CREATE aims at developing innovative membrane electrode assemblies for low-temperature polymer-electrolyte fuel cell (FC) and electrolyzer (EL) with much reduced cost. This will be achieved via elimination or drastic reduction of critical raw materials in their catalysts, in particular platinum group metals (PGM).
Key issues with present low-temperature FC & EL are the high contents of PGM in devices based on proton-exchange-membrane (PEM) and the need for liquid electrolytes in alkaline FC and EL. To overcome this, we will shift from PEM-based cells to 1) pure anion-conducting polymer-electrolytes and 2) to bipolar-membrane polymer electrolytes. The latter comprises anion and proton conducting ionomers and a junction. Bipolar membranes allow adapting the pH at each electrode, thereby opening the door to improved performance or PGM-free catalysts. Both strategies carry the potentiality to eliminate or drastically reduce the need for PGM while maintaining the advantages of PEM-based devices.
In strategy 1, novel anion-exchange ionomers and membranes will be developed and interfaced with catalysts based on Earth-abundant metal oxides or metal-carbon composites for the oxygen reactions, and with ultralow PGM or PGM-free catalysts for the hydrogen reactions.
In strategy 2, novel bipolar membrane designs, or designs unexplored for FC & EL, will be developed and interfaced with catalysts for the oxygen reactions (high pH side of the bipolar membrane) and with catalysts for the hydrogen reactions (low pH side). The ionomers and oxygen reaction catalysts developed in strategy 1 will be equally useful for strategy 2, while identified PGM-free and ultralow-PGM catalysts will be implemented for the hydrogen reactions on the acidic side.
Polymer-electrolyte FC & EL based on those concepts will be evaluated for targeted applications, i.e. photovoltaic electricity storage, off-grid back-up power and H2 production. The targeted market is distributed small-scale systems.
Fields of science
- natural scienceschemical sciencespolymer science
- engineering and technologyenvironmental engineeringenergy and fuelsfossil energynatural gas
- natural scienceschemical scienceselectrochemistryelectrolysis
- engineering and technologyenvironmental engineeringenergy and fuelsrenewable energywindpower
- engineering and technologyenvironmental engineeringenergy and fuelsfuel cell
- natural scienceschemical sciencesinorganic chemistrymetals
- engineering and technologyelectrical engineering, electronic engineering, information engineeringelectrical engineeringpower engineeringelectric power generation
- natural scienceschemical sciencesinorganic chemistryinorganic compounds
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Funding SchemeRIA - Research and Innovation action
02115 Boston Ma