Towards the discovery of efficient CO2 electroreduction catalysts: well-defined RuOx and MoSx nano catalysts

Información del proyecto

CO2-RR-MODCAT

Identificador del acuerdo de subvención: 705230

DOI

10.3030/705230

Proyecto cerrado

Fecha de la firma de la CE 29 Febrero 2016

Fecha de inicio 1 Mayo 2016

Fecha de finalización 30 Abril 2018

Financiado con arreglo a

• EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions

Coste total

€ 200 194,80

Aportación de la UE

€ 200 194,80

Coordinado por

DANMARKS TEKNISKE UNIVERSITET
Denmark

Objetivo

In future, fuels and basic chemicals may be produced via an electrolytic process that converts CO2, water and electricity derived from renewable energy sources. Such promising, yet underdeveloped technology needs fundamental breakthroughs in the development of efficient electrode catalysts, i.e. electrocatalysts, for CO2 reduction reaction (CO2-RR). In fact, none of the currently known catalysts has adequate efficiency.
In this project, I propose to investigate well-defined ruthenium oxide (RuOx) and molybdenum sulphide (MoSx) nano catalysts for the CO2-RR. The goal is to discover new, efficient catalysts on the basis of fundamental insight. In the first phase, model RuOx and MoSx catalysts (nanoparticles, thin films) will be investigated to elucidate the physicochemical parameters that control their performance. In the second phase, synthetic strategies will be applied to enhance the catalyst activity and selectivity; these will be based on the preparation of metal substituted RuOx and on the exploitation of catalyst-support interactions.
The proposed investigation is:
• Timely, given the relevance attributed by the European Union and by the chemical industry to the research on CO2 re-utilization strategies that involve the integration of renewable energy sources;
• Innovative. RuOx and MoSx are promising, yet largely unexplored catalysts for the CO2-RR. The strategies devised to enhance their performance are radically different from what has been proposed so far.
• Expected to provide high impact. The structure-activity descriptors identified through this study will open new perspectives for the design of efficient catalysts via controlled synthetic processes.
The research methodology is based on the synthesis of well-defined catalysts coupled with a multi-analytical characterization approach. As such, it is ideal to achieve the objectives and it will provide new knowledge for the researcher. The planned collaborations will have great impact for the host group.

Ámbito científico (EuroSciVoc)

• ciencias sociales › geografía social y económica › transporte › vehículo eléctrico
• humanidades › lenguas y literatura › estudios literarios
• ciencias naturales › ciencias químicas › catálisis › electrocatálisis
• ciencias naturales › ciencias químicas › química inorgánica › metales de transición
• ciencias naturales › ciencias químicas › química orgánica › alcoholes

Programa(s)

• H2020-EU.1.3. - EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions PROGRAMA PRINCIPAL
  
• H2020-EU.1.3.2. - Nurturing excellence by means of cross-border and cross-sector mobility
  

Tema(s)

• MSCA-IF-2015-EF - Marie Skłodowska-Curie Individual Fellowships (IF-EF)
  

Régimen de financiación

MSCA-IF-EF-ST - Standard EF

Convocatoria de propuestas

H2020-MSCA-IF-2015

Coordinador

DANMARKS TEKNISKE UNIVERSITET

• Aportación neta de la UEn: € 200 194,80
• Dirección: ANKER ENGELUNDS VEJ 101 ; 2800 KONGENS LYNGBY ; Dinamarca
• Región: Danmark › Hovedstaden › Københavns omegn
• Tipo de actividad: Higher or Secondary Education Establishments
• Coste total: € 200 194,80