Deliverables Documents, reports (2) Equilibrium phases diagram including all known phases Kesterites are complex materials that are commonly synthesized under non-stoichiometric and out-of-equilibrium conditions, implying that secondary phases are prone to occur. In this deliverable and using Density Functional Theory (termed “ab initio thermodynamics” in the research community), and the corresponding database of Gibbs free energies, the phase stability of kesterites as a function of temperature and partial pressures will be compared with additional competing solid phases (e.g. Cu-Sn and Cu-Zn ternary phases) and gases (oxygen, hydrogen and water), to provide quantitative insights into phase stability and separation, as well as optimal processing windows. ICL will contribute to this deliverable. STARCELL Gender Equality Action Plan Gender issues are very relevant in STARCELL, and in this deliverable all the required actions to promote the carrier of woman in Science and Technology will be described. Actions will be described in the frame of the consortium, but also presenting available data of the different partners of STARCELL. IREC will contribute to this deliverable with the inputs of the consortium. Websites, patent fillings, videos etc. (1) Project website The project website will be presented in this WP, with the detail of all the information available in the webpage created for STARCELL. IREC will contribute to this deliverable. Publications Peer reviewed articles (34) Complex Interplay between Absorber Composition and Alkali Doping in High-Efficiency Kesterite Solar Cells Author(s): Stefan G. Haass, Christian Andres, Renato Figi, Claudia Schreiner, Melanie Bürki, Yaroslav E. Romanyuk, Ayodhya N. Tiwari Published in: Advanced Energy Materials, Issue 8/4, 2018, Page(s) 1701760, ISSN 1614-6832 Publisher: Wiley-VCH Verlag DOI: 10.1002/aenm.201701760 Effects of potassium on kesterite solar cells: Similarities, differences and synergies with sodium Author(s): S. G. Haass, C. Andres, R. Figi, C. Schreiner, M. Bürki, A. N. Tiwari, Y. E. Romanyuk Published in: AIP Advances, Issue 8/1, 2018, Page(s) 015133, ISSN 2158-3226 Publisher: American Institute of Physics Inc. DOI: 10.1063/1.5013114 Chemistry and Dynamics of Ge in Kesterite: Toward Band-Gap-Graded Absorbers Author(s): José Márquez, Helena Stange, Charles J. Hages, Norbert Schaefer, Sergiu Levcenko, Sergio Giraldo, Edgardo Saucedo, Klaus Schwarzburg, Daniel Abou-Ras, Alex Redinger, Manuela Klaus, Christoph Genzel, Thomas Unold, Roland Mainz Published in: Chemistry of Materials, Issue 29/21, 2017, Page(s) 9399-9406, ISSN 0897-4756 Publisher: American Chemical Society DOI: 10.1021/acs.chemmater.7b03416 Instilling defect tolerance in new compounds Author(s): Aron Walsh, Alex Zunger Published in: Nature Materials, Issue 16/10, 2017, Page(s) 964-967, ISSN 1476-1122 Publisher: Nature Publishing Group DOI: 10.1038/nmat4973 How small amounts of Ge modify the formation pathways and crystallization of kesterites Author(s): S. Giraldo, E. Saucedo, M. Neuschitzer, F. Oliva, M. Placidi, X. Alcobé, V. Izquierdo-Roca, S. Kim, H. Tampo, H. Shibata, A. Pérez-Rodríguez, P. Pistor Published in: Energy & Environmental Science, Issue 11/3, 2018, Page(s) 582-593, ISSN 1754-5692 Publisher: Royal Society of Chemistry DOI: 10.1039/c7ee02318a Analysis of Failure Modes in Kesterite Solar Cells Author(s): Louis Grenet, Md Abdul Aziz Suzon, Fabrice Emieux, Frédéric Roux Published in: ACS Applied Energy Materials, Issue 1/5, 2018, Page(s) 2103-2113, ISSN 2574-0962 Publisher: American Chemical Society DOI: 10.1021/acsaem.8b00194 Structural characterization of off-stoichiometric kesterite-type Cu 2 ZnGeSe 4 compound semiconductors: from cation distribution to intrinsic point defect density Author(s): R. Gunder, J. A. Márquez-Prieto, G. Gurieva, T. Unold, S. Schorr Published in: CrystEngComm, Issue 20/11, 2018, Page(s) 1491-1498, ISSN 1466-8033 Publisher: Royal Society of Chemistry DOI: 10.1039/C7CE02090B Insights into the Formation Pathways of Cu 2 ZnSnSe 4 Using Rapid Thermal Processes Author(s): A. Hernández-Martínez, M. Placidi, L. Arqués, S. Giraldo, Y. Sánchez, V. Izquierdo-Roca, P. Pistor, M. Valentini, C. Malerba, E. Saucedo Published in: ACS Applied Energy Materials, Issue 1/5, 2018, Page(s) 1981-1989, ISSN 2574-0962 Publisher: American Chemical Society DOI: 10.1021/acsaem.8b00089 Identification of Killer Defects in Kesterite Thin-Film Solar Cells Author(s): Sunghyun Kim, Ji-Sang Park, Aron Walsh Published in: ACS Energy Letters, Issue 3/2, 2018, Page(s) 496-500, ISSN 2380-8195 Publisher: American Chemical Society DOI: 10.1021/acsenergylett.7b01313 Opposing effects of stacking faults and antisite domain boundaries on the conduction band edge in kesterite quaternary semiconductors Author(s): Ji-Sang Park, Sunghyun Kim, Aron Walsh Published in: Physical Review Materials, Issue 2/1, 2018, ISSN 2475-9953 Publisher: APS Physics DOI: 10.1103/PhysRevMaterials.2.014602 Role of electron-phonon coupling and thermal expansion on band gaps, carrier mobility, and interfacial offsets in kesterite thin-film solar cells Author(s): Bartomeu Monserrat, Ji-Sang Park, Sunghyun Kim, Aron Walsh Published in: Applied Physics Letters, Issue 112/19, 2018, Page(s) 193903, ISSN 0003-6951 Publisher: American Institute of Physics DOI: 10.1063/1.5028186 Cu2ZnGe(S1-xSex)4 – The challenge to synthesize single phase material Author(s): Sara Niedenzu, Galina Gurieva, Susan Schorr Published in: Thin Solid Films, Issue 669, 2019, Page(s) 625-628, ISSN 0040-6090 Publisher: Elsevier Sequoia DOI: 10.1016/j.tsf.2018.11.039 Lone-pair effect on carrier capture in Cu 2 ZnSnS 4 solar cells Author(s): Sunghyun Kim, Ji-Sang Park, Samantha N. Hood, Aron Walsh Published in: Journal of Materials Chemistry A, Issue 7/6, 2019, Page(s) 2686-2693, ISSN 2050-7488 Publisher: Royal Society of Chemistry DOI: 10.1039/C8TA10130B Quick-start guide for first-principles modelling of semiconductor interfaces Author(s): Ji-Sang Park, Young-Kwang Jung, Keith T Butler, Aron Walsh Published in: Journal of Physics: Energy, Issue 1/1, 2019, Page(s) 016001, ISSN 2515-7655 Publisher: IOP DOI: 10.1088/2515-7655/aad928 Analysis of the Voltage Losses in CZTSSe Solar Cells of Varying Sn Content Author(s): Mohammed Azzouzi, Antonio Cabas-Vidani, Stefan G. Haass, Jason A. Röhr, Yaroslav E. Romanyuk, Ayodhya N. Tiwari, Jenny Nelson Published in: The Journal of Physical Chemistry Letters, Issue 10/11, 2019, Page(s) 2829-2835, ISSN 1948-7185 Publisher: American Chemical Society DOI: 10.1021/acs.jpclett.9b00506 High-Efficiency (Li x Cu 1− x ) 2 ZnSn(S,Se) 4 Kesterite Solar Cells with Lithium Alloying Author(s): Antonio Cabas-Vidani, Stefan G. Haass, Christian Andres, Raquel Caballero, Renato Figi, Claudia Schreiner, José A. Márquez, Charles Hages, Thomas Unold, Davide Bleiner, Ayodhya N. Tiwari, Yaroslav E. Romanyuk Published in: Advanced Energy Materials, Issue 8/34, 2018, Page(s) 1801191, ISSN 1614-6832 Publisher: Wiley-VCH Verlag DOI: 10.1002/aenm.201801191 Stability and electronic properties of planar defects in quaternary I 2 -II-IV-VI 4 semiconductors Author(s): Ji-Sang Park, Sunghyun Kim, Aron Walsh Published in: Journal of Applied Physics, Issue 124/16, 2018, Page(s) 165705, ISSN 0021-8979 Publisher: American Institute of Physics DOI: 10.1063/1.5053424 Open-circuit voltage deficit in Cu 2 ZnSnS 4 solar cells by interface bandgap narrowing Author(s): Ji-Sang Park, Sunghyun Kim, Samantha N. Hood, Aron Walsh Published in: Applied Physics Letters, Issue 113/21, 2018, Page(s) 212103, ISSN 0003-6951 Publisher: American Institute of Physics DOI: 10.1063/1.5063793 Effect of Sb and Na Incorporation in Cu 2 ZnSnS 4 Solar Cells Author(s): Md Abdul Aziz Suzon, Louis Grenet, Fabrice Emieux, Eric De Vito, Frédéric Roux, Henri Mariette Published in: physica status solidi (a), Issue 216/11, 2019, Page(s) 1900070, ISSN 1862-6300 Publisher: Wiley - V C H Verlag GmbbH & Co. DOI: 10.1002/pssa.201900070 Status of materials and device modelling for kesterite solar cells Author(s): Samantha N Hood, Aron Walsh, Clas Persson, Konstantina Iordanidou, Dan Huang, Mukesh Kumar, Zacharie Jehl, Maykel Courel, Johan Lauwaert, Sanghyun Lee Published in: Journal of Physics: Energy, Issue 1/4, 2019, Page(s) 042004, ISSN 2515-7655 Publisher: IOP DOI: 10.1088/2515-7655/ab2dda Back and front contacts in kesterite solar cells: state-of-the-art and open questions Author(s): Charlotte Platzer-Björkman, Nicolas Barreau, Marcus Bär, Leo Choubrac, Louis Grenet, Jaeyeong Heo, Tomas Kubart, Alberto Mittiga, Yudania Sanchez, Jonathan Scragg, Soumyadeep Sinha, Matteo Valentini Published in: Journal of Physics: Energy, Issue 1/4, 2019, Page(s) 044005, ISSN 2515-7655 Publisher: IOP DOI: 10.1088/2515-7655/ab3708 Solution-based synthesis of kesterite thin film semiconductors Author(s): T Todorov, H W Hillhouse, S Aazou, Z Sekkat, O Vigil-Galán, S D Deshmukh, R Agrawal, S Bourdais, M Valdés, P Arnou, D B Mitzi, P J Dale Published in: Journal of Physics: Energy, Issue 2/1, 2020, Page(s) 012003, ISSN 2515-7655 Publisher: IOP DOI: 10.1088/2515-7655/ab3a81 Doping and alloying of kesterites Author(s): Yaroslav E Romanyuk, Stefan G Haass, Sergio Giraldo, Marcel Placidi, Devendra Tiwari, David J Fermin, Xiaojing Hao, Hao Xin, Thomas Schnabel, Marit Kauk-Kuusik, Paul Pistor, Stener Lie, Lydia H Wong Published in: Journal of Physics: Energy, Issue 1/4, 2019, Page(s) 044004, ISSN 2515-7655 Publisher: IOP DOI: 10.1088/2515-7655/ab23bc The electrical and optical properties of kesterites Author(s): Maarja Grossberg, Jüri Krustok, Charles J Hages, Douglas M Bishop, Oki Gunawan, Roland Scheer, Samantha M Lyam, Hannes Hempel, Sergiu Levcenco, Thomas Unold Published in: Journal of Physics: Energy, Issue 1/4, 2019, Page(s) 044002, ISSN 2515-7655 Publisher: IOP DOI: 10.1088/2515-7655/ab29a0 Physical routes for the synthesis of kesterite Author(s): T Ratz, G Brammertz, R Caballero, M León, S Canulescu, J Schou, L Gütay, D Pareek, T Taskesen, D-H Kim, J-K Kang, C Malerba, A Redinger, E Saucedo, B Shin, H Tampo, K Timmo, N D Nguyen, B Vermang Published in: Journal of Physics: Energy, Issue 1/4, 2019, Page(s) 042003, ISSN 2515-7655 Publisher: IOP DOI: 10.1088/2515-7655/ab281c Emerging inorganic solar cell efficiency tables (Version 1) Author(s): Lydia H Wong, Andriy Zakutayev, Jonathan D Major, Xiaojing Hao, Aron Walsh, Teodor K Todorov, Edgardo Saucedo Published in: Journal of Physics: Energy, Issue 1/3, 2019, Page(s) 032001, ISSN 2515-7655 Publisher: IOP DOI: 10.1088/2515-7655/ab2338 The effect of Cu-Zn disorder on charge carrier mobility and lifetime in Cu2ZnSnSe4 Author(s): Hannes Hempel, Rainer Eichberger, Ingrid Repins, Thomas Unold Published in: Thin Solid Films, Issue 666, 2018, Page(s) 40-43, ISSN 0040-6090 Publisher: Elsevier Sequoia DOI: 10.1016/j.tsf.2018.09.027 Relating Carrier Dynamics and Photovoltaic Device Performance of Single-Crystalline Cu 2 Zn Sn Se 4 Author(s): Siming Li, Michael A. Lloyd, Hannes Hempel, Charles J. Hages, José A. Márquez, Thomas Unold, Rainer Eichberger, Brian E. McCandless, Jason B. Baxter Published in: Physical Review Applied, Issue 11/3, 2019, ISSN 2331-7019 Publisher: APS DOI: 10.1103/physrevapplied.11.034005 Minority and Majority Charge Carrier Mobility in Cu2ZnSnSe4 revealed by Terahertz Spectroscopy Author(s): Hannes Hempel, Charles J. Hages, Rainer Eichberger, Ingrid Repins, Thomas Unold Published in: Scientific Reports, Issue 8/1, 2018, ISSN 2045-2322 Publisher: Nature Publishing Group DOI: 10.1038/s41598-018-32695-6 From sputtered metal precursors towards Cu2Zn(Sn1-x,Gex)Se4 thin film solar cells with shallow back grading Author(s): C. Andres, A. Cabas-Vidani, A.N. Tiwari, Y.E. Romanyuk Published in: Thin Solid Films, Issue 665, 2018, Page(s) 168-172, ISSN 0040-6090 Publisher: Elsevier Sequoia DOI: 10.1016/j.tsf.2018.09.022 Sputtered ZnSnO Buffer Layers for Kesterite Solar Cells Author(s): Louis Grenet, Fabrice Emieux, Jacob Andrade-Arvizu, Eric De Vito, Géraldine Lorin, Yudania Sánchez, Edgardo Saucedo, Frédéric Roux Published in: ACS Applied Energy Materials, Issue 3/2, 2020, Page(s) 1883-1891, ISSN 2574-0962 Publisher: ACS DOI: 10.1021/acsaem.9b02329 Anharmonic lattice relaxation during nonradiative carrier capture Author(s): Sunghyun Kim, Samantha N. Hood, Aron Walsh Published in: Physical Review B, Issue 100/4, 2019, ISSN 2469-9950 Publisher: APS DOI: 10.1103/physrevb.100.041202 Defect characterisation in Cu 2 ZnSnSe 4 kesterites via resonance Raman spectroscopy and the impact on optoelectronic solar cell properties Author(s): Mirjana Dimitrievska, Florian Oliva, Maxim Guc, Sergio Giraldo, Edgardo Saucedo, Alejandro Pérez-Rodríguez, Victor Izquierdo-Roca Published in: Journal of Materials Chemistry A, Issue 7/21, 2019, Page(s) 13293-13304, ISSN 2050-7488 Publisher: Royal Society of Chemistry DOI: 10.1039/c9ta03625c Identifying the Real Minority Carrier Lifetime in Nonideal Semiconductors: A Case Study of Kesterite Materials Author(s): Charles J. Hages, Alex Redinger, Sergiu Levcenko, Hannes Hempel, Mark J. Koeper, Rakesh Agrawal, Dieter Greiner, Christian A. Kaufmann, Thomas Unold Published in: Advanced Energy Materials, 2017, Page(s) 1700167, ISSN 1614-6832 Publisher: Wiley-VCH Verlag DOI: 10.1002/aenm.201700167 Conference proceedings (2) Challenges and structural characterization of the solid solution Cu<inf>2</inf>Zn(Ge<inf>x</inf> Si<inf>1-x</inf>) Se<inf>4</inf> Author(s): Sara Niedenzu, Galina Gurieva, Susan Schorr Published in: 2018 IEEE 7th World Conference on Photovoltaic Energy Conversion (WCPEC) (A Joint Conference of 45th IEEE PVSC, 28th PVSEC & 34th EU PVSEC), 2018, Page(s) 3290-3293, ISBN 978-1-5386-8529-7 Publisher: IEEE DOI: 10.1109/PVSC.2018.8547352 Structural and Optoelectronic Characterization of (Ag<inf>x</inf> Cu<inf>1-x</inf>) ZnSnSe<inf>4</inf> solid solution Author(s): Galina Gurieva, Alexandra Franz, Jose Marquez Prieto, Thomas Unold, Susan Schorr Published in: 2018 IEEE 7th World Conference on Photovoltaic Energy Conversion (WCPEC) (A Joint Conference of 45th IEEE PVSC, 28th PVSEC & 34th EU PVSEC), 2018, Page(s) 0808-0811, ISBN 978-1-5386-8529-7 Publisher: IEEE DOI: 10.1109/PVSC.2018.8548043 Non-peer reviewed articles (1) The Steady Rise of Kesterite Solar Cells Author(s): Suzanne K. Wallace, David B. Mitzi, Aron Walsh Published in: ACS Energy Letters, Issue 2/4, 2017, Page(s) 776-779, ISSN 2380-8195 Publisher: American Chemical Society DOI: 10.1021/acsenergylett.7b00131 Searching for OpenAIRE data... There was an error trying to search data from OpenAIRE No results available
