Catalytic C–F Bond Functionalization for the Fixation of Environmentally Persistent Fluorocarbons

Publications

Peer reviewed articles (19)

Palladium-Catalyzed Carbon-Fluorine and Carbon-Hydrogen Bond Alumination of Fluoroarenes and Heteroarenes

Author(s): Wenyi Chen, Thomas N. Hooper, Jamues Ng, Andrew J. P. White, Mark R. Crimmin
Published in: Angewandte Chemie International Edition, Issue 56/41, 2017, Page(s) 12687-12691, ISSN 1433-7851
DOI: 10.1002/anie.201706378

Mild sp 2 Carbon–Oxygen Bond Activation by an Isolable Ruthenium(II) Bis(dinitrogen) Complex: Experiment and Theory

Author(s): Samantha Lau, Bryan Ward, Xueer Zhou, Andrew J. P. White, Ian J. Casely, Stuart A. Macgregor, Mark R. Crimmin
Published in: Organometallics, Issue 36/18, 2017, Page(s) 3654-3663, ISSN 0276-7333
DOI: 10.1021/acs.organomet.7b00632

A combined experimental and computational study on the reaction of fluoroarenes with Mg–Mg, Mg–Zn, Mg–Al and Al–Zn bonds

Author(s): Clare Bakewell, Bryan J. Ward, Andrew J. P. White, Mark R. Crimmin
Published in: Chemical Science, Issue 9/8, 2018, Page(s) 2348-2356, ISSN 2041-6520
DOI: 10.1039/c7sc05059c

Room temperature catalytic carbon–hydrogen bond alumination of unactivated arenes: mechanism and selectivity

Author(s): Thomas N. Hooper, Martí Garçon, Andrew J. P. White, Mark R. Crimmin
Published in: Chemical Science, Issue 9/24, 2018, Page(s) 5435-5440, ISSN 2041-6520
DOI: 10.1039/c8sc02072h

Reactions of Fluoroalkanes with Mg−Mg Bonds: Scope, sp 3 C−F/sp 2 C−F Coupling and Mechanism

Author(s): Greg Coates, Bryan J. Ward, Clare Bakewell, Andrew J. P. White, Mark R. Crimmin
Published in: Chemistry - A European Journal, Issue 24/61, 2018, Page(s) 16282-16286, ISSN 0947-6539
DOI: 10.1002/chem.201804580

Reactions of Fluoroalkenes with an Aluminium(I) Complex

Author(s): Clare Bakewell, Andrew J. P. White, Mark R. Crimmin
Published in: Angewandte Chemie International Edition, Issue 57/22, 2018, Page(s) 6638-6642, ISSN 1433-7851
DOI: 10.1002/anie.201802321

Palladium-catalysed magnesiation of benzene

Author(s): Martí Garçon, Andrew J. P. White, Mark R. Crimmin
Published in: Chemical Communications, Issue 54/87, 2018, Page(s) 12326-12328, ISSN 1359-7345
DOI: 10.1039/C8CC06392C

Carbon Chain Growth by Sequential Reactions of CO and CO 2 with [W(CO) 6 ] and an Aluminum(I) Reductant

Author(s): Richard Y. Kong, Mark R. Crimmin
Published in: Journal of the American Chemical Society, Issue 140/42, 2018, Page(s) 13614-13617, ISSN 0002-7863
DOI: 10.1021/jacs.8b09761

Reversible insertion of CO into an aluminium–carbon bond

Author(s): Richard Y. Kong, Mark R. Crimmin
Published in: Chemical Communications, 2019, Page(s) 10.1039/c9cc02818h, ISSN 1359-7345
DOI: 10.1039/c9cc02818h

Reversible alkene binding and allylic C–H activation with an aluminium( i ) complex

Author(s): Clare Bakewell, Andrew J. P. White, Mark R. Crimmin
Published in: Chemical Science, Issue 10/8, 2019, Page(s) 2452-2458, ISSN 2041-6520
DOI: 10.1039/c8sc04865g

Selective Hydrodefluorination of Hexafluoropropene to Industrially Relevant Hydrofluoroolefins

Author(s): Nicholas Phillips, Andrew White, Mark Crimmin
Published in: Advanced Synthesis & Catalysis, 2019, Page(s) 10.1002/adsc.201900234, ISSN 1615-4150
DOI: 10.1002/adsc.201900234

Unravelling nucleophilic aromatic substitution pathways with bimetallic nucleophiles

Author(s): Martí Garçon, Clare Bakewell, Andrew J. P. White, Mark R. Crimmin
Published in: Chemical Communications, Issue 55/12, 2019, Page(s) 1805-1808, ISSN 1359-7345
DOI: 10.1039/c8cc09701a

Functionalisation of Carbon–Fluorine Bonds with Main Group Reagents

Author(s): Mark Crimmin, Wenyi Chen, Clare Bakewell
Published in: Synthesis, Issue 49/04, 2017, Page(s) 810-821, ISSN 0039-7881
DOI: 10.1055/s-0036-1588663

Organometallic chemistry using partially fluorinated benzenes

Author(s): Sebastian D. Pike, Mark R. Crimmin, Adrian B. Chaplin
Published in: Chem. Commun., Issue 53/26, 2017, Page(s) 3615-3633, ISSN 1359-7345
DOI: 10.1039/C6CC09575E

Addition of Carbon–Fluorine Bonds to a Mg(I)–Mg(I) Bond: An Equivalent of Grignard Formation in Solution

Author(s): Clare Bakewell, Andrew J. P. White, Mark R. Crimmin
Published in: Journal of the American Chemical Society, Issue 138/39, 2016, Page(s) 12763-12766, ISSN 0002-7863
DOI: 10.1021/jacs.6b08104

The partial dehydrogenation of aluminium dihydrides

Author(s): Thomas N. Hooper, Samantha Lau, Wenyi Chen, Ryan K. Brown, Martí Garçon, Karen Luong, Nathan S. Barrow, Andrew S. Tatton, George A. Sackman, Christopher Richardson, Andrew J. P. White, Richard I. Cooper, Alison J. Edwards, Ian J. Casely, Mark R. Crimmin
Published in: Chemical Science, Issue 10/35, 2019, Page(s) 8083-8093, ISSN 2041-6520
DOI: 10.1039/c9sc02750e

Defluorosilylation of Industrially Relevant Fluoroolefins Using Nucleophilic Silicon Reagents

Author(s): Greg Coates, Hui Yee Tan, Carolin Kalff, Andrew J. P. White, Mark R. Crimmin
Published in: Angewandte Chemie International Edition, Issue 58/36, 2019, Page(s) 12514-12518, ISSN 1433-7851
DOI: 10.1002/anie.201906825

A hexagonal planar transition-metal complex

Author(s): Martí Garçon, Clare Bakewell, George A. Sackman, Andrew J. P. White, Richard I. Cooper, Alison J. Edwards, Mark R. Crimmin
Published in: Nature, Issue 574/7778, 2019, Page(s) 390-393, ISSN 0028-0836
DOI: 10.1038/s41586-019-1616-2

Dihydridoboranes: Selective Reagents for Hydroboration and Hydrodefluorination

Author(s): Nicholas A. Phillips, James O’Hanlon, Thomas N. Hooper, Andrew J. P. White, Mark R. Crimmin
Published in: Organic Letters, Issue 21/18, 2019, Page(s) 7289-7293, ISSN 1523-7060
DOI: 10.1021/acs.orglett.9b02515