Towards a Greener Reduction Chemistry by Using Cobalt Coordination Complexes as Catalysts and Light-driven Water Reduction as a Source of Reductive Equivalents

Project Information

GREENLIGHT_REDCAT

Grant agreement ID: 648304

DOI

10.3030/648304

Project closed

EC signature date 11 June 2015

Start date 1 July 2015

End date 31 December 2020

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 999 063,00

EU contribution

€ 1 999 063,00

Coordinated by

FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA
Spain

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Publications

Peer reviewed articles (12)

Crystal‐to‐Crystal Synthesis of Photocatalytic Metal–Organic Frameworks for Visible‐Light Reductive Coupling and Mechanistic Investigations

Author(s): Luis Gutiérrez, Suvendu Sekhar Mondal, Alberto Bucci, Noufal Kandoth, Eduardo C. Escudero‐Adán, Alexandr Shafir, Julio Lloret‐Fillol
Published in: ChemSusChem, Issue 13/13, 2020, Page(s) 3418-3428, ISSN 1864-5631
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/cssc.202000465

A Highly Active N-heterocyclic Carbene MnI complex for Selective Electrocatalytic CO2 Reduction to CO

Author(s): Julio Lloret-Fillol, Federico Franco, Mara F. Pinto, Beatriz Royo
Published in: Angewandte Chemie International Edition, 2018, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201800705

Bioinspired Electro-Organocatalytic Material Efficient for Hydrogen Production

Author(s): Octavio González-del Moral, Arnau Call, Federico Franco, Alicia Moya, Jose Antonio Nieto-Rodríguez, María Frias, Jose L. G. Fierro, Miquel Costas, Julio Lloret-Fillol, José Alemán, Rubén Mas-Ballesté
Published in: Chemistry - A European Journal, 2018, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201705655

Understanding light-driven H 2 evolution through the electronic tuning of aminopyridine cobalt complexes

Author(s): Arnau Call, Federico Franco, Noufal Kandoth, Sergio Fernández, María González-Béjar, Julia Pérez-Prieto, Josep M. Luis, Julio Lloret-Fillol
Published in: Chemical Science, 2018, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7SC04328G

Synthesis and Reactivity of Copper(I) Complexes Based on C 3 -Symmetric Tripodal HTIM(PR 2 ) 3 Ligands

Author(s): Ekaterina S. Smirnova, Ferran Acuña-Parés, Eduardo C. Escudero-Adán, Christian Jelsch, Julio Lloret-Fillol
Published in: European Journal of Inorganic Chemistry, Issue 2018/23, 2018, Page(s) 2612-2620, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.201800074

Design of Iron Coordination Complexes as Highly Active Homogenous Water Oxidation Catalysts by Deuteration of Oxidation-Sensitive Sites

Author(s): Zoel Codolà, Ilaria Gamba, Ferran Acuña-Parés, Carla Casadevall, Martin Clémancey, Jean-Marc Latour, Josep M. Luis, Julio Lloret-Fillol, Miquel Costas
Published in: Journal of the American Chemical Society, Issue 141/1, 2018, Page(s) 323-333, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.8b10211

A Unified Electro- and Photocatalytic CO 2 to CO Reduction Mechanism with Aminopyridine Cobalt Complexes

Author(s): Sergio Fernández, Federico Franco, Carla Casadevall, Vlad Martin-Diaconescu, Josep M. Luis, Julio Lloret-Fillol
Published in: Journal of the American Chemical Society, Issue 142/1, 2019, Page(s) 120-133, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.9b06633

Cobalt Amide Imidate Imidazolate Frameworks as Highly Active Oxygen Evolution Model Materials

Author(s): Alberto Bucci, Suvendu Sekhar Mondal, Vlad Martin-Diaconescu, Alexandr Shafir, Julio Lloret-Fillol
Published in: ACS Applied Energy Materials, Issue 2/12, 2019, Page(s) 8930-8938, ISSN 2574-0962
Publisher: ACS Publisher
DOI: 10.1021/acsaem.9b01977

Reductive Cyclization of Unactivated Alkyl Chlorides with Tethered Alkenes under Visible-Light Photoredox Catalysis

Author(s): Miguel Claros, Felix Ungeheuer, Federico Franco, Vlad Martin-Diaconescu, Alicia Casitas, Julio Lloret-Fillol
Published in: Angewandte Chemie International Edition, Issue 58/15, 2019, Page(s) 4869-4874, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201812702

Improved Electro- and Photocatalytic Water Reduction by Confined Cobalt Catalysts in Streptavidin

Author(s): Arnau Call, Carla Casadevall, Adrian Romero-Rivera, Vlad Martin-Diaconescu, Dayn J. Sommer, Sílvia Osuna, Giovanna Ghirlanda, Julio Lloret-Fillol
Published in: ACS Catalysis, Issue 9/7, 2019, Page(s) 5837-5846, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.8b04981

Enhancement and control of the selectivity in light-driven ketone versus water reduction using aminopyridine cobalt complexes

Author(s): Arnau Call, Julio Lloret-Fillol
Published in: Chemical Communications, Issue 54/69, 2018, Page(s) 9643-9646, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8cc04239j

Dual cobalt–copper light-driven catalytic reduction of aldehydes and aromatic ketones in aqueous media

Author(s): Arnau Call, Carla Casadevall, Ferran Acuña-Parés, Alicia Casitas, Julio Lloret-Fillol
Published in: Chem. Sci., Issue 8/7, 2017, Page(s) 4739-4749, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7SC01276D

Intellectual Property Rights

Patent (3)

PHOTOREACTOR

Application/Publication number: 17 382313
Date: 2017-05-31
Applicant(s): FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA

PROCEDURE FOR THE ACTIVATION OF ORGANIC CHLORIDE COMPOUNDS AND A CATALYTIC COMPOSITION USED IN THE PROCESS

Application/Publication number: 18 382332
Date: 2018-05-15
Applicant(s): FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA

A photocatalytic reduction process and a catalytic composition used in the process

Application/Publication number: PCT/ES2017/ 070314
Date: 2017-05-16
Applicant(s): FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA