The Electron as a Catalyst

Project Information

e-Cat

Grant agreement ID: 692640

DOI

10.3030/692640

Project closed

EC signature date 22 April 2016

Start date 1 October 2016

End date 31 March 2022

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 2 490 000,00

EU contribution

€ 2 490 000,00

Coordinated by

UNIVERSITAET MUENSTER
Germany

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (47)

Radical Aryl Migration from Boron to Carbon

Author(s): Dinghai Wang, Christian Mück-Lichtenfeld, Constantin G. Daniliuc, Armido Studer
Published in: Journal of the American Chemical Society, Issue 143/25, 2021, Page(s) 9320-9326, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c04217

Cooperative NHC and Photoredox Catalysis for the Synthesis of β‐Trifluoromethylated Alkyl Aryl Ketones

Author(s): Qing-Yuan Meng, Nadine Döben, Armido Studer
Published in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202008040

Allylboronic Esters as Acceptors in Radical Addition, Boron 1,2-Migration, and Trapping Cascades

Author(s): Kalipada Jana, Armido Studer
Published in: Organic Letters, 2022, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.2c00039

Preparation of α-Perfluoroalkyl Ketones from α,β-Unsaturated Ketones via Formal Hydroperfluoroalkylation

Author(s): Kalipada Jana, Isao Mizota, Armido Studer
Published in: Organic Letters, Issue 23/4, 2021, Page(s) 1280-1284, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.0c04260

Remote Site‐Selective Radical C(sp 3 )−H Monodeuteration of Amides using D 2 O

Author(s): Lin Wang, Yong Xia, Volker Derdau, Armido Studer
Published in: Angewandte Chemie International Edition, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202104254

Benzylic C−H acylation by cooperative NHC and photoredox catalysis

Author(s): Qing-Yuan Meng, Lena Lezius, Armido Studer
Published in: Nature Communications, Issue 12/1, 2021, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-021-22292-z

Remote Radical Desaturation of Unactivated C−H Bonds in Amides

Author(s): Yong Xia, Kalipada Jana, Armido Studer
Published in: Chemistry – A European Journal, 2021, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202103509

Synthesis of 1,3‐Bis‐(boryl)alkanes through Boronic Ester Induced Consecutive Double 1,2‐Migration

Author(s): Cai You, Armido Studer
Published in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202007541

Cooperative NHC/Photoredox Catalyzed Ring‐Opening of Aryl Cyclopropanes to 1‐Aroyloxylated‐3‐Acylated Alkanes

Author(s): Zhijun Zuo, Constantin G. Daniliuc, Armido Studer
Published in: Angewandte Chemie International Edition, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202110304

Fe‐Catalyzed Anaerobic Mukaiyama‐Type Hydration of Alkenes using Nitroarenes

Author(s): Anup Bhunia, Klaus Bergander, Constantin Gabriel Daniliuc, Armido Studer
Published in: Angewandte Chemie International Edition, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202015740

Intramolecular Hydrogen Atom Transfer Induced 1,2-Migration of Boronate Complexes

Author(s): Dinghai Wang, Kalipada Jana, Armido Studer
Published in: Organic Letters, 2021, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.1c01998

Aroyl Fluorides as Bifunctional Reagents for Dearomatizing Fluoroaroylation of Benzofurans

Author(s): Xiaoye Yu, Qing-Yuan Meng, Constantin G. Daniliuc, Armido Studer
Published in: Journal of the American Chemical Society, Issue 143/25, 2022, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c01735

1,4-Aryl migration in ketene-derived enolates by a polar-radical-crossover cascade

Author(s): Niklas Radhoff, Armido Studer
Published in: Nature Communications, 2022, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-022-30817-3

Alkene 1,2-Difunctionalization by Radical Alkenyl Migration

Author(s): Xinjun Tang, Armido Studer
Published in: Angewandte Chemie International Edition, Issue 57/3, 2018, Page(s) 814-817, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201710397

Synthesis of α-Chiral Ketones and Chiral Alkanes Using Radical Polar Crossover Reactions of Vinyl Boron Ate Complexes

Author(s): Carolin Gerleve, Marvin Kischkewitz, Armido Studer
Published in: Angewandte Chemie International Edition, Issue 57/9, 2018, Page(s) 2441-2444, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201711390

Transition Metal-Free 1,2-Carboboration of Unactivated Alkenes

Author(s): Ying Cheng, Christian Mück-Lichtenfeld, Armido Studer
Published in: Journal of the American Chemical Society, Issue 140/20, 2018, Page(s) 6221-6225, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.8b03333

Radical-Polar Crossover Reactions of Dienylboronate Complexes: Synthesis of Functionalized Allylboronic Esters

Author(s): Marvin Kischkewitz, Carolin Gerleve, Armido Studer
Published in: Organic Letters, Issue 20/12, 2018, Page(s) 3666-3669, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.8b01459

Metal-Free Direct C−H Cyanation of Alkenes

Author(s): Xi Wang, Armido Studer
Published in: Angewandte Chemie International Edition, 2018, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201807303

Preparation of Alkyl Boronic Esters Using Radical-Polar Crossover Reactions of Vinylboron Ate Complexes

Author(s): Marvin Kischkewitz
Published in: Organic Syntheses, Issue 95, 2018, Page(s) 205-217, ISSN 2333-3553
Publisher: American Chemical Society
DOI: 10.15227/orgsyn.095.0205

Metal-Free Radical Borylation of Alkyl and Aryl Iodides

Author(s): Ying Cheng, Christian Mück-Lichtenfeld, Armido Studer
Published in: Angewandte Chemie International Edition, 2018, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201810782

Photoinitiated Three-Component α-Perfluoroalkyl-β-heteroarylation of Unactivated Alkenes via Electron Catalysis

Author(s): Danqing Zheng, Armido Studer
Published in: Organic Letters, Issue 21/1, 2018, Page(s) 325-329, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.8b03849

Catalytic protodeboronation of pinacol boronic esters: formal anti-Markovnikov hydromethylation of alkenes

Author(s): Florian Clausen, Marvin Kischkewitz, Klaus Bergander, Armido Studer
Published in: Chemical Science, 2019, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9sc02067e

Deoxygenative Borylation of Secondary and Tertiary Alcohols

Author(s): Florian W. Friese, Armido Studer
Published in: Angewandte Chemie International Edition, Issue 58/28, 2019, Page(s) 9561-9564, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201904028

New avenues for C−B bond formation via radical intermediates

Author(s): Florian W. Friese, Armido Studer
Published in: Chemical Science, 2019, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9sc03765a

Chemistry With N-Centered Radicals Generated by Single-Electron Transfer-Oxidation Using Photoredox Catalysis

Author(s): Heng Jiang, Armido Studer
Published in: CCS Chemistry, 2019, Page(s) 38-49, ISSN 2096-5745
Publisher: Chinese Chmeical Societyy Publishing
DOI: 10.31635/ccschem.019.20180026

Hydrogen Atom Transfer Induced Boron Retaining Coupling of Organoboronic Esters and Organolithium Reagents

Author(s): Dinghai Wang, Christian Mück-Lichtenfeld, Armido Studer
Published in: Journal of the American Chemical Society, Issue 141/36, 2019, Page(s) 14126-14130, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.9b07960

Radical-polar crossover reactions of vinylboron ate complexes

Author(s): Marvin Kischkewitz, Kazuhiro Okamoto, Christian Mück-Lichtenfeld, Armido Studer
Published in: Science, Issue 355/6328, 2017, Page(s) 936-938, ISSN 0036-8075
Publisher: American Association for the Advancement of Science
DOI: 10.1126/science.aal3803

Construction of Polycyclic γ-Lactams and Related Heterocycles via Electron Catalysis

Author(s): Jun Xuan, Constantin G. Daniliuc, Armido Studer
Published in: Organic Letters, Issue 18/24, 2016, Page(s) 6372-6375, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.6b03267

Electron-Catalyzed Fluoroalkylation of Vinyl Azides

Author(s): Emily G. Mackay, Armido Studer
Published in: Chemistry - A European Journal, Issue 22/38, 2016, Page(s) 13455-13458, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201602855

Radical perfluoroalkylation – easy access to 2-perfluoroalkylindol-3-imines via electron catalysis

Author(s): Dirk Leifert, Denis G. Artiukhin, Johannes Neugebauer, Anzhela Galstyan, Cristian Alejandro Strassert, Armido Studer
Published in: Chem. Commun., Issue 52/35, 2016, Page(s) 5997-6000, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/C6CC02284G

Radical Cascade Cyclization: Reaction of 1,6-Enynes with Aryl Radicals by Electron Catalysis

Author(s): Jun Xuan, Dario Gonzalez-Abradelo, Cristian Alejandro Strassert, Constantin-Gabriel Daniliuc, Armido Studer
Published in: European Journal of Organic Chemistry, Issue 2016/29, 2016, Page(s) 4961-4964, ISSN 1434-193X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejoc.201601033

Intermolecular radical carboamination of alkenes

Author(s): Heng Jiang, Armido Studer
Published in: Chemical Society Reviews, 2020, ISSN 0306-0012
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9cs00692c

Base-Promoted C–C Bond Activation Enables Radical Allylation with Homoallylic Alcohols

Author(s): Maximilian Lübbesmeyer, Emily G. Mackay, Mark A. R. Raycroft, Jonas Elfert, Derek A. Pratt, Armido Studer
Published in: Journal of the American Chemical Society, Issue 142/5, 2020, Page(s) 2609-2616, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.9b12343

Regio- and Stereoselective Radical Perfluoroalkyltriflation of Alkynes Using Phenyl(perfluoroalkyl)iodonium Triflates

Author(s): Xi Wang, Armido Studer
Published in: Organic Letters, Issue 19/11, 2017, Page(s) 2977-2980, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.7b01215

Transition‐metal‐free Oxidative Cross‐Coupling of Tetraarylborates to Biaryls Using Organic Oxidants

Author(s): Carolin Gerleve, Armido Studer
Published in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202002595

1, n -Bisborylalkanes via Radical Boron Migration

Author(s): Dinghai Wang, Christian Mück-Lichtenfeld, Armido Studer
Published in: Journal of the American Chemical Society, Issue 142/20, 2020, Page(s) 9119-9123, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.0c03058

Iodine(III) Reagents in Radical Chemistry

Author(s): Xi Wang, Armido Studer
Published in: Accounts of Chemical Research, Issue 50/7, 2017, Page(s) 1712-1724, ISSN 0001-4842
Publisher: American Chemical Society
DOI: 10.1021/acs.accounts.7b00148

Perfluoroalkylation of Aryl- N , N -dimethyl Hydrazones Using Hypervalent Iodine(III) Reagents or Perfluoroalkyl Iodides

Author(s): Benjamin Janhsen, Armido Studer
Published in: The Journal of Organic Chemistry, Issue 82/22, 2017, Page(s) 11703-11710, ISSN 0022-3263
Publisher: American Chemical Society
DOI: 10.1021/acs.joc.7b00934

α-Perfluoroalkyl-β-alkynylation of alkenes via radical alkynyl migration

Author(s): Xinjun Tang, Armido Studer
Published in: Chem. Sci., Issue 8/10, 2017, Page(s) 6888-6892, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7SC02175E

Radical Hydrodehalogenation of Aryl Bromides and Chlorides with Sodium Hydride and 1,4-Dioxane

Author(s): Tobias Hokamp, Abhishek Dewanji, Maximilian Lübbesmeyer, Christian Mück-Lichtenfeld, Ernst-Ulrich Würthwein, Armido Studer
Published in: Angewandte Chemie International Edition, Issue 56/43, 2017, Page(s) 13275-13278, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201706534

1-Trifluoromethylisoquinolines from α-Benzylated Tosylmethyl Isocyanide Derivatives in a Modular Approach

Author(s): Lin Wang, Armido Studer
Published in: Organic Letters, Issue 19/20, 2017, Page(s) 5701-5704, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.7b02882

Oxindole Synthesis via Polar Radical Crossover of Ketene derived Amide Enolates in a Formal [3+2] Cycloaddition

Author(s): Niklas Radhoff, Armido Studer
Published in: Chemical Science, 2022, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1sc07134c

Three-component 1,2-carboamination of vinyl boronic esters via amidyl radical induced 1,2-migration

Author(s): Cai You, Armido Studer
Published in: Chemical Science, 2021, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1sc05811h

Regio‐ and Stereoselective 1,2‐Carboboration of Ynamides with Aryldichloroboranes

Author(s): Cai You, Mika Sakai, Constantin G. Daniliuc, Klaus Bergander, Shigehiro Yamaguchi, Armido Studer
Published in: Angewandte Chemie International Edition, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202107647

Three‐Component Aminoarylation of Electron‐Rich Alkenes by Merging Photoredox with Nickel Catalysis

Author(s): Heng Jiang, Xiaoye Yu, Constantin G. Daniliuc, Armido Studer
Published in: Angewandte Chemie International Edition, Issue 60/26, 2021, Page(s) 14399-14404, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202101775

Functionalization of α‐C(sp 3 )−H Bonds in Amides Using Radical Translocating Arylating Groups

Author(s): Niklas Radhoff, Armido Studer
Published in: Angewandte Chemie International Edition, Issue 60/7, 2021, Page(s) 3561-3565, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202013275

Direct α-Acylation of Alkenes via N-Heterocyclic Carbene, Sulfinate, and Photoredox Cooperative Triple Catalysis

Author(s): Kun Liu, Armido Studer
Published in: Journal of the American Chemical Society, Issue 143/13, 2021, Page(s) 4903-4909, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c01022