Entangled pincer ligand architectures and their application in the transition-metal-mediated activation of alkanes

Project Information

ENTANGLED-TM-ALKANE

Grant agreement ID: 637313

DOI 10.3030/637313

Project closed

EC signature date 17 February 2015

Start date 1 April 2015

End date 30 September 2020

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 521 137,33

EU contribution € 1 521 137,33

Coordinated by

UNIVERSITY OF WARWICK
United Kingdom

Publications

Peer reviewed articles (21)

Terminal Alkyne Coupling Reactions Through a Ring: Effect of Ring Size on Rate and Regioselectivity

Author(s): Caroline M. Storey, Matthew R. Gyton, Rhiann E. Andrew, Adrian B. Chaplin
Published in: Chemistry—A European Journal, Issue 26/64, 2020, Page(s) 14715-14723, ISSN 1521-3765
Publisher: Wiley-VCH
DOI: 10.1002/chem.202002962

Reactions of Rh(PNP) pincer complexes with terminal alkynes: homocoupling through a ring or not at all

Author(s): Thomas M. Hood, Adrian B. Chaplin
Published in: Dalton Transactions, 2020, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0dt03550e

Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand.

Author(s): J. Emerson-King, S. Pan, M. R. Gyton, R. Tonner-Zech and A. B. Chaplin
Published in: Chemical Communications, 2023, Page(s) 2150 – 2152, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2cc06837k

Synthesis and rhodium complexes of macrocyclic PNP and PONOP pincer ligands

Author(s): Thomas M. Hood, Matthew R. Gyton, Adrian B. Chaplin
Published in: Dalton Transactions, Issue 49/7, 2020, Page(s) 2077-2086, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/C9DT04474D

Modulation of Metal Carbonyl Stretching Frequencies in the Second Coordination Sphere through the Internal Stark Effect

Author(s): Gemma L. Parker; Ruben Van Lommel; Nil Roig; Mercedes Alonso; Adrian B. Chaplin
Published in: Chemistry—A European Journal, 2022, Page(s) e202202283, ISSN 1521-3765
Publisher: Wiley-VCH
DOI: 10.1002/chem.202202283

Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex

Author(s): Amy E. Kynman, Samantha Lau, Sean O. Dowd, Tobias Krämer, Adrian B. Chaplin
Published in: European Journal of Inorganic Chemistry, Issue 2020/41, 2020, Page(s) 3899-3906, ISSN 1099-0682
Publisher: Wiley-VCH
DOI: 10.1002/ejic.202000780

Synthesis and group 9 complexes of macrocyclic PCP and POCOP pincer ligands

Author(s): Baptiste Leforestier, Matthew R. Gyton, Adrian B. Chaplin
Published in: Dalton Transactions, Issue 49/7, 2020, Page(s) 2087-2101, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9dt04835a

Iridium complexes of an ortho-trifluoromethylphenyl substituted PONOP pincer ligand.

Author(s): W. Poole, I. Bustos, T. M. Hood, J. E. Smart and A. B. Chaplin
Published in: Dalton Transactions, 2022, Page(s) 1096 – 1104, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2dt03608h

Oxidative Addition of a Mechanically Entrapped C(sp)–C(sp) Bond to a Rhodium(I) Pincer Complex

Author(s): Baptiste Leforestier, Matthew R. Gyton, Adrian B. Chaplin
Published in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202009546

Divergent stereoisomers of molybdenum carbonyl complexes of NHC-based pincer ligands

Author(s): Samantha L. Apps, Rhiannon E. Alflatt, Baptiste Leforestier, Caroline M. Storey, Adrian B. Chaplin
Published in: Polyhedron, Issue 143, 2018, Page(s) 57-61, ISSN 0277-5387
Publisher: Pergamon Press
DOI: 10.1016/j.poly.2017.08.001

Terminal Alkyne Coupling Reactions through a Ring: Mechanistic Insights and Regiochemical Switching

Author(s): Caroline M. Storey, Matthew R. Gyton, Rhiann E. Andrew, Adrian B. Chaplin
Published in: Angewandte Chemie International Edition, Issue 57/37, 2018, Page(s) 12003-12006, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201807028

Rotaxane synthesis exploiting the M( i )/M( iii ) redox couple

Author(s): Jack Emerson-King, Richard C. Knighton, Matthew R. Gyton, Adrian B. Chaplin
Published in: Dalton Transactions, Issue 46/35, 2017, Page(s) 11645-11655, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7dt02648j

Rhodium(III) and Iridium(III) Complexes of a NHC-Based Macrocycle: Persistent Weak Agostic Interactions and Reactions with Dihydrogen

Author(s): Matthew R. Gyton, Baptiste Leforestier, Adrian B. Chaplin
Published in: Organometallics, Issue 37/21, 2018, Page(s) 3963-3971, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.8b00595

A convenient method for the generation of {Rh(PNP)} + and {Rh(PONOP)} + fragments: reversible formation of vinylidene derivatives

Author(s): Matthew R. Gyton, Thomas M. Hood, Adrian B. Chaplin
Published in: Dalton Transactions, Issue 48/9, 2019, Page(s) 2877-2880, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8dt05049j

Synthesis and Structural Dynamics of Five-Coordinate Rh(III) and Ir(III) PNP and PONOP Pincer Complexes

Author(s): Thomas M. Hood, Baptiste Leforestier, Matthew R. Gyton, Adrian B. Chaplin
Published in: Inorganic Chemistry, Issue 58/11, 2019, Page(s) 7593-7601, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b00957

Rhodium(I) Pincer Complexes of Nitrous Oxide

Author(s): Matthew R. Gyton, Baptiste Leforestier, Adrian B. Chaplin
Published in: Angewandte Chemie International Edition, Issue 58/43, 2019, Page(s) 15295-15298, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201908333

Probing the Donor Properties of Pincer Ligands Using Rhodium Carbonyl Fragments: An Experimental and Computational Case Study

Author(s): Gemma L. Parker, Samantha Lau, Baptiste Leforestier, Adrian B. Chaplin
Published in: European Journal of Inorganic Chemistry, Issue 2019/33, 2019, Page(s) 3791-3798, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.201900727

Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles

Author(s): Rhiann E. Andrew, Caroline M. Storey, Adrian B. Chaplin
Published in: Dalton Trans., Issue 45/21, 2016, Page(s) 8937-8944, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c6dt01263a

A shape changing tandem Rh(CNC) catalyst: preparation of bicyclo[4.2.0]octa-1,5,7-trienes from terminal aryl alkynes

Author(s): Caroline M. Storey, Audrius Kalpokas, Matthew R. Gyton, Tobias Krämer, Adrian B. Chaplin
Published in: Chemical Science, Issue 11/8, 2020, Page(s) 2051-2057, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9sc06153c

Synthesis and reactivity of iridium complexes of a macrocyclic PNP pincer ligand

Author(s): Thomas M. Hood, Adrian B. Chaplin
Published in: Dalton Transactions, Issue 50/7, 2021, Page(s) 2472-2482, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0dt04303f

Isolation and structural characterisation of rhodium( iii ) η 2 -fluoroarene complexes: experimental verification of predicted regioselectivity

Author(s): Matthew R. Gyton, Amy E. Kynman, Baptiste Leforestier, Angelo Gallo, Józef R. Lewandowski, Adrian B. Chaplin
Published in: Dalton Transactions, Issue 49/18, 2020, Page(s) 5791-5793, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0dt01137a

Book chapters (1)

Complexes of NHC-Based CEC Pincer Ligands: Structural Diversity and Applications

Author(s): Caroline M. Storey, Hans P. Cook, Adrian B. Chaplin
Published in: Pincer Compounds: Chemistry and Applications, 2018, Page(s) 173-189, ISBN 9780-128129326
Publisher: Elsevier
DOI: 10.1016/B978-0-12-812931-9.00008-6