The Electron as a Catalyst

Informazioni relative al progetto

e-Cat

ID dell’accordo di sovvenzione: 692640

DOI 10.3030/692640

Progetto chiuso

Data della firma CE 22 Aprile 2016

Data di avvio 1 Ottobre 2016

Data di completamento 31 Marzo 2022

Finanziato da

• EXCELLENT SCIENCE - European Research Council (ERC)

Costo totale € 2 490 000,00

Contributo UE € 2 490 000,00

Coordinato da

UNIVERSITAET MUENSTER
Germany

CORDIS fornisce collegamenti ai risultati finali pubblici e alle pubblicazioni dei progetti ORIZZONTE.

I link ai risultati e alle pubblicazioni dei progetti del 7° PQ, così come i link ad alcuni tipi di risultati specifici come dataset e software, sono recuperati dinamicamente da .OpenAIRE .

Pubblicazioni

Peer reviewed articles (47)

Radical Aryl Migration from Boron to Carbon

Autori: Dinghai Wang, Christian Mück-Lichtenfeld, Constantin G. Daniliuc, Armido Studer
Pubblicato in: Journal of the American Chemical Society, Numero 143/25, 2021, Pagina/e 9320-9326, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.1c04217

Cooperative NHC and Photoredox Catalysis for the Synthesis of β‐Trifluoromethylated Alkyl Aryl Ketones

Autori: Qing-Yuan Meng, Nadine Döben, Armido Studer
Pubblicato in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202008040

Allylboronic Esters as Acceptors in Radical Addition, Boron 1,2-Migration, and Trapping Cascades

Autori: Kalipada Jana, Armido Studer
Pubblicato in: Organic Letters, 2022, ISSN 1523-7060
Editore: American Chemical Society
DOI: 10.1021/acs.orglett.2c00039

Preparation of α-Perfluoroalkyl Ketones from α,β-Unsaturated Ketones via Formal Hydroperfluoroalkylation

Autori: Kalipada Jana, Isao Mizota, Armido Studer
Pubblicato in: Organic Letters, Numero 23/4, 2021, Pagina/e 1280-1284, ISSN 1523-7060
Editore: American Chemical Society
DOI: 10.1021/acs.orglett.0c04260

Remote Site‐Selective Radical C(sp 3 )−H Monodeuteration of Amides using D 2 O

Autori: Lin Wang, Yong Xia, Volker Derdau, Armido Studer
Pubblicato in: Angewandte Chemie International Edition, 2021, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202104254

Benzylic C−H acylation by cooperative NHC and photoredox catalysis

Autori: Qing-Yuan Meng, Lena Lezius, Armido Studer
Pubblicato in: Nature Communications, Numero 12/1, 2021, ISSN 2041-1723
Editore: Nature Publishing Group
DOI: 10.1038/s41467-021-22292-z

Remote Radical Desaturation of Unactivated C−H Bonds in Amides

Autori: Yong Xia, Kalipada Jana, Armido Studer
Pubblicato in: Chemistry – A European Journal, 2021, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202103509

Synthesis of 1,3‐Bis‐(boryl)alkanes through Boronic Ester Induced Consecutive Double 1,2‐Migration

Autori: Cai You, Armido Studer
Pubblicato in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202007541

Cooperative NHC/Photoredox Catalyzed Ring‐Opening of Aryl Cyclopropanes to 1‐Aroyloxylated‐3‐Acylated Alkanes

Autori: Zhijun Zuo, Constantin G. Daniliuc, Armido Studer
Pubblicato in: Angewandte Chemie International Edition, 2021, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202110304

Fe‐Catalyzed Anaerobic Mukaiyama‐Type Hydration of Alkenes using Nitroarenes

Autori: Anup Bhunia, Klaus Bergander, Constantin Gabriel Daniliuc, Armido Studer
Pubblicato in: Angewandte Chemie International Edition, 2021, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202015740

Intramolecular Hydrogen Atom Transfer Induced 1,2-Migration of Boronate Complexes

Autori: Dinghai Wang, Kalipada Jana, Armido Studer
Pubblicato in: Organic Letters, 2021, ISSN 1523-7060
Editore: American Chemical Society
DOI: 10.1021/acs.orglett.1c01998

Aroyl Fluorides as Bifunctional Reagents for Dearomatizing Fluoroaroylation of Benzofurans

Autori: Xiaoye Yu, Qing-Yuan Meng, Constantin G. Daniliuc, Armido Studer
Pubblicato in: Journal of the American Chemical Society, Numero 143/25, 2022, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.2c01735

1,4-Aryl migration in ketene-derived enolates by a polar-radical-crossover cascade

Autori: Niklas Radhoff, Armido Studer
Pubblicato in: Nature Communications, 2022, ISSN 2041-1723
Editore: Nature Publishing Group
DOI: 10.1038/s41467-022-30817-3

Alkene 1,2-Difunctionalization by Radical Alkenyl Migration

Autori: Xinjun Tang, Armido Studer
Pubblicato in: Angewandte Chemie International Edition, Numero 57/3, 2018, Pagina/e 814-817, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201710397

Synthesis of α-Chiral Ketones and Chiral Alkanes Using Radical Polar Crossover Reactions of Vinyl Boron Ate Complexes

Autori: Carolin Gerleve, Marvin Kischkewitz, Armido Studer
Pubblicato in: Angewandte Chemie International Edition, Numero 57/9, 2018, Pagina/e 2441-2444, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201711390

Transition Metal-Free 1,2-Carboboration of Unactivated Alkenes

Autori: Ying Cheng, Christian Mück-Lichtenfeld, Armido Studer
Pubblicato in: Journal of the American Chemical Society, Numero 140/20, 2018, Pagina/e 6221-6225, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.8b03333

Radical-Polar Crossover Reactions of Dienylboronate Complexes: Synthesis of Functionalized Allylboronic Esters

Autori: Marvin Kischkewitz, Carolin Gerleve, Armido Studer
Pubblicato in: Organic Letters, Numero 20/12, 2018, Pagina/e 3666-3669, ISSN 1523-7060
Editore: American Chemical Society
DOI: 10.1021/acs.orglett.8b01459

Metal-Free Direct C−H Cyanation of Alkenes

Autori: Xi Wang, Armido Studer
Pubblicato in: Angewandte Chemie International Edition, 2018, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201807303

Preparation of Alkyl Boronic Esters Using Radical-Polar Crossover Reactions of Vinylboron Ate Complexes

Autori: Marvin Kischkewitz
Pubblicato in: Organic Syntheses, Numero 95, 2018, Pagina/e 205-217, ISSN 2333-3553
Editore: American Chemical Society
DOI: 10.15227/orgsyn.095.0205

Metal-Free Radical Borylation of Alkyl and Aryl Iodides

Autori: Ying Cheng, Christian Mück-Lichtenfeld, Armido Studer
Pubblicato in: Angewandte Chemie International Edition, 2018, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201810782

Photoinitiated Three-Component α-Perfluoroalkyl-β-heteroarylation of Unactivated Alkenes via Electron Catalysis

Autori: Danqing Zheng, Armido Studer
Pubblicato in: Organic Letters, Numero 21/1, 2018, Pagina/e 325-329, ISSN 1523-7060
Editore: American Chemical Society
DOI: 10.1021/acs.orglett.8b03849

Catalytic protodeboronation of pinacol boronic esters: formal anti-Markovnikov hydromethylation of alkenes

Autori: Florian Clausen, Marvin Kischkewitz, Klaus Bergander, Armido Studer
Pubblicato in: Chemical Science, 2019, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/c9sc02067e

Deoxygenative Borylation of Secondary and Tertiary Alcohols

Autori: Florian W. Friese, Armido Studer
Pubblicato in: Angewandte Chemie International Edition, Numero 58/28, 2019, Pagina/e 9561-9564, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201904028

New avenues for C−B bond formation via radical intermediates

Autori: Florian W. Friese, Armido Studer
Pubblicato in: Chemical Science, 2019, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/c9sc03765a

Chemistry With N-Centered Radicals Generated by Single-Electron Transfer-Oxidation Using Photoredox Catalysis

Autori: Heng Jiang, Armido Studer
Pubblicato in: CCS Chemistry, 2019, Pagina/e 38-49, ISSN 2096-5745
Editore: Chinese Chmeical Societyy Publishing
DOI: 10.31635/ccschem.019.20180026

Hydrogen Atom Transfer Induced Boron Retaining Coupling of Organoboronic Esters and Organolithium Reagents

Autori: Dinghai Wang, Christian Mück-Lichtenfeld, Armido Studer
Pubblicato in: Journal of the American Chemical Society, Numero 141/36, 2019, Pagina/e 14126-14130, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.9b07960

Radical-polar crossover reactions of vinylboron ate complexes

Autori: Marvin Kischkewitz, Kazuhiro Okamoto, Christian Mück-Lichtenfeld, Armido Studer
Pubblicato in: Science, Numero 355/6328, 2017, Pagina/e 936-938, ISSN 0036-8075
Editore: American Association for the Advancement of Science
DOI: 10.1126/science.aal3803

Construction of Polycyclic γ-Lactams and Related Heterocycles via Electron Catalysis

Autori: Jun Xuan, Constantin G. Daniliuc, Armido Studer
Pubblicato in: Organic Letters, Numero 18/24, 2016, Pagina/e 6372-6375, ISSN 1523-7060
Editore: American Chemical Society
DOI: 10.1021/acs.orglett.6b03267

Electron-Catalyzed Fluoroalkylation of Vinyl Azides

Autori: Emily G. Mackay, Armido Studer
Pubblicato in: Chemistry - A European Journal, Numero 22/38, 2016, Pagina/e 13455-13458, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201602855

Radical perfluoroalkylation – easy access to 2-perfluoroalkylindol-3-imines via electron catalysis

Autori: Dirk Leifert, Denis G. Artiukhin, Johannes Neugebauer, Anzhela Galstyan, Cristian Alejandro Strassert, Armido Studer
Pubblicato in: Chem. Commun., Numero 52/35, 2016, Pagina/e 5997-6000, ISSN 1359-7345
Editore: Royal Society of Chemistry
DOI: 10.1039/C6CC02284G

Radical Cascade Cyclization: Reaction of 1,6-Enynes with Aryl Radicals by Electron Catalysis

Autori: Jun Xuan, Dario Gonzalez-Abradelo, Cristian Alejandro Strassert, Constantin-Gabriel Daniliuc, Armido Studer
Pubblicato in: European Journal of Organic Chemistry, Numero 2016/29, 2016, Pagina/e 4961-4964, ISSN 1434-193X
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/ejoc.201601033

Intermolecular radical carboamination of alkenes

Autori: Heng Jiang, Armido Studer
Pubblicato in: Chemical Society Reviews, 2020, ISSN 0306-0012
Editore: Royal Society of Chemistry
DOI: 10.1039/c9cs00692c

Base-Promoted C–C Bond Activation Enables Radical Allylation with Homoallylic Alcohols

Autori: Maximilian Lübbesmeyer, Emily G. Mackay, Mark A. R. Raycroft, Jonas Elfert, Derek A. Pratt, Armido Studer
Pubblicato in: Journal of the American Chemical Society, Numero 142/5, 2020, Pagina/e 2609-2616, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.9b12343

Regio- and Stereoselective Radical Perfluoroalkyltriflation of Alkynes Using Phenyl(perfluoroalkyl)iodonium Triflates

Autori: Xi Wang, Armido Studer
Pubblicato in: Organic Letters, Numero 19/11, 2017, Pagina/e 2977-2980, ISSN 1523-7060
Editore: American Chemical Society
DOI: 10.1021/acs.orglett.7b01215

Transition‐metal‐free Oxidative Cross‐Coupling of Tetraarylborates to Biaryls Using Organic Oxidants

Autori: Carolin Gerleve, Armido Studer
Pubblicato in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202002595

1, n -Bisborylalkanes via Radical Boron Migration

Autori: Dinghai Wang, Christian Mück-Lichtenfeld, Armido Studer
Pubblicato in: Journal of the American Chemical Society, Numero 142/20, 2020, Pagina/e 9119-9123, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.0c03058

Iodine(III) Reagents in Radical Chemistry

Autori: Xi Wang, Armido Studer
Pubblicato in: Accounts of Chemical Research, Numero 50/7, 2017, Pagina/e 1712-1724, ISSN 0001-4842
Editore: American Chemical Society
DOI: 10.1021/acs.accounts.7b00148

Perfluoroalkylation of Aryl- N , N -dimethyl Hydrazones Using Hypervalent Iodine(III) Reagents or Perfluoroalkyl Iodides

Autori: Benjamin Janhsen, Armido Studer
Pubblicato in: The Journal of Organic Chemistry, Numero 82/22, 2017, Pagina/e 11703-11710, ISSN 0022-3263
Editore: American Chemical Society
DOI: 10.1021/acs.joc.7b00934

α-Perfluoroalkyl-β-alkynylation of alkenes via radical alkynyl migration

Autori: Xinjun Tang, Armido Studer
Pubblicato in: Chem. Sci., Numero 8/10, 2017, Pagina/e 6888-6892, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/C7SC02175E

Radical Hydrodehalogenation of Aryl Bromides and Chlorides with Sodium Hydride and 1,4-Dioxane

Autori: Tobias Hokamp, Abhishek Dewanji, Maximilian Lübbesmeyer, Christian Mück-Lichtenfeld, Ernst-Ulrich Würthwein, Armido Studer
Pubblicato in: Angewandte Chemie International Edition, Numero 56/43, 2017, Pagina/e 13275-13278, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201706534

1-Trifluoromethylisoquinolines from α-Benzylated Tosylmethyl Isocyanide Derivatives in a Modular Approach

Autori: Lin Wang, Armido Studer
Pubblicato in: Organic Letters, Numero 19/20, 2017, Pagina/e 5701-5704, ISSN 1523-7060
Editore: American Chemical Society
DOI: 10.1021/acs.orglett.7b02882

Oxindole Synthesis via Polar Radical Crossover of Ketene derived Amide Enolates in a Formal [3+2] Cycloaddition

Autori: Niklas Radhoff, Armido Studer
Pubblicato in: Chemical Science, 2022, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/d1sc07134c

Three-component 1,2-carboamination of vinyl boronic esters via amidyl radical induced 1,2-migration

Autori: Cai You, Armido Studer
Pubblicato in: Chemical Science, 2021, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/d1sc05811h

Regio‐ and Stereoselective 1,2‐Carboboration of Ynamides with Aryldichloroboranes

Autori: Cai You, Mika Sakai, Constantin G. Daniliuc, Klaus Bergander, Shigehiro Yamaguchi, Armido Studer
Pubblicato in: Angewandte Chemie International Edition, 2021, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202107647

Three‐Component Aminoarylation of Electron‐Rich Alkenes by Merging Photoredox with Nickel Catalysis

Autori: Heng Jiang, Xiaoye Yu, Constantin G. Daniliuc, Armido Studer
Pubblicato in: Angewandte Chemie International Edition, Numero 60/26, 2021, Pagina/e 14399-14404, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202101775

Functionalization of α‐C(sp 3 )−H Bonds in Amides Using Radical Translocating Arylating Groups

Autori: Niklas Radhoff, Armido Studer
Pubblicato in: Angewandte Chemie International Edition, Numero 60/7, 2021, Pagina/e 3561-3565, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202013275

Direct α-Acylation of Alkenes via N-Heterocyclic Carbene, Sulfinate, and Photoredox Cooperative Triple Catalysis

Autori: Kun Liu, Armido Studer
Pubblicato in: Journal of the American Chemical Society, Numero 143/13, 2021, Pagina/e 4903-4909, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.1c01022