Solid Catalysts for activation of aromatic C-H bonds

Project Information

H-CCAT

Grant agreement ID: 720996

DOI 10.3030/720996

Project closed

EC signature date 9 November 2016

Start date 1 January 2017

End date 30 June 2021

Funded under

• INDUSTRIAL LEADERSHIP - Leadership in enabling and industrial technologies - Advanced materials

Total cost € 7 588 312,50

EU contribution € 7 588 312,50

Coordinated by

KATHOLIEKE UNIVERSITEIT LEUVEN
Belgium

Deliverables

Websites, patent fillings, videos etc. (5)

Public website and yearly updates
First summer school
Mid-term workshop
Final workshop
Policy brief towards future regulatory issues

Demonstrators, pilots, prototypes (2)

Delivery of first generation of Pd-functionalized hybrid silicas for direct C-H arylation
Delivery of first generation of Pd-functionalized redox MOFs for oxidative aryl homocoupling

Open Research Data Pilot (1)

Delivery of research data to an open data pilot

Delivery of research data to an open data pilot based on the data management plan

Documents, reports (1)

Definition of innovative tools for controlling selectivity

Publications

Peer reviewed articles (12)

Towards Sustainable C−H Functionalization Reactions: The Emerging Role of Bio-Based Reaction Media

Author(s): Stefano Santoro, Assunta Marrocchi, Daniela Lanari, Lutz Ackermann, Luigi Vaccaro
Published in: Chemistry - A European Journal, 2018, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201801114

A continuous flow approach for the C–H functionalization of 1,2,3-triazoles in γ-valerolactone as a biomass-derived medium

Author(s): Francesco Ferlin, Lorenzo Luciani, Stefano Santoro, Assunta Marrocchi, Daniela Lanari, Alexander Bechtoldt, Lutz Ackermann, Luigi Vaccaro
Published in: Green Chemistry, Issue 20/12, 2018, Page(s) 2888-2893, ISSN 1463-9262
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8gc01115j

Ruthenium( ii ) oxidase catalysis for C–H alkenylations in biomass-derived γ-valerolactone

Author(s): Alexander Bechtoldt, Marcel E. Baumert, Luigi Vaccaro, Lutz Ackermann
Published in: Green Chemistry, Issue 20/2, 2018, Page(s) 398-402, ISSN 1463-9262
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7GC03353B

Single-site metal–organic framework catalysts for the oxidative coupling of arenes via C–H/C–H activation

Author(s): Niels Van Velthoven, Steve Waitschat, Sachin M. Chavan, Pei Liu, Simon Smolders, Jannick Vercammen, Bart Bueken, Sara Bals, Karl Petter Lillerud, Norbert Stock, Dirk E. De Vos
Published in: Chemical Science, Issue 10/12, 2019, Page(s) 3616-3622, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/C8SC05510F

Waste minimized synthesis of pharmaceutically active compounds via heterogeneous manganese catalysed C–H oxidation in flow

Author(s): Francesco Ferlin, Pilar María Luque Navarro, Yanlong Gu, Daniela Lanari, Luigi Vaccaro
Published in: Green Chemistry, Issue 22/2, 2020, Page(s) 397-403, ISSN 1463-9262
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9gc02961c

The Dual Effect of the Acetate Ligand on the Mechanism of the Pd‐Catalyzed C−H/C−H Coupling of Benzene

Author(s): Igor Beckers, Mickaël Henrion, Dirk E. De Vos
Published in: ChemCatChem, Issue 12/1, 2019, Page(s) 90-94, ISSN 1867-3880
Publisher: Wiley - VCH Verlag GmbH & CO. KGaA
DOI: 10.1002/cctc.201901238

C2–H Arylation of indoles catalyzed by Palladium containing Metal‐Organic‐Framework (Pd‐MOF) in bioderived γ‐valerolactone (GVL)

Author(s): Luigi Vaccaro, Ioannis Anastasiou, Niels Van Velthoven, Elena Tomarelli, Aurora Lombi, Daniela Lanari, Dirk De Vos, Pei Liu, Sara Bals
Published in: ChemSusChem, 2020, ISSN 1864-5631
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/cssc.202000378

Heterogeneous Manganese‐Catalyzed Oxidase C−H/C−O Cyclization to Access Pharmaceutically Active Compounds

Author(s): Francesco Ferlin, Alberto Marini, Nicola Ascani, Lutz Ackermann, Daniela Lanari, Luigi Vaccaro
Published in: ChemCatChem, Issue 12/2, 2019, Page(s) 449-454, ISSN 1867-3880
Publisher: Wiley - VCH Verlag GmbH & CO. KGaA
DOI: 10.1002/cctc.201901659

3D printing in chemical engineering and catalytic technology: structured catalysts, mixers and reactors

Author(s): Cesar Parra-Cabrera, Clement Achille, Simon Kuhn, Rob Ameloot
Published in: Chemical Society Reviews, Issue 47/1, 2018, Page(s) 209-230, ISSN 0306-0012
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7cs00631d

Reusable Pd@PEG Catalyst for Aerobic Dehydrogenative C−H/C−H Arylations of 1,2,3‐Triazoles

Author(s): Francesco Ferlin, Santhivardhana Reddy Yetra, Svenja Warratz, Luigi Vaccaro, Lutz Ackermann
Published in: Chemistry – A European Journal, Issue 25/49, 2019, Page(s) 11427-11431, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201902901

Expanding the Variety of Zirconium-based Inorganic Building Units for Metal-Organic Frameworks

Author(s): Sebastian Leubner, Haishuang Zhao, Niels Van Velthoven, Mickaël Henrion, Helge Reinsch, Dirk E. De Vos, Ute Kolb, Norbert Stock
Published in: Angewandte Chemie International Edition, Issue 58/32, 2019, Page(s) 10995-11000, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201905456

Continuous flow/waste-minimized synthesis of benzoxazoles catalysed by heterogeneous manganese systems

Author(s): Francesco Ferlin, Mitchell K. van der Hulst, Stefano Santoro, Daniela Lanari, Luigi Vaccaro
Published in: Green Chemistry, Issue 21/19, 2019, Page(s) 5298-5305, ISSN 1463-9262
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9gc01641d