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Development of Molecular-defined Non-noble Metal Complexes and Nano-structured Materials for Sustainable Redox Reactions Development of Molecular-defined Non-noble Metal Complexes and Nano-structured

Publications

MOF-derived cobalt nanoparticles catalyze a general synthesis of amines

Author(s): Rajenahally V. Jagadeesh, Kathiravan Murugesan, Ahmad S. Alshammari, Helfried Neumann, Marga-Martina Pohl, Jörg Radnik, Matthias Beller
Published in: Science, 358/6361, 2017, Page(s) 326-332, ISSN 0036-8075
Publisher: American Association for the Advancement of Science
DOI: 10.1126/science.aan6245

Hydrogenation of Pyridines Using a Nitrogen-Modified Titania-Supported Cobalt Catalyst

Author(s): Feng Chen, Wu Li, Basudev Sahoo, Carsten Kreyenschulte, Giovanni Agostini, Henrik Lund, Kathrin Junge, Matthias Beller
Published in: Angewandte Chemie International Edition, 57/44, 2018, Page(s) 14488-14492, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201803426

Simple ruthenium-catalyzed reductive amination enables the synthesis of a broad range of primary amines

Author(s): Thirusangumurugan Senthamarai, Kathiravan Murugesan, Jacob Schneidewind, Narayana V. Kalevaru, Wolfgang Baumann, Helfried Neumann, Paul C. J. Kamer, Matthias Beller, Rajenahally V. Jagadeesh
Published in: Nature Communications, 9/1, 2018, Page(s) 4123, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-018-06416-6

Homogeneous Catalysis by Manganese-Based Pincer Complexes

Author(s): Marcel Garbe, Kathrin Junge, Matthias Beller
Published in: European Journal of Organic Chemistry, 2017/30, 2017, Page(s) 4344-4362, ISSN 1434-193X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejoc.201700376

Molecular Defined Molybdenum–Pincer Complexes and Their Application in Catalytic Hydrogenations

Author(s): Thomas Leischner, Anke Spannenberg, Kathrin Junge, Matthias Beller
Published in: Organometallics, 37/23, 2018, Page(s) 4402-4408, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.8b00410

Cobalt-based nanoparticles prepared from MOF–carbon templates as efficient hydrogenation catalysts

Author(s): Kathiravan Murugesan, Thirusangumurugan Senthamarai, Manzar Sohail, Ahmad S. Alshammari, Marga-Martina Pohl, Matthias Beller, Rajenahally V. Jagadeesh
Published in: Chemical Science, 9/45, 2018, Page(s) 8553-8560, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8sc02807a

Tailored Cobalt-Catalysts for Reductive Alkylation of Anilines with Carboxylic Acids under Mild Conditions

Author(s): Weiping Liu, Basudev Sahoo, Anke Spannenberg, Kathrin Junge, Matthias Beller
Published in: Angewandte Chemie International Edition, 57/36, 2018, Page(s) 11673-11677, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201806132

Expedient Synthesis of N -Methyl- and N -Alkylamines by Reductive Amination using Reusable Cobalt Oxide Nanoparticles

Author(s): Thirusangumurugan Senthamarai, Kathiravan Murugesan, Kishore Natte, Narayana V. Kalevaru, Helfried Neumann, Paul C. J. Kamer, Rajenahally V. Jagadeesh
Published in: ChemCatChem, 10/6, 2018, Page(s) 1235-1240, ISSN 1867-3880
Publisher: Wiley - VCH Verlag GmbH & CO. KGaA
DOI: 10.1002/cctc.201701617

Stable and reusable nanoscale Fe 2 O 3 -catalyzed aerobic oxidation process for the selective synthesis of nitriles and primary amides

Author(s): Kathiravan Murugesan, Thirusangumurugan Senthamarai, Manzar Sohail, Muhammad Sharif, Narayana V. Kalevaru, Rajenahally V. Jagadeesh
Published in: Green Chemistry, 20/1, 2018, Page(s) 266-273, ISSN 1463-9262
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7gc02627g

Monodisperse nickel-nanoparticles for stereo- and chemoselective hydrogenation of alkynes to alkenes

Author(s): Kathiravan Murugesan, Ahmad S. Alshammari, Manzar Sohail, Matthias Beller, Rajenahally V. Jagadeesh
Published in: Journal of Catalysis, 370, 2019, Page(s) 372-377, ISSN 0021-9517
Publisher: Academic Press
DOI: 10.1016/j.jcat.2018.12.018

Cobalt–Pincer Complexes in Catalysis

Author(s): Kathrin Junge, Veronica Papa, Matthias Beller
Published in: Chemistry – A European Journal, 25/1, 2018, Page(s) 122-143, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201803016

Reduction of Nitro Compounds Using 3d-Non-Noble Metal Catalysts

Author(s): Dario Formenti, Francesco Ferretti, Florian Korbinian Scharnagl, Matthias Beller
Published in: Chemical Reviews, 119/4, 2018, Page(s) 2611-2680, ISSN 0009-2665
Publisher: American Chemical Society
DOI: 10.1021/acs.chemrev.8b00547

Supported Cobalt Nanoparticles for Hydroformylation Reactions

Author(s): Maximilian Franz Hertrich, Florian Korbinian Scharnagl, Anahit Pews‐Davtyan, Carsten Robert Kreyenschulte, Henrik Lund, Stephan Bartling, Ralf Jackstell, Matthias Beller
Published in: Chemistry – A European Journal, 25/21, 2019, Page(s) 5534-5538, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201806282

Reusable Nickel Nanoparticles‐Catalyzed Reductive Amination for Selective Synthesis of Primary Amines

Author(s): Kathiravan Murugesan, Matthias Beller, Rajenahally V. Jagadeesh
Published in: Angewandte Chemie International Edition, 58/15, 2019, Page(s) 5064-5068, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201812100

Iron-catalysed regioselective hydrogenation of terminal epoxides to alcohols under mild conditions

Author(s): Weiping Liu, Wu Li, Anke Spannenberg, Kathrin Junge, Matthias Beller
Published in: Nature Catalysis, 2/6, 2019, Page(s) 523-528, ISSN 2520-1158
Publisher: Nature catalysis
DOI: 10.1038/s41929-019-0286-7

Nickel‐Catalyzed Stereodivergent Synthesis of E ‐ and Z ‐Alkenes by Hydrogenation of Alkynes

Author(s): Kathiravan Murugesan, Charles Beromeo Bheeter, Pim R. Linnebank, Anke Spannenberg, Joost N. H. Reek, Rajenahally V. Jagadeesh, Matthias Beller
Published in: ChemSusChem, 12/14, 2019, Page(s) 3363-3369, ISSN 1864-5631
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/cssc.201900784

Cobalt-Nanoparticles Catalyzed Efficient and Selective Hydrogenation of Aromatic Hydrocarbons

Author(s): Kathiravan Murugesan, Thirusangumurugan Senthamarai, Ahmad S. Alshammari, Rashid M. Altamimi, Carsten Kreyenschulte, Marga-Martina Pohl, Henrik Lund, Rajenahally V. Jagadeesh, Matthias Beller
Published in: ACS Catalysis, 9/9, 2019, Page(s) 8581-8591, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.9b02193

Levulinic Acid Derived Reusable Cobalt-Nanoparticles-Catalyzed Sustainable Synthesis of γ-Valerolactone

Author(s): Kathiravan Murugesan, Ahmad S. Alshammari, Manzar Sohail, Rajenahally V. Jagadeesh
Published in: ACS Sustainable Chemistry & Engineering, 7/17, 2019, Page(s) 14756-14764, ISSN 2168-0485
Publisher: American Chemical Society
DOI: 10.1021/acssuschemeng.9b02692

Molecularly Defined Manganese Catalyst for Low-Temperature Hydrogenation of Carbon Monoxide to Methanol

Author(s): Pavel Ryabchuk, Kenta Stier, Kathrin Junge, Marek P. Checinski, Matthias Beller
Published in: Journal of the American Chemical Society, 141/42, 2019, Page(s) 16923-16929, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.9b08990

Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines

Author(s): Kathiravan Murugesan, Zhihong Wei, Vishwas G. Chandrashekhar, Helfried Neumann, Anke Spannenberg, Haijun Jiao, Matthias Beller, Rajenahally V. Jagadeesh
Published in: Nature Communications, 10/1, 2019, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-019-13351-7

Ultra-small cobalt nanoparticles from molecularly-defined Co–salen complexes for catalytic synthesis of amines

Author(s): Thirusangumurugan Senthamarai, Vishwas G. Chandrashekhar, Manoj B. Gawande, Narayana V. Kalevaru, Radek Zbořil, Paul C. J. Kamer, Rajenahally V. Jagadeesh, Matthias Beller
Published in: Chemical Science, 11/11, 2020, Page(s) 2973-2981, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9sc04963k

Cyclometalated Ruthenium Pincer Complexes as Catalysts for the α‐Alkylation of Ketones with Alcohols

Author(s): Patrick Piehl, Roberta Amuso, Elisabetta Alberico, Henrik Junge, Bartolo Gabriele, Helfried Neumann, Matthias Beller
Published in: Chemistry – A European Journal, 26/27, 2020, Page(s) 6050-6055, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202000396

General and selective synthesis of primary amines using Ni-based homogeneous catalysts

Author(s): Kathiravan Murugesan, Zhihong Wei, Vishwas G. Chandrashekhar, Haijun Jiao, Matthias Beller, Rajenahally V. Jagadeesh
Published in: Chemical Science, 11/17, 2020, Page(s) 4332-4339, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0sc01084g

Reductive amination using cobalt-based nanoparticles for synthesis of amines

Author(s): Kathiravan Murugesan, Vishwas G. Chandrashekhar, Thirusangumurugan Senthamarai, Rajenahally V. Jagadeesh, Matthias Beller
Published in: Nature Protocols, 15/4, 2020, Page(s) 1313-1337, ISSN 1754-2189
Publisher: Nature Publishing Group
DOI: 10.1038/s41596-019-0258-z

Synthesis of Single Atom Based Heterogeneous Platinum Catalysts: High Selectivity and Activity for Hydrosilylation Reactions

Author(s): Xinjiang Cui, Kathrin Junge, Xingchao Dai, Carsten Kreyenschulte, Marga-Martina Pohl, Sebastian Wohlrab, Feng Shi, Angelika Brückner, Matthias Beller
Published in: ACS Central Science, 3/6, 2017, Page(s) 580-585, ISSN 2374-7943
Publisher: American Chemical Society
DOI: 10.1021/acscentsci.7b00105

Intermetallic nickel silicide nanocatalyst—A non-noble metal–based general hydrogenation catalyst

Author(s): Pavel Ryabchuk, Giovanni Agostini, Marga-Martina Pohl, Henrik Lund, Anastasiya Agapova, Henrik Junge, Kathrin Junge, Matthias Beller
Published in: Science Advances, 4/6, 2018, Page(s) eaat0761, ISSN 2375-2548
Publisher: Sciencemag
DOI: 10.1126/sciadv.aat0761

Bridging homogeneous and heterogeneous catalysis by heterogeneous single-metal-site catalysts

Author(s): Xinjiang Cui, Wu Li, Pavel Ryabchuk, Kathrin Junge, Matthias Beller
Published in: Nature Catalysis, 1/6, 2018, Page(s) 385-397, ISSN 2520-1158
Publisher: Springer
DOI: 10.1038/s41929-018-0090-9

Datasets

CCDC 1822578: Experimental Crystal Structure Determination

Author(s): Liu, Weiping; Sahoo, Basudev; Spannenberg, Anke; Junge, Kathrin; Beller, Matthias
Published in: Cambridge Crystallographic Data Centre

CCDC 1895727: Experimental Crystal Structure Determination

Author(s): Liu, Weiping; Li, Wu; Spannenberg, Anke; Junge, Kathrin; Beller, Matthias
Published in: Cambridge Crystallographic Data Centre

CCDC 1897492: Experimental Crystal Structure Determination

Author(s): Murugesan, Kathiravan; Wei, Zhihong; Chandrashekhar, Vishwas G.; Neumann, Helfried; Spannenberg, Anke; Jiao, Haijun; Beller, Matthias; Jagadeesh, Rajenahally V.
Published in: Cambridge Crystallographic Data Centre

CCDC 1895730: Experimental Crystal Structure Determination

Author(s): Liu, Weiping; Li, Wu; Spannenberg, Anke; Junge, Kathrin; Beller, Matthias
Published in: Cambridge Crystallographic Data Centre

CCDC 1847005: Experimental Crystal Structure Determination

Author(s): Leischner, Thomas; Spannenberg, Anke; Junge, Kathrin; Beller, Matthias
Published in: Cambridge Crystallographic Data Centre

CCDC 1847003: Experimental Crystal Structure Determination

Author(s): Leischner, Thomas; Spannenberg, Anke; Junge, Kathrin; Beller, Matthias
Published in: Cambridge Crystallographic Data Centre

CCDC 1895728: Experimental Crystal Structure Determination

Author(s): Liu, Weiping; Li, Wu; Spannenberg, Anke; Junge, Kathrin; Beller, Matthias
Published in: Cambridge Crystallographic Data Centre

CCDC 1961437: Experimental Crystal Structure Determination

Author(s): Piehl, Patrick; Amuso, Roberta; Alberico, Elisabetta; Junge, Henrik; Gabriele, Bartolo; Neumann, Helfried; Beller, Matthias
Published in: Cambridge Crystallographic Data Centre

CCDC 1895726: Experimental Crystal Structure Determination

Author(s): Liu, Weiping; Li, Wu; Spannenberg, Anke; Junge, Kathrin; Beller, Matthias
Published in: Cambridge Crystallographic Data Centre

CCDC 1961436: Experimental Crystal Structure Determination

Author(s): Piehl, Patrick; Amuso, Roberta; Alberico, Elisabetta; Junge, Henrik; Gabriele, Bartolo; Neumann, Helfried; Beller, Matthias
Published in: Cambridge Crystallographic Data Centre

CCDC 1961435: Experimental Crystal Structure Determination

Author(s): Piehl, Patrick; Amuso, Roberta; Alberico, Elisabetta; Junge, Henrik; Gabriele, Bartolo; Neumann, Helfried; Beller, Matthias
Published in: Cambridge Crystallographic Data Centre

CCDC 1847006: Experimental Crystal Structure Determination

Author(s): Leischner, Thomas; Spannenberg, Anke; Junge, Kathrin; Beller, Matthias
Published in: Cambridge Crystallographic Data Centre

CCDC 1847004: Experimental Crystal Structure Determination

Author(s): Leischner, Thomas; Spannenberg, Anke; Junge, Kathrin; Beller, Matthias
Published in: Cambridge Crystallographic Data Centre

CCDC 1897493: Experimental Crystal Structure Determination

Author(s): Murugesan, Kathiravan; Wei, Zhihong; Chandrashekhar, Vishwas G.; Neumann, Helfried; Spannenberg, Anke; Jiao, Haijun; Beller, Matthias; Jagadeesh, Rajenahally V.
Published in: Cambridge Crystallographic Data Centre

CCDC 1869414: Experimental Crystal Structure Determination

Author(s): Murugesan, Kathiravan; Bheeter, Charles Beromeo; Linnebank, Pim R.; Spannenberg, Anke; Reek, Joost N. H.; Jagadeesh, Rajenahally V.; Beller, Matthias
Published in: Cambridge Crystallographic Data Centre

CCDC 1895729: Experimental Crystal Structure Determination

Author(s): Liu, Weiping; Li, Wu; Spannenberg, Anke; Junge, Kathrin; Beller, Matthias
Published in: Cambridge Crystallographic Data Centre