Towards Artificial Enzymes: Bio-inspired Oxidations in Photoactive Metal-Organic Frameworks

Publications

Altering the nature of coupling by changing the oxidation state in a {Mn6} cage

Author(s): Swetanshu Tandon, Munuswamy Venkatesan, Wolfgang Schmitt, Graeme W. Watson
Published in: Dalton Transactions, 2020, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0dt01404d

Hyper-crosslinked 4-amino-1,8-naphthalimide Tröger’s base containing pyridinium covalent organic polymer (COP) for discriminative fluorescent sensing of chemical explosives

Author(s): Jason M. Delente and Deivasigamani Umadevi and Kevin Byrne and Wolfgang Schmitt and Graeme W. Watson and Thorfinnur Gunnlaugsson and Sankarasekaran Shanmugaraju,
Published in: Supramolecular Chemistry, 2020, ISSN 1061-0278
Publisher: Taylor & Francis
DOI: 10.1080/10610278.2020.1825715

Mixed donor, phenanthroline photoactive MOFs with favourable CO2 selectivity

Author(s): Caitlin J. Setter, Michael B. Price, Luke Conte, Wolfgang Schmitt, Stuart R. Batten, Christopher Richardson, Matthew R. Hill, Ravichandar Babarao and Lauren K. Macreadie
Published in: Chemical Communications, 2020, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cc05715k

Synthetic Approaches to Metallo-Supramolecular CoII Polygons and Potential Use for H2O Oxidation

Author(s): Ayuk M. Ako, Amal Cherian Kathalikkattil, Rory Elliott, Joaquín Soriano-López, Ian M. McKeogh, Muhammad Zubair, Nianyong Zhu, Max García-Melchor, Paul E. Kruger, and Wolfgang Schmitt*
Published in: Inorganic Chemistry, 2020, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c02182

Tuning photoactive metal–organic frameworks for luminescence and photocatalytic applications

Author(s): Éadaoin Whelan, Friedrich W.Steuber, Thorfinnur Gunnlaugsson, WolfgangSchmitt
Published in: Coordination Chemistry Reviews, 2021, ISSN 0010-8545
Publisher: Elsevier BV
DOI: 10.1016/j.ccr.2020.213757

A cubane-type manganese complex with H2O oxidation capabilities

Author(s): Tandon, Swetanshu, Soriano-López, Joaquín, Kathalikkattil, Amal C., Jin, Guanghua, Wix, Paul, Venkatesan, Munuswamy, Lundy, Ross, Morris, Michael A., Watson, Graeme W., Schmitt, Wolfgang,
Published in: Sustainable Energy & Fuels, 2020, ISSN 2398-4902
Publisher: RSC
DOI: 10.1039/d0se00701c

Ultra-large supramolecular coordination cages composed of endohedral Archimedean and Platonic bodies

Author(s): Kevin Byrne, Muhammad Zubair, Nianyong Zhu, Xiao-Ping Zhou, Daniel S. Fox, Hongzhou Zhang, Brendan Twamley, Matthew J. Lennox, Tina Düren, Wolfgang Schmitt
Published in: Nature Communications, Issue 8, 2017, Page(s) 15268, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/ncomms15268

Hetero-metallic, functionalizable polyoxomolybdate clusters via a “top-down” synthetic method

Author(s): Colm Healy, Brendan Twamley, Munuswamy Venkatesan, Sebastian Schmidt, Thorfinnur Gunnlaugsson, Wolfgang Schmitt
Published in: Chemical Communications, Issue 53/77, 2017, Page(s) 10660-10663, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7CC05498J

A resilient and luminescent stimuli-responsive hydrogel from a heterotopic 1,8-naphthalimide-derived ligand

Author(s): Chris S. Hawes, Amy D. Lynes, Kevin Byrne, Wolfgang Schmitt, Gavin Ryan, Matthias E. Möbius, Thorfinnur Gunnlaugsson
Published in: Chemical Communications, Issue 53/44, 2017, Page(s) 5989-5992, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7cc03482b

Coordination chemistry of flexible benzene-1,3,5-tricarboxamide derived carboxylates; notable structural resilience and vaguely familiar packing motifs

Author(s): Amy D. Lynes, Chris S. Hawes, Kevin Byrne, Wolfgang Schmitt, Thorfinnur Gunnlaugsson
Published in: Dalton Transactions, Issue 47/15, 2018, Page(s) 5259-5268, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/C8DT00439K

Computational modelling of water oxidation catalysts

Author(s): Joaquín Soriano-López, Wolfgang Schmitt, Max García-Melchor
Published in: Current Opinion in Electrochemistry, Issue 7, 2018, Page(s) 22-30, ISSN 2451-9103
Publisher: Elsevier
DOI: 10.1016/j.coelec.2017.10.001

CO 2 Adsorption in SIFSIX-14-Cu-i: High Performance, Inflected Isotherms, and Water-Triggered Release via Reversible Structural Transformation

Author(s): Debobroto Sensharma, Sebastien Vaesen, Colm Healy, Jens Hartmann, Amal Cherian Kathalikkattil, Paul Wix, Friedrich Steuber, Nianyong Zhu, Wolfgang Schmitt
Published in: European Journal of Inorganic Chemistry, Issue 2018/19, 2018, Page(s) 1993-1997, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.201800217

A Schiff-base cross-linked supramolecular polymer containing diiminophenol compartments and its interaction with copper(II) ions

Author(s): Marcel Klein-Hitpaß, Amy D. Lynes, Chris S. Hawes, Kevin Byrne, Wolfgang Schmitt, Thorfinnur Gunnlaugsson
Published in: Supramolecular Chemistry, Issue 30/2, 2017, Page(s) 93-102, ISSN 1061-0278
Publisher: Taylor & Francis
DOI: 10.1080/10610278.2017.1362108

Multicomponent halide templating: The effect of structure-directing agents on the assembly of molecular and extended coordination compounds

Author(s): Colm Healy, Wolfgang Schmitt
Published in: Coordination Chemistry Reviews, Issue 371, 2018, Page(s) 67-85, ISSN 0010-8545
Publisher: Elsevier BV
DOI: 10.1016/j.ccr.2018.05.014

Framework Isomerism: Highly Augmented Copper(II)-Paddlewheel-Based MOF with Unusual (3,4)-Net Topology

Author(s): Nianyong Zhu, Debobroto Sensharma, Paul Wix, Matthew J. Lennox, Tina Düren, Wai-Yeung Wong, Wolfgang Schmitt
Published in: European Journal of Inorganic Chemistry, Issue 2016/13-14, 2016, Page(s) 1939-1943, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.201501194

Benzene-1,3,5-tricarboxamide n-alkyl ester and carboxylic acid derivatives: tuneable structural, morphological and thermal properties

Author(s): Amy D. Lynes, Chris S. Hawes, Edward N. Ward, Benjamin Haffner, Matthias E. Möbius, Kevin Byrne, Wolfgang Schmitt, Robert Pal, Thorfinnur Gunnlaugsson
Published in: CrystEngComm, Issue 19/10, 2017, Page(s) 1427-1438, ISSN 1466-8033
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7CE00206H

Flexible Porous Coordination Polymers from Divergent Photoluminescent 4-Oxo-1,8-naphthalimide Ligands

Author(s): Chris S. Hawes, Kevin Byrne, Wolfgang Schmitt, Thorfinnur Gunnlaugsson
Published in: Inorganic Chemistry, Issue 55/21, 2016, Page(s) 11570-11582, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.6b02137

Facile adaptation of 1D Mn( ii ) chain motifs to form 3D azo-pyridine-based coordination polymers

Author(s): Ayuk M. Ako, Chris S. Hawes, Brendan Twamley, Wolfgang Schmitt
Published in: CrystEngComm, Issue 19/6, 2017, Page(s) 994-1000, ISSN 1466-8033
Publisher: Royal Society of Chemistry
DOI: 10.1039/C6CE02493A

Anion-directed supramolecular chemistry modulating the magnetic properties of nanoscopic Mn coordination clusters: from polynuclear high-spin complexes to SMMs

Author(s): Lei Zhang, Theresa Chimamkpam, Camelia I. Onet, Nianyong Zhu, Rodolphe Clérac, Wolfgang Schmitt
Published in: Dalton Trans., Issue 45/44, 2016, Page(s) 17705-17713, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/C6DT02642G

Structural variation in cation-assisted assembly of high-nuclearity Mn arsonate and phosphonate wheels

Author(s): Theresa O. Chimamkpam, Rodolphe Clérac, Dmitri Mitcov, Brendan Twamley, Munuswamy Venkatesan, Wolfgang Schmitt
Published in: Dalton Trans., Issue 45/4, 2016, Page(s) 1349-1353, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/C5DT04820F

Bio-inspired synthetic approaches: from hierarchical, hybrid supramolecular assemblies to CaCO 3 -based microspheres

Author(s): Bartosz Marzec, Lei Zhang, Nianyong Zhu, Wolfgang Schmitt
Published in: Dalton Trans., 2017, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7DT00914C

A Mn 13 -cluster based coordination polymer as a co-catalyst of CdS for enhanced visible-light driven H 2 evolution

Author(s): Tian Wen, Lei Zhang, Wolfgang Schmitt
Published in: Dalton Transactions, Issue 47/32, 2018, Page(s) 10857-10860, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8dt01755g

Universal scaling relations for the rational design of molecular water oxidation catalysts with near-zero overpotential

Author(s): Michael John Craig, Gabriel Coulter, Eoin Dolan, Joaquín Soriano-López, Eric Mates-Torres, Wolfgang Schmitt, Max García-Melchor
Published in: Nature Communications, Issue 10/1, 2019, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-019-12994-w

Light-harvesting, 3rd generation Ru II /Co II MOF with a large, tubular channel aperture

Author(s): Luana Martins, Lauren K. Macreadie, Debobroto Sensharma, Sebastien Vaesen, Xia Zhang, John J. Gough, Mariah O'Doherty, Nian-Yong Zhu, Manuel Rüther, John E. O'Brien, A. Louise Bradley, Wolfgang Schmitt
Published in: Chemical Communications, Issue 55/34, 2019, Page(s) 5013-5016, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9cc00206e

Self-assembled bright luminescent hierarchical materials from a tripodal benzoate antenna and heptadentate Eu(III) and Tb(III) cyclen complexes

Author(s): Aramballi J. Savyasachi, David F. Caffrey, Kevin Byrne, Gerard Tobin, Bruno D’Agostino, Wolfgang Schmitt, Thorfinnur Gunnlaugsson
Published in: Frontiers of Chemical Science and Engineering, Issue 13/1, 2019, Page(s) 171-184, ISSN 2095-0179
Publisher: Higher Education Press
DOI: 10.1007/s11705-018-1762-3

Assembly, disassembly and reassembly: a “top-down” synthetic strategy towards hybrid, mixed-metal {Mo 10 Co 6 } POM clusters

Author(s): Colm Healy, Friedrich W. Steuber, Paul Wix, Lauren K. Macreadie, Amal Cherian Kathalikkattil, Wolfgang Schmitt
Published in: Dalton Transactions, Issue 48/9, 2019, Page(s) 3018-3027, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9dt00075e

Synthesis of new Mn 19 analogues and their structural, electrochemical and catalytic properties

Author(s): Elodie Chevallot-Beroux, Ayuk M. Ako, Wolfgang Schmitt, Brendan Twamley, Joseph Moran, Boudon Corinne, Laurent Ruhlmann, Samir Mameri
Published in: Dalton Transactions, Issue 48/15, 2019, Page(s) 4830-4836, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8dt04807j

An Fe( iii )-doped coordination polymer of Mn 13 -clusters with improved activity for the oxygen reduction reaction

Author(s): Tian Wen, Wolfgang Schmitt, Lei Zhang
Published in: Dalton Transactions, Issue 48/15, 2019, Page(s) 4794-4797, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9dt00199a

A highly augmented, (12,3)-connected Zr-MOF containing hydrated coordination sites for the catalytic transformation of gaseous CO 2 to cyclic carbonates

Author(s): Guanghua Jin, Debobroto Sensharma, Nianyong Zhu, Sebastien Vaesen, Wolfgang Schmitt
Published in: Dalton Transactions, Issue 48/41, 2019, Page(s) 15487-15492, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9dt02117e

Passing it up the ranks: hierarchical ion-size dependent supramolecular response in 1D coordination polymers

Author(s): Debobroto Sensharma, Paul Wix, Amal Cherian Kathalikkattil, Wolfgang Schmitt
Published in: CrystEngComm, Issue 20/35, 2018, Page(s) 5127-5131, ISSN 1466-8033
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8ce01211c

Flexible Metal–Organic Frameworks for Light-Switchable CO 2 Sorption Using an Auxiliary Ligand Strategy

Author(s): Debobroto Sensharma, Nianyong Zhu, Swetanshu Tandon, Sebastien Vaesen, Graeme W. Watson, Wolfgang Schmitt
Published in: Inorganic Chemistry, Issue 58/15, 2019, Page(s) 9766-9772, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b00768

Multimodal switching of a redox-active macrocycle

Author(s): Daniel T. Payne, Whitney A. Webre, Yoshitaka Matsushita, Nianyong Zhu, Zdenĕk Futera, Jan Labuta, Wipakorn Jevasuwan, Naoki Fukata, John S. Fossey, Francis D’Souza, Katsuhiko Ariga, Wolfgang Schmitt, Jonathan P. Hill
Published in: Nature Communications, Issue 10/1, 2019, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-019-08978-5

Modulating Structural and Electronic Properties of Rare Archimedean and Johnson-Type Mn Cages

Author(s): Swetanshu Tandon, Friedrich W. Steuber, Amal C. Kathalikkattil, Munuswamy Venkatesan, Graeme W. Watson, and Wolfgang Schmitt*
Published in: Inorganic Chemistry, 2021, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.1c00984

Bioinspired Water Oxidation Using a Mn-Oxo Cluster Stabilized by Non-Innocent Organic Tyrosine Y161 and Plastoquinone Mimics

Author(s): Joaquín Soriano-López, Rory Elliott, Amal C. Kathalikkattil, Ayuk M. Ako, Muhamed Mulahmetović, Munuswamy Venkatesan, and Wolfgang Schmitt
Published in: ACS Sustainable Chemistry and Engineering., 2020, ISSN 2168-0485
Publisher: American Chemical Society
DOI: 10.1021/acssuschemeng.0c03379

Node-Dependent Photoinduced Electron Transfer in Third-Generation 2D MOFs Containing Earth-Abundant Metal Ions,

Author(s): Friedrich W Steuber, John J Gough, Éadaoin Whelan, Lyubomyr Burtnyak, A Louise Bradley, Wolfgang Schmitt,
Published in: Inorganic Chemistry, 2020, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c02475

2D Porphyrinic Metal-Organic Frameworks Featuring Rod-Shaped Secondary Building Units

Author(s): Rory Elliott, Aoife A. Ryan,Aviral Aggarwal, Nianyong Zhu, Friedrich W. Steuber ,Mathias O. Senge Wolfgang Schmitt
Published in: Molecules, 2021, ISSN 1420-3049
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/molecules26102955

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