Enantioselective Light-induced Catalysis for Organic Synthesis

Project Information

ELICOS

Grant agreement ID: 665951

DOI 10.3030/665951

Project closed

EC signature date 11 June 2015

Start date 1 January 2016

End date 31 December 2020

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 2 357 901,00

EU contribution € 2 357 901,00

Coordinated by

TECHNISCHE UNIVERSITAET MUENCHEN
Germany

Publications

Peer reviewed articles (21)

Chiral 1,3,2-Oxazaborolidine Catalysts for Enantioselective Photochemical Reactions

Author(s): Daniel P. Schwinger, Thorsten Bach
Published in: Accounts of Chemical Research, Issue 53/9, 2020, Page(s) 1933-1943, ISSN 0001-4842
Publisher: American Chemical Society
DOI: 10.1021/acs.accounts.0c00379

Visible Light-Mediated Photochemical Reactions of 2-(2′-Alkenyloxy)cycloalk-2-enones

Author(s): Raphaela Graßl, Christian Jandl, Thorsten Bach
Published in: The Journal of Organic Chemistry, Issue 85/17, 2020, Page(s) 11426-11439, ISSN 0022-3263
Publisher: American Chemical Society
DOI: 10.1021/acs.joc.0c01501

Evidence for Triplet Sensitization in the Visible-Light-Induced [2+2] Photocycloaddition of Eniminium Ions

Author(s): Fabian M. Hörmann, Tim S. Chung, Elsa Rodriguez, Matthias Jakob, Thorsten Bach
Published in: Angewandte Chemie International Edition, Issue 57/3, 2018, Page(s) 827-831, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201710441

Iminium and enamine catalysis in enantioselective photochemical reactions

Author(s): You-Quan Zou, Fabian M. Hörmann, Thorsten Bach
Published in: Chemical Society Reviews, Issue 47/2, 2018, Page(s) 278-290, ISSN 0306-0012
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7cs00509a

Synthesis of Chiral Thiourea-Thioxanthone Hybrids

Author(s): Thorsten Bach, Florian Mayr, Lisa-Marie Mohr, Elsa Rodriguez
Published in: Synthesis, Issue 49/23, 2017, Page(s) 5238-5250, ISSN 0039-7881
Publisher: Georg Thieme Verlag
DOI: 10.1055/s-0036-1590931

Chromophore Activation of α,β-Unsaturated Carbonyl Compounds and Its Application to Enantioselective Photochemical Reactions

Author(s): Christoph Brenninger, John D. Jolliffe, Thorsten Bach
Published in: Angewandte Chemie International Edition, Issue 57/44, 2018, Page(s) 14338-14349, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201804006

Intermolecular [2+2] Photocycloaddition of β-Nitrostyrenes to Olefins upon Irradiation with Visible Light

Author(s): Thorsten Bach, Lisa-Marie Mohr
Published in: Synlett, Issue 28/20, 2017, Page(s) 2946-2950, ISSN 0936-5214
Publisher: Georg Thieme Verlag
DOI: 10.1055/s-0036-1588524

Enantioselective Intermolecular [2+2] Photocycloaddition Reaction of Cyclic Enones and Its Application in a Synthesis of (−)-Grandisol

Author(s): Saner Poplata, Thorsten Bach
Published in: Journal of the American Chemical Society, Issue 140/9, 2018, Page(s) 3228-3231, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.8b01011

α-Thio Carbocations (Thionium Ions) as Intermediates in Brønsted Acid-Catalyzed Reactions of Enone-Derived 1,3-Dithianes and 1,3-Dithiolanes

Author(s): Christoph Brenninger, Thorsten Bach
Published in: Topics in Catalysis, Issue 61/7-8, 2018, Page(s) 623-629, ISSN 1022-5528
Publisher: Baltzer Science Publishers B.V.
DOI: 10.1007/s11244-018-0905-6

[6π] Photocyclization to cis -Hexahydrocarbazol-4-ones: Substrate Modification, Mechanism, and Scope

Author(s): Sachin G. Modha, Alexander Pöthig, Andreas Dreuw, Thorsten Bach
Published in: The Journal of Organic Chemistry, Issue 84/3, 2018, Page(s) 1139-1153, ISSN 0022-3263
Publisher: American Chemical Society
DOI: 10.1021/acs.joc.8b03144

Enantioselective Lewis Acid Catalyzed ortho Photocycloaddition of Olefins to Phenanthrene-9-carboxaldehydes

Author(s): Simone Stegbauer, Christian Jandl, Thorsten Bach
Published in: Angewandte Chemie International Edition, Issue 57/44, 2018, Page(s) 14593-14596, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201808919

Recent Advances in the Synthesis of Cyclobutanes by Olefin [2 + 2] Photocycloaddition Reactions

Author(s): Saner Poplata, Andreas Tröster, You-Quan Zou, Thorsten Bach
Published in: Chemical Reviews, Issue 116/17, 2016, Page(s) 9748-9815, ISSN 0009-2665
Publisher: American Chemical Society
DOI: 10.1021/acs.chemrev.5b00723

A Chiral Thiourea as a Template for Enantioselective Intramolecular [2 + 2] Photocycloaddition Reactions

Author(s): Florian Mayr, Richard Brimioulle, Thorsten Bach
Published in: The Journal of Organic Chemistry, Issue 81/16, 2016, Page(s) 6965-6971, ISSN 0022-3263
Publisher: American Chemical Society
DOI: 10.1021/acs.joc.6b01039

Brønsted Acid Catalysis in Visible-Light-Induced [2+2] Photocycloaddition Reactions of Enone Dithianes

Author(s): Christoph Brenninger, Alexander Pöthig, Thorsten Bach
Published in: Angewandte Chemie International Edition, Issue 56/15, 2017, Page(s) 4337-4341, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201700837

Enantioselective photocyclisation reactions of 2-aryloxycyclohex-2-enones mediated by a chiral copper-bisoxazoline complex

Author(s): Verena Edtmüller, Alexander Pöthig, Thorsten Bach
Published in: Tetrahedron, Issue 73/33, 2017, Page(s) 5037-5048, ISSN 0040-4020
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.tet.2017.05.005

Intramolecular [2+2] Photocycloaddition of Cyclic Enones: Selectivity Control by Lewis Acids and Mechanistic Implications

Author(s): Saner Poplata, Andreas Bauer, Golo Storch, Thorsten Bach
Published in: Chemistry – A European Journal, Issue 25/34, 2019, Page(s) 8135-8148, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201901304

Visible light-mediated intermolecular [2 + 2] photocycloaddition of 1-aryl-2-nitroethenes and olefins

Author(s): Lisa-Marie Mohr, Andreas Bauer, Christian Jandl, Thorsten Bach
Published in: Organic & Biomolecular Chemistry, Issue 17/30, 2019, Page(s) 7192-7203, ISSN 1477-0520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9ob01146c

Reversal of reaction type selectivity by Lewis acid coordination: the ortho photocycloaddition of 1- and 2-naphthaldehyde

Author(s): Simone Stegbauer, Noah Jeremias, Christian Jandl, Thorsten Bach
Published in: Chemical Science, Issue 10/37, 2019, Page(s) 8566-8570, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9sc03315g

Lewis Acid Catalyzed Enantioselective Photochemical Rearrangements on the Singlet Potential Energy Surface

Author(s): Malte Leverenz, Christian Merten, Andreas Dreuw, Thorsten Bach
Published in: Journal of the American Chemical Society, Issue 141/51, 2019, Page(s) 20053-20057, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.9b12068

A Thioxanthone Sensitizer with a Chiral Phosphoric Acid Binding Site: Properties and Applications in Visible Light‐Mediated Cycloadditions

Author(s): Franziska Pecho, You‐Quan Zou, Johannes Gramüller, Tadashi Mori, Stefan M. Huber, Andreas Bauer, Ruth M. Gschwind, Thorsten Bach
Published in: Chemistry – A European Journal, Issue 26/23, 2020, Page(s) 5190-5194, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202000720

Triplet Energy Transfer from Ruthenium Complexes to Chiral Eniminium Ions: Enantioselective Synthesis of Cyclobutanecarbaldehydes by [2+2] Photocycloaddition

Author(s): Fabian M. Hörmann, Christoph Kerzig, Tim S. Chung, Andreas Bauer, Oliver S. Wenger, Thorsten Bach
Published in: Angewandte Chemie International Edition, Issue 59/24, 2020, Page(s) 9659-9668, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202001634