N2 as Chemical Feedstock – Synthetic Nitrogen Fixation beyond Haber-Bosch

Project Information

N2FEED

Grant agreement ID: 646747

DOI

10.3030/646747

Project closed

EC signature date 6 May 2015

Start date 1 June 2015

End date 30 November 2020

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 998 500,00

EU contribution

€ 1 998 500,00

Coordinated by

GEORG-AUGUST-UNIVERSITAT GOTTINGEN STIFTUNG OFFENTLICHEN RECHTS
Germany

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Non-peer reviewed articles (1)

A Terminal Chlorophosphinidene Complex

Author(s): Josh Abbenseth, Sven Schneider
Published in: Zeitschrift für anorganische und allgemeine Chemie, Issue 646/13, 2020, Page(s) 565-569, ISSN 0044-2313
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/zaac.202000010

Peer reviewed articles (29)

A platinum(ii) metallonitrene with a triplet ground state

Author(s): Jian Sun, Josh Abbenseth, Hendrik Verplancke, Martin Diefenbach, Bas de Bruin, David Hunger, Christian Würtele, Joris van Slageren, Max C. Holthausen, Sven Schneider
Published in: Nature Chemistry, Issue 12/11, 2020, Page(s) 1054-1059, ISSN 1755-4330
Publisher: Nature Publishing Group
DOI: 10.1038/s41557-020-0522-4

The Metaphosphite (PO 2 − ) Anion as a Ligand

Author(s): Josh Abbenseth, Florian Wätjen, Markus Finger, Sven Schneider
Published in: Angewandte Chemie, Issue 132/52, 2020, Page(s) 23780-23784, ISSN 0044-8249
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202011750

Stabilizing P≡P: P22–, P2⋅–, and P20 as bridging ligands

Author(s): Jian Sun, Hendrik Verplancke, Julia I. Schweizer, Martin Diefenbach, Christian Würtele, Matthias Otte, Igor Tkach, Christian Herwig, Christian Limberg, Serhiy Demeshko, Max C. Holthausen, Sven Schneider
Published in: Chem, Issue 7/7, 2021, Page(s) 1952-1962, ISSN 2451-9294
Publisher: Science Direct
DOI: 10.1016/j.chempr.2021.06.006

Examination of Protonation-Induced Dinitrogen Splitting by in Situ EXAFS Spectroscopy

Author(s): Josh Abbenseth, Jean-Pierre H. Oudsen, Bas Venderbosch, Serhiy Demeshko, Markus Finger, Christian Herwig, Christian Würtele, Max C. Holthausen, Christian Limberg, Moniek Tromp, Sven Schneider
Published in: Inorganic Chemistry, Issue 59/19, 2020, Page(s) 14367-14375, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c02134

Cyanate Formation via Photolytic Splitting of Dinitrogen

Author(s): Bastian Schluschaß, Jan-Hendrik Borter, Severine Rupp, Serhiy Demeshko, Christian Herwig, Christian Limberg, Nicholas A. Maciulis, Jessica Schneider, Christian Würtele, Vera Krewald, Dirk Schwarzer, Sven Schneider
Published in: JACS Au, Issue 1/6, 2021, Page(s) 879-894, ISSN 2691-3704
Publisher: ACS
DOI: 10.1021/jacsau.1c00117

(Electro‐)chemical Splitting of Dinitrogen with a Rhenium Pincer Complex

Author(s): Richt S. Alten, Florian Wätjen, Serhiy Demeshko, Alexander J. M. Miller, Christian Würtele, Inke Siewert, Sven Schneider
Published in: European Journal of Inorganic Chemistry, Issue 2020/15-16, 2020, Page(s) 1402-1410, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.201901278

Dinitrogen Splitting Coupled to Protonation

Author(s): Gleb A. Silantyev, Moritz Förster, Bastian Schluschaß, Josh Abbenseth, Christian Würtele, Christian Volkmann, Max C. Holthausen, Sven Schneider
Published in: Angewandte Chemie International Edition, Issue 56/21, 2017, Page(s) 5872-5876, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201701504

Four- and Five-Coordinate Osmium(IV) Nitrides and Imides: Circumventing the “Nitrido Wall”

Author(s): Josh Abbenseth, Sarah C. Bete, Markus Finger, Christian Volkmann, Christian Würtele, Sven Schneider
Published in: Organometallics, Issue 37/5, 2017, Page(s) 802-811, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.7b00707

A Ruthenium Hydrido Dinitrogen Core Conserved across Multielectron/Multiproton Changes to the Pincer Ligand Backbone

Author(s): Quinton J. Bruch, Brian M. Lindley, Bjorn Askevold, Sven Schneider, Alexander J. M. Miller
Published in: Inorganic Chemistry, Issue 57/4, 2018, Page(s) 1964-1975, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.7b02889

The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion

Author(s): Felix Schneck, Jennifer Ahrens, Markus Finger, A. Claudia Stückl, Christian Würtele, Dirk Schwarzer, Sven Schneider
Published in: Nature Communications, Issue 9/1, 2018, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-018-03239-3

Iron catalyzed hydrogenation and electrochemical reduction of CO 2 : The role of functional ligands

Author(s): Arne Glüer, Sven Schneider
Published in: Journal of Organometallic Chemistry, Issue 861, 2018, Page(s) 159-173, ISSN 0022-328X
Publisher: Elsevier BV
DOI: 10.1016/j.jorganchem.2018.02.025

An iridium( iii / iv / v ) redox series featuring a terminal imido complex with triplet ground state

Author(s): Markus Kinauer, Martin Diefenbach, Heiko Bamberger, Serhiy Demeshko, Edward J. Reijerse, Christian Volkmann, Christian Würtele, Joris van Slageren, Bas de Bruin, Max C. Holthausen, Sven Schneider
Published in: Chemical Science, Issue 9/18, 2018, Page(s) 4325-4332, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/C8SC01113C

Mechanism of Chemical and Electrochemical N 2 Splitting by a Rhenium Pincer Complex

Author(s): Brian M. Lindley, Richt S. van Alten, Markus Finger, Florian Schendzielorz, Christian Würtele, Alexander J. M. Miller, Inke Siewert, Sven Schneider
Published in: Journal of the American Chemical Society, 2018, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.8b03755

A Terminal Osmium(IV) Nitride: Ammonia Formation and Ambiphilic Reactivity

Author(s): Florian S. Schendzielorz, Markus Finger, Christian Volkmann, Christian Würtele, Sven Schneider
Published in: Angewandte Chemie International Edition, Issue 55/38, 2016, Page(s) 11417-11420, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201604917

Coupling of terminal iridium nitrido complexes

Author(s): Josh Abbenseth, Markus Finger, Christian Würtele, Müge Kasanmascheff, Sven Schneider
Published in: Inorg. Chem. Front., Issue 3/4, 2016, Page(s) 469-477, ISSN 2052-1553
Publisher: RSC
DOI: 10.1039/C5QI00267B

Chemical Non-Innocence of an Aliphatic PNP Pincer Ligand

Author(s): Felix Schneck, Markus Finger, Moniek Tromp, Sven Schneider
Published in: Chemistry - A European Journal, Issue 23/1, 2017, Page(s) 33-37, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201604407

Conversion of Dinitrogen into Acetonitrile under Ambient Conditions

Author(s): Isabel Klopsch, Markus Kinauer, Markus Finger, Christian Würtele, Sven Schneider
Published in: Angewandte Chemie, Issue 128/15, 2016, Page(s) 4864-4867, ISSN 0044-8249
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.201600790

A square-planar osmium( ii ) complex

Author(s): Josh Abbenseth, Martin Diefenbach, Sarah C. Bete, Christian Würtele, Christian Volkmann, Serhiy Demeshko, Max C. Holthausen, Sven Schneider
Published in: Chemical Communications, Issue 53/40, 2017, Page(s) 5511-5514, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7cc01569k

Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer

Author(s): Josh Abbenseth, Daniel Delony, Marc C. Neben, Christian Würtele, Bas de Bruin, Sven Schneider
Published in: Angewandte Chemie International Edition, Issue 58/19, 2019, Page(s) 6338-6341, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201901470

Synthesis of Benzonitrile from Dinitrogen

Author(s): Isabel Klopsch, Florian Schendzielorz, Christian Volkmann, Christian Würtele, Sven Schneider
Published in: Zeitschrift für anorganische und allgemeine Chemie, Issue 644/17, 2018, Page(s) 916-919, ISSN 0044-2313
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/zaac.201800181

Photochemically Driven Reverse Water-Gas Shift at Ambient Conditions mediated by a Nickel Pincer Complex

Author(s): Felix Schneck, Florian Schendzielorz, Nareh Hatami, Markus Finger, Christian Würtele, Sven Schneider
Published in: Angewandte Chemie, Issue 130/44, 2018, Page(s) 14690-14695, ISSN 0044-8249
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.201803396

Selectivity of tungsten mediated dinitrogen splitting vs. proton reduction

Author(s): Bastian Schluschaß, Josh Abbenseth, Serhiy Demeshko, Markus Finger, Alicja Franke, Christian Herwig, Christian Würtele, Ivana Ivanovic-Burmazovic, Christian Limberg, Joshua Telser, Sven Schneider
Published in: Chemical Science, Issue 10/44, 2019, Page(s) 10275-10282, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9sc03779a

Oxidative Coupling of Terminal Rhenium Pnictide Complexes

Author(s): Josh Abbenseth, Martin Diefenbach, Alexander Hinz, Lukas Alig, Christian Würtele, Jose M. Goicoechea, Max C. Holthausen, Sven Schneider
Published in: Angewandte Chemie International Edition, Issue 58/32, 2019, Page(s) 10966-10970, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201905130

First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands

Author(s): Lukas Alig, Maximilian Fritz, Sven Schneider
Published in: Chemical Reviews, Issue 119/4, 2018, Page(s) 2681-2751, ISSN 0009-2665
Publisher: American Chemical Society
DOI: 10.1021/acs.chemrev.8b00555

A Terminal Iridium Oxo Complex with a Triplet Ground State

Author(s): Daniel Delony, Markus Kinauer, Martin Diefenbach, Serhiy Demeshko, Christian Würtele, Max C. Holthausen, Sven Schneider
Published in: Angewandte Chemie International Edition, Issue 58/32, 2019, Page(s) 10971-10974, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201905325

Metal-Ligand Cooperative Synthesis of Benzonitrile by Electrochemical Reduction and Photolytic Splitting of Dinitrogen

Author(s): Florian Schendzielorz, Markus Finger, Josh Abbenseth, Christian Würtele, Vera Krewald, Sven Schneider
Published in: Angewandte Chemie International Edition, Issue 58/3, 2019, Page(s) 830-834, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201812125

Nitrogen Fixation via Splitting into Nitrido Complexes

Author(s): Sebastian J. K. Forrest, Bastian Schluschaß, Ekaterina Y. Yuzik-Klimova, Sven Schneider
Published in: Chemical Reviews, Issue 121/11, 2021, Page(s) 6522-6587, ISSN 0009-2665
Publisher: American Chemical Society
DOI: 10.1021/acs.chemrev.0c00958

Exploring the Coordination Chemistry of N 2 with Technetium PNP Pincer-Type Complexes

Author(s): Manuel Luca Besmer, Henrik Braband, Sven Schneider, Bernhard Spingler, Roger Alberto
Published in: Inorganic Chemistry, Issue 60/9, 2021, Page(s) 6696-6701, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.1c00503

Hydrosilane Synthesis by Catalytic Hydrogenolysis of Chlorosilanes and Silyl Triflates

Author(s): Arne Glüer, Julia I. Schweizer, Uhut S. Karaca, Christian Würtele, Martin Diefenbach, Max C. Holthausen, Sven Schneider
Published in: Inorganic Chemistry, Issue 57/21, 2018, Page(s) 13822-13828, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.8b02336

Book chapters (1)

Functionalization of N2 by Mid to Late Transition Metals via N–N Bond Cleavage

Author(s): Isabel Klopsch, Ekaterina Yu Yuzik-Klimova, Sven Schneider
Published in: Topics in Organometallic Chemistry, Issue 60, 2017, Page(s) 71-112, ISBN 978-3-319-57713-5
Publisher: Springer International Publishing
DOI: 10.1007/3418_2016_12