Solid Catalysts for activation of aromatic C-H bonds

Informations projet

H-CCAT

N° de convention de subvention: 720996

DOI 10.3030/720996

Projet clôturé

Date de signature de la CE 9 Novembre 2016

Date de début 1 Janvier 2017

Date de fin 30 Juin 2021

Financé au titre de

• INDUSTRIAL LEADERSHIP - Leadership in enabling and industrial technologies - Advanced materials

Coût total € 7 588 312,50

Contribution de l’UE € 7 588 312,50

Coordonné par

KATHOLIEKE UNIVERSITEIT LEUVEN
Belgium

Livrables

Websites, patent fillings, videos etc. (5)

Public website and yearly updates
First summer school
Mid-term workshop
Final workshop
Policy brief towards future regulatory issues

Demonstrators, pilots, prototypes (2)

Delivery of first generation of Pd-functionalized hybrid silicas for direct C-H arylation
Delivery of first generation of Pd-functionalized redox MOFs for oxidative aryl homocoupling

Open Research Data Pilot (1)

Delivery of research data to an open data pilot

Delivery of research data to an open data pilot based on the data management plan

Documents, reports (1)

Definition of innovative tools for controlling selectivity

Publications

Peer reviewed articles (12)

Towards Sustainable C−H Functionalization Reactions: The Emerging Role of Bio-Based Reaction Media

Auteurs: Stefano Santoro, Assunta Marrocchi, Daniela Lanari, Lutz Ackermann, Luigi Vaccaro
Publié dans: Chemistry - A European Journal, 2018, ISSN 0947-6539
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201801114

A continuous flow approach for the C–H functionalization of 1,2,3-triazoles in γ-valerolactone as a biomass-derived medium

Auteurs: Francesco Ferlin, Lorenzo Luciani, Stefano Santoro, Assunta Marrocchi, Daniela Lanari, Alexander Bechtoldt, Lutz Ackermann, Luigi Vaccaro
Publié dans: Green Chemistry, Numéro 20/12, 2018, Page(s) 2888-2893, ISSN 1463-9262
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c8gc01115j

Ruthenium( ii ) oxidase catalysis for C–H alkenylations in biomass-derived γ-valerolactone

Auteurs: Alexander Bechtoldt, Marcel E. Baumert, Luigi Vaccaro, Lutz Ackermann
Publié dans: Green Chemistry, Numéro 20/2, 2018, Page(s) 398-402, ISSN 1463-9262
Éditeur: Royal Society of Chemistry
DOI: 10.1039/C7GC03353B

Single-site metal–organic framework catalysts for the oxidative coupling of arenes via C–H/C–H activation

Auteurs: Niels Van Velthoven, Steve Waitschat, Sachin M. Chavan, Pei Liu, Simon Smolders, Jannick Vercammen, Bart Bueken, Sara Bals, Karl Petter Lillerud, Norbert Stock, Dirk E. De Vos
Publié dans: Chemical Science, Numéro 10/12, 2019, Page(s) 3616-3622, ISSN 2041-6520
Éditeur: Royal Society of Chemistry
DOI: 10.1039/C8SC05510F

Waste minimized synthesis of pharmaceutically active compounds via heterogeneous manganese catalysed C–H oxidation in flow

Auteurs: Francesco Ferlin, Pilar María Luque Navarro, Yanlong Gu, Daniela Lanari, Luigi Vaccaro
Publié dans: Green Chemistry, Numéro 22/2, 2020, Page(s) 397-403, ISSN 1463-9262
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c9gc02961c

The Dual Effect of the Acetate Ligand on the Mechanism of the Pd‐Catalyzed C−H/C−H Coupling of Benzene

Auteurs: Igor Beckers, Mickaël Henrion, Dirk E. De Vos
Publié dans: ChemCatChem, Numéro 12/1, 2019, Page(s) 90-94, ISSN 1867-3880
Éditeur: Wiley - VCH Verlag GmbH & CO. KGaA
DOI: 10.1002/cctc.201901238

C2–H Arylation of indoles catalyzed by Palladium containing Metal‐Organic‐Framework (Pd‐MOF) in bioderived γ‐valerolactone (GVL)

Auteurs: Luigi Vaccaro, Ioannis Anastasiou, Niels Van Velthoven, Elena Tomarelli, Aurora Lombi, Daniela Lanari, Dirk De Vos, Pei Liu, Sara Bals
Publié dans: ChemSusChem, 2020, ISSN 1864-5631
Éditeur: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/cssc.202000378

Heterogeneous Manganese‐Catalyzed Oxidase C−H/C−O Cyclization to Access Pharmaceutically Active Compounds

Auteurs: Francesco Ferlin, Alberto Marini, Nicola Ascani, Lutz Ackermann, Daniela Lanari, Luigi Vaccaro
Publié dans: ChemCatChem, Numéro 12/2, 2019, Page(s) 449-454, ISSN 1867-3880
Éditeur: Wiley - VCH Verlag GmbH & CO. KGaA
DOI: 10.1002/cctc.201901659

3D printing in chemical engineering and catalytic technology: structured catalysts, mixers and reactors

Auteurs: Cesar Parra-Cabrera, Clement Achille, Simon Kuhn, Rob Ameloot
Publié dans: Chemical Society Reviews, Numéro 47/1, 2018, Page(s) 209-230, ISSN 0306-0012
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c7cs00631d

Reusable Pd@PEG Catalyst for Aerobic Dehydrogenative C−H/C−H Arylations of 1,2,3‐Triazoles

Auteurs: Francesco Ferlin, Santhivardhana Reddy Yetra, Svenja Warratz, Luigi Vaccaro, Lutz Ackermann
Publié dans: Chemistry – A European Journal, Numéro 25/49, 2019, Page(s) 11427-11431, ISSN 0947-6539
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201902901

Expanding the Variety of Zirconium-based Inorganic Building Units for Metal-Organic Frameworks

Auteurs: Sebastian Leubner, Haishuang Zhao, Niels Van Velthoven, Mickaël Henrion, Helge Reinsch, Dirk E. De Vos, Ute Kolb, Norbert Stock
Publié dans: Angewandte Chemie International Edition, Numéro 58/32, 2019, Page(s) 10995-11000, ISSN 1433-7851
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201905456

Continuous flow/waste-minimized synthesis of benzoxazoles catalysed by heterogeneous manganese systems

Auteurs: Francesco Ferlin, Mitchell K. van der Hulst, Stefano Santoro, Daniela Lanari, Luigi Vaccaro
Publié dans: Green Chemistry, Numéro 21/19, 2019, Page(s) 5298-5305, ISSN 1463-9262
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c9gc01641d