Entangled pincer ligand architectures and their application in the transition-metal-mediated activation of alkanes

Informazioni relative al progetto

ENTANGLED-TM-ALKANE

ID dell’accordo di sovvenzione: 637313

DOI 10.3030/637313

Progetto chiuso

Data della firma CE 17 Febbraio 2015

Data di avvio 1 Aprile 2015

Data di completamento 30 Settembre 2020

Finanziato da

• EXCELLENT SCIENCE - European Research Council (ERC)

Costo totale € 1 521 137,33

Contributo UE € 1 521 137,33

Coordinato da

UNIVERSITY OF WARWICK
United Kingdom

Pubblicazioni

Peer reviewed articles (21)

Terminal Alkyne Coupling Reactions Through a Ring: Effect of Ring Size on Rate and Regioselectivity

Autori: Caroline M. Storey, Matthew R. Gyton, Rhiann E. Andrew, Adrian B. Chaplin
Pubblicato in: Chemistry—A European Journal, Numero 26/64, 2020, Pagina/e 14715-14723, ISSN 1521-3765
Editore: Wiley-VCH
DOI: 10.1002/chem.202002962

Reactions of Rh(PNP) pincer complexes with terminal alkynes: homocoupling through a ring or not at all

Autori: Thomas M. Hood, Adrian B. Chaplin
Pubblicato in: Dalton Transactions, 2020, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/d0dt03550e

Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand.

Autori: J. Emerson-King, S. Pan, M. R. Gyton, R. Tonner-Zech and A. B. Chaplin
Pubblicato in: Chemical Communications, 2023, Pagina/e 2150 – 2152, ISSN 1359-7345
Editore: Royal Society of Chemistry
DOI: 10.1039/d2cc06837k

Synthesis and rhodium complexes of macrocyclic PNP and PONOP pincer ligands

Autori: Thomas M. Hood, Matthew R. Gyton, Adrian B. Chaplin
Pubblicato in: Dalton Transactions, Numero 49/7, 2020, Pagina/e 2077-2086, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/C9DT04474D

Modulation of Metal Carbonyl Stretching Frequencies in the Second Coordination Sphere through the Internal Stark Effect

Autori: Gemma L. Parker; Ruben Van Lommel; Nil Roig; Mercedes Alonso; Adrian B. Chaplin
Pubblicato in: Chemistry—A European Journal, 2022, Pagina/e e202202283, ISSN 1521-3765
Editore: Wiley-VCH
DOI: 10.1002/chem.202202283

Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex

Autori: Amy E. Kynman, Samantha Lau, Sean O. Dowd, Tobias Krämer, Adrian B. Chaplin
Pubblicato in: European Journal of Inorganic Chemistry, Numero 2020/41, 2020, Pagina/e 3899-3906, ISSN 1099-0682
Editore: Wiley-VCH
DOI: 10.1002/ejic.202000780

Synthesis and group 9 complexes of macrocyclic PCP and POCOP pincer ligands

Autori: Baptiste Leforestier, Matthew R. Gyton, Adrian B. Chaplin
Pubblicato in: Dalton Transactions, Numero 49/7, 2020, Pagina/e 2087-2101, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/c9dt04835a

Iridium complexes of an ortho-trifluoromethylphenyl substituted PONOP pincer ligand.

Autori: W. Poole, I. Bustos, T. M. Hood, J. E. Smart and A. B. Chaplin
Pubblicato in: Dalton Transactions, 2022, Pagina/e 1096 – 1104, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/d2dt03608h

Oxidative Addition of a Mechanically Entrapped C(sp)–C(sp) Bond to a Rhodium(I) Pincer Complex

Autori: Baptiste Leforestier, Matthew R. Gyton, Adrian B. Chaplin
Pubblicato in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202009546

Divergent stereoisomers of molybdenum carbonyl complexes of NHC-based pincer ligands

Autori: Samantha L. Apps, Rhiannon E. Alflatt, Baptiste Leforestier, Caroline M. Storey, Adrian B. Chaplin
Pubblicato in: Polyhedron, Numero 143, 2018, Pagina/e 57-61, ISSN 0277-5387
Editore: Pergamon Press
DOI: 10.1016/j.poly.2017.08.001

Terminal Alkyne Coupling Reactions through a Ring: Mechanistic Insights and Regiochemical Switching

Autori: Caroline M. Storey, Matthew R. Gyton, Rhiann E. Andrew, Adrian B. Chaplin
Pubblicato in: Angewandte Chemie International Edition, Numero 57/37, 2018, Pagina/e 12003-12006, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201807028

Rotaxane synthesis exploiting the M( i )/M( iii ) redox couple

Autori: Jack Emerson-King, Richard C. Knighton, Matthew R. Gyton, Adrian B. Chaplin
Pubblicato in: Dalton Transactions, Numero 46/35, 2017, Pagina/e 11645-11655, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/c7dt02648j

Rhodium(III) and Iridium(III) Complexes of a NHC-Based Macrocycle: Persistent Weak Agostic Interactions and Reactions with Dihydrogen

Autori: Matthew R. Gyton, Baptiste Leforestier, Adrian B. Chaplin
Pubblicato in: Organometallics, Numero 37/21, 2018, Pagina/e 3963-3971, ISSN 0276-7333
Editore: American Chemical Society
DOI: 10.1021/acs.organomet.8b00595

A convenient method for the generation of {Rh(PNP)} + and {Rh(PONOP)} + fragments: reversible formation of vinylidene derivatives

Autori: Matthew R. Gyton, Thomas M. Hood, Adrian B. Chaplin
Pubblicato in: Dalton Transactions, Numero 48/9, 2019, Pagina/e 2877-2880, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/c8dt05049j

Synthesis and Structural Dynamics of Five-Coordinate Rh(III) and Ir(III) PNP and PONOP Pincer Complexes

Autori: Thomas M. Hood, Baptiste Leforestier, Matthew R. Gyton, Adrian B. Chaplin
Pubblicato in: Inorganic Chemistry, Numero 58/11, 2019, Pagina/e 7593-7601, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b00957

Rhodium(I) Pincer Complexes of Nitrous Oxide

Autori: Matthew R. Gyton, Baptiste Leforestier, Adrian B. Chaplin
Pubblicato in: Angewandte Chemie International Edition, Numero 58/43, 2019, Pagina/e 15295-15298, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201908333

Probing the Donor Properties of Pincer Ligands Using Rhodium Carbonyl Fragments: An Experimental and Computational Case Study

Autori: Gemma L. Parker, Samantha Lau, Baptiste Leforestier, Adrian B. Chaplin
Pubblicato in: European Journal of Inorganic Chemistry, Numero 2019/33, 2019, Pagina/e 3791-3798, ISSN 1434-1948
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.201900727

Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles

Autori: Rhiann E. Andrew, Caroline M. Storey, Adrian B. Chaplin
Pubblicato in: Dalton Trans., Numero 45/21, 2016, Pagina/e 8937-8944, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/c6dt01263a

A shape changing tandem Rh(CNC) catalyst: preparation of bicyclo[4.2.0]octa-1,5,7-trienes from terminal aryl alkynes

Autori: Caroline M. Storey, Audrius Kalpokas, Matthew R. Gyton, Tobias Krämer, Adrian B. Chaplin
Pubblicato in: Chemical Science, Numero 11/8, 2020, Pagina/e 2051-2057, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/c9sc06153c

Synthesis and reactivity of iridium complexes of a macrocyclic PNP pincer ligand

Autori: Thomas M. Hood, Adrian B. Chaplin
Pubblicato in: Dalton Transactions, Numero 50/7, 2021, Pagina/e 2472-2482, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/d0dt04303f

Isolation and structural characterisation of rhodium( iii ) η 2 -fluoroarene complexes: experimental verification of predicted regioselectivity

Autori: Matthew R. Gyton, Amy E. Kynman, Baptiste Leforestier, Angelo Gallo, Józef R. Lewandowski, Adrian B. Chaplin
Pubblicato in: Dalton Transactions, Numero 49/18, 2020, Pagina/e 5791-5793, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/d0dt01137a

Book chapters (1)

Complexes of NHC-Based CEC Pincer Ligands: Structural Diversity and Applications

Autori: Caroline M. Storey, Hans P. Cook, Adrian B. Chaplin
Pubblicato in: Pincer Compounds: Chemistry and Applications, 2018, Pagina/e 173-189, ISBN 9780-128129326
Editore: Elsevier
DOI: 10.1016/B978-0-12-812931-9.00008-6