Enantioselective Light-induced Catalysis for Organic Synthesis

Informazioni relative al progetto

ELICOS

ID dell’accordo di sovvenzione: 665951

DOI 10.3030/665951

Progetto chiuso

Data della firma CE 11 Giugno 2015

Data di avvio 1 Gennaio 2016

Data di completamento 31 Dicembre 2020

Finanziato da

• EXCELLENT SCIENCE - European Research Council (ERC)

Costo totale € 2 357 901,00

Contributo UE € 2 357 901,00

Coordinato da

TECHNISCHE UNIVERSITAET MUENCHEN
Germany

Pubblicazioni

Peer reviewed articles (21)

Chiral 1,3,2-Oxazaborolidine Catalysts for Enantioselective Photochemical Reactions

Autori: Daniel P. Schwinger, Thorsten Bach
Pubblicato in: Accounts of Chemical Research, Numero 53/9, 2020, Pagina/e 1933-1943, ISSN 0001-4842
Editore: American Chemical Society
DOI: 10.1021/acs.accounts.0c00379

Visible Light-Mediated Photochemical Reactions of 2-(2′-Alkenyloxy)cycloalk-2-enones

Autori: Raphaela Graßl, Christian Jandl, Thorsten Bach
Pubblicato in: The Journal of Organic Chemistry, Numero 85/17, 2020, Pagina/e 11426-11439, ISSN 0022-3263
Editore: American Chemical Society
DOI: 10.1021/acs.joc.0c01501

Evidence for Triplet Sensitization in the Visible-Light-Induced [2+2] Photocycloaddition of Eniminium Ions

Autori: Fabian M. Hörmann, Tim S. Chung, Elsa Rodriguez, Matthias Jakob, Thorsten Bach
Pubblicato in: Angewandte Chemie International Edition, Numero 57/3, 2018, Pagina/e 827-831, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201710441

Iminium and enamine catalysis in enantioselective photochemical reactions

Autori: You-Quan Zou, Fabian M. Hörmann, Thorsten Bach
Pubblicato in: Chemical Society Reviews, Numero 47/2, 2018, Pagina/e 278-290, ISSN 0306-0012
Editore: Royal Society of Chemistry
DOI: 10.1039/c7cs00509a

Synthesis of Chiral Thiourea-Thioxanthone Hybrids

Autori: Thorsten Bach, Florian Mayr, Lisa-Marie Mohr, Elsa Rodriguez
Pubblicato in: Synthesis, Numero 49/23, 2017, Pagina/e 5238-5250, ISSN 0039-7881
Editore: Georg Thieme Verlag
DOI: 10.1055/s-0036-1590931

Chromophore Activation of α,β-Unsaturated Carbonyl Compounds and Its Application to Enantioselective Photochemical Reactions

Autori: Christoph Brenninger, John D. Jolliffe, Thorsten Bach
Pubblicato in: Angewandte Chemie International Edition, Numero 57/44, 2018, Pagina/e 14338-14349, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201804006

Intermolecular [2+2] Photocycloaddition of β-Nitrostyrenes to Olefins upon Irradiation with Visible Light

Autori: Thorsten Bach, Lisa-Marie Mohr
Pubblicato in: Synlett, Numero 28/20, 2017, Pagina/e 2946-2950, ISSN 0936-5214
Editore: Georg Thieme Verlag
DOI: 10.1055/s-0036-1588524

Enantioselective Intermolecular [2+2] Photocycloaddition Reaction of Cyclic Enones and Its Application in a Synthesis of (−)-Grandisol

Autori: Saner Poplata, Thorsten Bach
Pubblicato in: Journal of the American Chemical Society, Numero 140/9, 2018, Pagina/e 3228-3231, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.8b01011

α-Thio Carbocations (Thionium Ions) as Intermediates in Brønsted Acid-Catalyzed Reactions of Enone-Derived 1,3-Dithianes and 1,3-Dithiolanes

Autori: Christoph Brenninger, Thorsten Bach
Pubblicato in: Topics in Catalysis, Numero 61/7-8, 2018, Pagina/e 623-629, ISSN 1022-5528
Editore: Baltzer Science Publishers B.V.
DOI: 10.1007/s11244-018-0905-6

[6π] Photocyclization to cis -Hexahydrocarbazol-4-ones: Substrate Modification, Mechanism, and Scope

Autori: Sachin G. Modha, Alexander Pöthig, Andreas Dreuw, Thorsten Bach
Pubblicato in: The Journal of Organic Chemistry, Numero 84/3, 2018, Pagina/e 1139-1153, ISSN 0022-3263
Editore: American Chemical Society
DOI: 10.1021/acs.joc.8b03144

Enantioselective Lewis Acid Catalyzed ortho Photocycloaddition of Olefins to Phenanthrene-9-carboxaldehydes

Autori: Simone Stegbauer, Christian Jandl, Thorsten Bach
Pubblicato in: Angewandte Chemie International Edition, Numero 57/44, 2018, Pagina/e 14593-14596, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201808919

Recent Advances in the Synthesis of Cyclobutanes by Olefin [2 + 2] Photocycloaddition Reactions

Autori: Saner Poplata, Andreas Tröster, You-Quan Zou, Thorsten Bach
Pubblicato in: Chemical Reviews, Numero 116/17, 2016, Pagina/e 9748-9815, ISSN 0009-2665
Editore: American Chemical Society
DOI: 10.1021/acs.chemrev.5b00723

A Chiral Thiourea as a Template for Enantioselective Intramolecular [2 + 2] Photocycloaddition Reactions

Autori: Florian Mayr, Richard Brimioulle, Thorsten Bach
Pubblicato in: The Journal of Organic Chemistry, Numero 81/16, 2016, Pagina/e 6965-6971, ISSN 0022-3263
Editore: American Chemical Society
DOI: 10.1021/acs.joc.6b01039

Brønsted Acid Catalysis in Visible-Light-Induced [2+2] Photocycloaddition Reactions of Enone Dithianes

Autori: Christoph Brenninger, Alexander Pöthig, Thorsten Bach
Pubblicato in: Angewandte Chemie International Edition, Numero 56/15, 2017, Pagina/e 4337-4341, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201700837

Enantioselective photocyclisation reactions of 2-aryloxycyclohex-2-enones mediated by a chiral copper-bisoxazoline complex

Autori: Verena Edtmüller, Alexander Pöthig, Thorsten Bach
Pubblicato in: Tetrahedron, Numero 73/33, 2017, Pagina/e 5037-5048, ISSN 0040-4020
Editore: Pergamon Press Ltd.
DOI: 10.1016/j.tet.2017.05.005

Intramolecular [2+2] Photocycloaddition of Cyclic Enones: Selectivity Control by Lewis Acids and Mechanistic Implications

Autori: Saner Poplata, Andreas Bauer, Golo Storch, Thorsten Bach
Pubblicato in: Chemistry – A European Journal, Numero 25/34, 2019, Pagina/e 8135-8148, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201901304

Visible light-mediated intermolecular [2 + 2] photocycloaddition of 1-aryl-2-nitroethenes and olefins

Autori: Lisa-Marie Mohr, Andreas Bauer, Christian Jandl, Thorsten Bach
Pubblicato in: Organic & Biomolecular Chemistry, Numero 17/30, 2019, Pagina/e 7192-7203, ISSN 1477-0520
Editore: Royal Society of Chemistry
DOI: 10.1039/c9ob01146c

Reversal of reaction type selectivity by Lewis acid coordination: the ortho photocycloaddition of 1- and 2-naphthaldehyde

Autori: Simone Stegbauer, Noah Jeremias, Christian Jandl, Thorsten Bach
Pubblicato in: Chemical Science, Numero 10/37, 2019, Pagina/e 8566-8570, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/c9sc03315g

Lewis Acid Catalyzed Enantioselective Photochemical Rearrangements on the Singlet Potential Energy Surface

Autori: Malte Leverenz, Christian Merten, Andreas Dreuw, Thorsten Bach
Pubblicato in: Journal of the American Chemical Society, Numero 141/51, 2019, Pagina/e 20053-20057, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.9b12068

A Thioxanthone Sensitizer with a Chiral Phosphoric Acid Binding Site: Properties and Applications in Visible Light‐Mediated Cycloadditions

Autori: Franziska Pecho, You‐Quan Zou, Johannes Gramüller, Tadashi Mori, Stefan M. Huber, Andreas Bauer, Ruth M. Gschwind, Thorsten Bach
Pubblicato in: Chemistry – A European Journal, Numero 26/23, 2020, Pagina/e 5190-5194, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202000720

Triplet Energy Transfer from Ruthenium Complexes to Chiral Eniminium Ions: Enantioselective Synthesis of Cyclobutanecarbaldehydes by [2+2] Photocycloaddition

Autori: Fabian M. Hörmann, Christoph Kerzig, Tim S. Chung, Andreas Bauer, Oliver S. Wenger, Thorsten Bach
Pubblicato in: Angewandte Chemie International Edition, Numero 59/24, 2020, Pagina/e 9659-9668, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202001634