chemistry, Issue 2019/33, 2019, Page(s) 3791-3798, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.201900727

Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles

Author(s): Rhiann E. Andrew, Caroline M. Storey, Adrian B. Chaplin
Published in: Dalton Trans., Issue 45/21, 2016, Page(s) 8937-8944, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c6dt01263a

A shape changing tandem Rh(CNC) catalyst: preparation of bicyclo[4.2.0]octa-1,5,7-trienes from terminal aryl alkynes

Author(s): Caroline M. Storey, Audrius Kalpokas, Matthew R. Gyton, Tobias Krämer, Adrian B. Chaplin
Published in: Chemical Science, Issue 11/8, 2020, Page(s) 2051-2057, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9sc06153c

Synthesis and reactivity of iridium complexes of a macrocyclic PNP pincer ligand

Author(s): Thomas M. Hood, Adrian B. Chaplin
Published in: Dalton Transactions, Issue 50/7, 2021, Page(s) 2472-2482, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0dt04303f

Isolation and structural characterisation of rhodium( iii ) η 2 -fluoroarene complexes: experimental verification of predicted regioselectivity

Author(s): Matthew R. Gyton, Amy E. Kynman, Baptiste Leforestier, Angelo Gallo, Józef R. Lewandowski, Adrian B. Chaplin
Published in: Dalton Transactions, Issue 49/18, 2020, Page(s) 5791-5793, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0dt01137a

Book chapters (1)

Complexes of NHC-Based CEC Pincer Ligands: Structural Diversity and Applications

Author(s): Caroline M. Storey, Hans P. Cook, Adrian B. Chaplin
Published in: Pincer Compounds: Chemistry and Applications, 2018, Page(s) 173-189, ISBN 9780-128129326
Publisher: Elsevier
DOI: 10.1016/B978-0-12-812931-9.00008-6