Fundamental Studies in Catalysis – Reactivity Design with Experimental and Computational Tools

Informazioni relative al progetto

FunCatDesign

ID dell’accordo di sovvenzione: 637993

DOI

10.3030/637993

Progetto chiuso

Data della firma CE 24 Febbraio 2015

Data di avvio 1 Maggio 2015

Data di completamento 30 Aprile 2020

Finanziato da

• EXCELLENT SCIENCE - European Research Council (ERC)

Costo totale

€ 1 491 875,00

Contributo UE

€ 1 491 875,00

Coordinato da

RHEINISCH-WESTFAELISCHE TECHNISCHE HOCHSCHULE AACHEN
Germany

CORDIS fornisce collegamenti ai risultati finali pubblici e alle pubblicazioni dei progetti ORIZZONTE.

I link ai risultati e alle pubblicazioni dei progetti del 7° PQ, così come i link ad alcuni tipi di risultati specifici come dataset e software, sono recuperati dinamicamente da .OpenAIRE .

Pubblicazioni

Peer reviewed articles (18)

Divergent Reactivity of a Dinuclear (NHC)Nickel(I) Catalyst versus Nickel(0) Enables Chemoselective Trifluoromethylselenolation

Autori: Alexander B. Dürr, Henry C. Fisher, Indrek Kalvet, Khai-Nghi Truong, Franziska Schoenebeck
Pubblicato in: Angewandte Chemie International Edition, Numero 56/43, 2017, Pagina/e 13431-13435, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201706423

Palladium(I) Dimer Enabled Extremely Rapid and Chemoselective Alkylation of Aryl Bromides over Triflates and Chlorides in Air

Autori: Indrek Kalvet, Theresa Sperger, Thomas Scattolin, Guillaume Magnin, Franziska Schoenebeck
Pubblicato in: Angewandte Chemie International Edition, Numero 56/25, 2017, Pagina/e 7078-7082, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201701691

Palladium-Catalyzed Decarbonylative Trifluoromethylation of Acid Fluorides

Autori: Sinead T. Keaveney, Franziska Schoenebeck
Pubblicato in: Angewandte Chemie International Edition, Numero 57/15, 2018, Pagina/e 4073-4077, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201800644

Efficient Synthesis of Trifluoromethyl Amines through a Formal Umpolung Strategy from the Bench-Stable Precursor (Me 4 N)SCF 3

Autori: Thomas Scattolin, Kristina Deckers, Franziska Schoenebeck
Pubblicato in: Angewandte Chemie International Edition, Numero 56/1, 2017, Pagina/e 221-224, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201609480

When Weaker Can Be Tougher: The Role of Oxidation State (I) in P- vs N-Ligand-Derived Ni-Catalyzed Trifluoromethylthiolation of Aryl Halides

Autori: Indrek Kalvet, Qianqian Guo, Graham J. Tizzard, Franziska Schoenebeck
Pubblicato in: ACS Catalysis, Numero 7/3, 2017, Pagina/e 2126-2132, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.6b03344

Site-Selective C−S Bond Formation at C−Br over C−OTf and C−Cl Enabled by an Air-Stable, Easily Recoverable, and Recyclable Palladium(I) Catalyst

Autori: Thomas Scattolin, Erdem Senol, Guoyin Yin, Qianqian Guo, Franziska Schoenebeck
Pubblicato in: Angewandte Chemie International Edition, Numero 57/38, 2018, Pagina/e 12425-12429, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201806036

Gold-Catalyzed C–H Functionalization with Aryl Germanes

Autori: Christoph Fricke, Amit Dahiya, William B. Reid, Franziska Schoenebeck
Pubblicato in: ACS Catalysis, Numero 9/10, 2019, Pagina/e 9231-9236, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.9b02841

Arylation of Axially Chiral Phosphorothioate Salts by Dinuclear Pd I Catalysis

Autori: Xiang-Yu Chen, Maoping Pu, Hong-Gang Cheng, Theresa Sperger, Franziska Schoenebeck
Pubblicato in: Angewandte Chemie International Edition, Numero 58/33, 2019, Pagina/e 11395-11399, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201906063

E -Olefins through intramolecular radical relocation

Autori: Ajoy Kapat, Theresa Sperger, Sinem Guven, Franziska Schoenebeck
Pubblicato in: Science, Numero 363/6425, 2019, Pagina/e 391-396, ISSN 0036-8075
Editore: American Association for the Advancement of Science
DOI: 10.1126/science.aav1610

Rapid Room-Temperature, Chemoselective Csp2 −Csp2 Coupling of Poly(pseudo)halogenated Arenes Enabled by Palladium(I) Catalysis in Air

Autori: Indrek Kalvet, Guillaume Magnin, Franziska Schoenebeck
Pubblicato in: Angewandte Chemie, Numero 129/6, 2017, Pagina/e 1603-1607, ISSN 0044-8249
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/ange.201609635

Modular Functionalization of Arenes in a Triply Selective Sequence: Rapid C(sp 2 ) and C(sp 3 ) Coupling of C−Br, C−OTf, and C−Cl Bonds Enabled by a Single Palladium(I) Dimer

Autori: Sinead T. Keaveney, Gourab Kundu, Franziska Schoenebeck
Pubblicato in: Angewandte Chemie International Edition, Numero 57/38, 2018, Pagina/e 12573-12577, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201808386

A General and Air-tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis

Autori: Guillaume Magnin, Jamie Clifton, Franziska Schoenebeck
Pubblicato in: Angewandte Chemie International Edition, Numero 58/30, 2019, Pagina/e 10179-10183, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201903765

Divergent Reactivity of Stannane and Silane in the Trifluoromethylation of Pd II : Cyclic Transition State versus Difluorocarbene Release

Autori: Maoping Pu, Italo A. Sanhueza, Erdem Senol, Franziska Schoenebeck
Pubblicato in: Angewandte Chemie International Edition, Numero 57/46, 2018, Pagina/e 15081-15085, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201808229

Orthogonal Nanoparticle Catalysis with Organogermanes

Autori: Christoph Fricke, Grant J. Sherborne, Ignacio Funes‐Ardoiz, Erdem Senol, Sinem Guven, Franziska Schoenebeck
Pubblicato in: Angewandte Chemie International Edition, Numero 58/49, 2019, Pagina/e 17788-17795, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201910060

Site‐Selective, Modular Diversification of Polyhalogenated Aryl Fluorosulfates (ArOSO 2 F) Enabled by an Air‐Stable Pd I Dimer

Autori: Marvin Mendel, Indrek Kalvet, Daniel Hupperich, Guillaume Magnin, Franziska Schoenebeck
Pubblicato in: Angewandte Chemie International Edition, Numero 59/5, 2020, Pagina/e 2115-2119, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201911465

Selective ortho ‐Functionalization of Adamantylarenes Enabled by Dispersion and an Air‐Stable Palladium(I) Dimer

Autori: Indrek Kalvet, Kristina Deckers, Ignacio Funes‐Ardoiz, Guillaume Magnin, Theresa Sperger, Marius Kremer, Franziska Schoenebeck
Pubblicato in: Angewandte Chemie International Edition, Numero 59/20, 2020, Pagina/e 7721-7725, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202001326

N ‐Trifluoromethyl Hydrazines, Indoles and Their Derivatives

Autori: Samir Bouayad‐Gervais, Thomas Scattolin, Franziska Schoenebeck
Pubblicato in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202004321

Modular and Selective Arylation of Aryl Germanes (C−GeEt 3 ) over C−Bpin, C−SiR 3 and Halogens Enabled by Light‐Activated Gold Catalysis

Autori: Grant J. Sherborne, Avetik G. Gevondian, Ignacio Funes‐Ardoiz, Amit Dahiya, Christoph Fricke, Franziska Schoenebeck
Pubblicato in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202005066