Fundamental Studies in Catalysis – Reactivity Design with Experimental and Computational Tools

Project Information

FunCatDesign

Grant agreement ID: 637993

DOI

10.3030/637993

Project closed

EC signature date 24 February 2015

Start date 1 May 2015

End date 30 April 2020

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 491 875,00

EU contribution

€ 1 491 875,00

Coordinated by

RHEINISCH-WESTFAELISCHE TECHNISCHE HOCHSCHULE AACHEN
Germany

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (18)

Divergent Reactivity of a Dinuclear (NHC)Nickel(I) Catalyst versus Nickel(0) Enables Chemoselective Trifluoromethylselenolation

Author(s): Alexander B. Dürr, Henry C. Fisher, Indrek Kalvet, Khai-Nghi Truong, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 56/43, 2017, Page(s) 13431-13435, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201706423

Palladium(I) Dimer Enabled Extremely Rapid and Chemoselective Alkylation of Aryl Bromides over Triflates and Chlorides in Air

Author(s): Indrek Kalvet, Theresa Sperger, Thomas Scattolin, Guillaume Magnin, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 56/25, 2017, Page(s) 7078-7082, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201701691

Palladium-Catalyzed Decarbonylative Trifluoromethylation of Acid Fluorides

Author(s): Sinead T. Keaveney, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 57/15, 2018, Page(s) 4073-4077, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201800644

Efficient Synthesis of Trifluoromethyl Amines through a Formal Umpolung Strategy from the Bench-Stable Precursor (Me 4 N)SCF 3

Author(s): Thomas Scattolin, Kristina Deckers, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 56/1, 2017, Page(s) 221-224, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201609480

When Weaker Can Be Tougher: The Role of Oxidation State (I) in P- vs N-Ligand-Derived Ni-Catalyzed Trifluoromethylthiolation of Aryl Halides

Author(s): Indrek Kalvet, Qianqian Guo, Graham J. Tizzard, Franziska Schoenebeck
Published in: ACS Catalysis, Issue 7/3, 2017, Page(s) 2126-2132, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.6b03344

Site-Selective C−S Bond Formation at C−Br over C−OTf and C−Cl Enabled by an Air-Stable, Easily Recoverable, and Recyclable Palladium(I) Catalyst

Author(s): Thomas Scattolin, Erdem Senol, Guoyin Yin, Qianqian Guo, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 57/38, 2018, Page(s) 12425-12429, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201806036

Gold-Catalyzed C–H Functionalization with Aryl Germanes

Author(s): Christoph Fricke, Amit Dahiya, William B. Reid, Franziska Schoenebeck
Published in: ACS Catalysis, Issue 9/10, 2019, Page(s) 9231-9236, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.9b02841

Arylation of Axially Chiral Phosphorothioate Salts by Dinuclear Pd I Catalysis

Author(s): Xiang-Yu Chen, Maoping Pu, Hong-Gang Cheng, Theresa Sperger, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 58/33, 2019, Page(s) 11395-11399, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201906063

E -Olefins through intramolecular radical relocation

Author(s): Ajoy Kapat, Theresa Sperger, Sinem Guven, Franziska Schoenebeck
Published in: Science, Issue 363/6425, 2019, Page(s) 391-396, ISSN 0036-8075
Publisher: American Association for the Advancement of Science
DOI: 10.1126/science.aav1610

Rapid Room-Temperature, Chemoselective Csp2 −Csp2 Coupling of Poly(pseudo)halogenated Arenes Enabled by Palladium(I) Catalysis in Air

Author(s): Indrek Kalvet, Guillaume Magnin, Franziska Schoenebeck
Published in: Angewandte Chemie, Issue 129/6, 2017, Page(s) 1603-1607, ISSN 0044-8249
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.201609635

Modular Functionalization of Arenes in a Triply Selective Sequence: Rapid C(sp 2 ) and C(sp 3 ) Coupling of C−Br, C−OTf, and C−Cl Bonds Enabled by a Single Palladium(I) Dimer

Author(s): Sinead T. Keaveney, Gourab Kundu, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 57/38, 2018, Page(s) 12573-12577, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201808386

A General and Air-tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis

Author(s): Guillaume Magnin, Jamie Clifton, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 58/30, 2019, Page(s) 10179-10183, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201903765

Divergent Reactivity of Stannane and Silane in the Trifluoromethylation of Pd II : Cyclic Transition State versus Difluorocarbene Release

Author(s): Maoping Pu, Italo A. Sanhueza, Erdem Senol, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 57/46, 2018, Page(s) 15081-15085, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201808229

Orthogonal Nanoparticle Catalysis with Organogermanes

Author(s): Christoph Fricke, Grant J. Sherborne, Ignacio Funes‐Ardoiz, Erdem Senol, Sinem Guven, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 58/49, 2019, Page(s) 17788-17795, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201910060

Site‐Selective, Modular Diversification of Polyhalogenated Aryl Fluorosulfates (ArOSO 2 F) Enabled by an Air‐Stable Pd I Dimer

Author(s): Marvin Mendel, Indrek Kalvet, Daniel Hupperich, Guillaume Magnin, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 59/5, 2020, Page(s) 2115-2119, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201911465

Selective ortho ‐Functionalization of Adamantylarenes Enabled by Dispersion and an Air‐Stable Palladium(I) Dimer

Author(s): Indrek Kalvet, Kristina Deckers, Ignacio Funes‐Ardoiz, Guillaume Magnin, Theresa Sperger, Marius Kremer, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 59/20, 2020, Page(s) 7721-7725, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202001326

N ‐Trifluoromethyl Hydrazines, Indoles and Their Derivatives

Author(s): Samir Bouayad‐Gervais, Thomas Scattolin, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202004321

Modular and Selective Arylation of Aryl Germanes (C−GeEt 3 ) over C−Bpin, C−SiR 3 and Halogens Enabled by Light‐Activated Gold Catalysis

Author(s): Grant J. Sherborne, Avetik G. Gevondian, Ignacio Funes‐Ardoiz, Amit Dahiya, Christoph Fricke, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202005066