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Efficient electronic transport at room temperature by T-shaped molecules in graphene based chemically modified three-terminal nanodevices

Objective

Tmol4TRANS aims to create operative molecular systems that will efficiently be inserted in three-terminal nanodevices to function as transistors at room temperature (RT).
In the front-line of molecular electronics, the implementation of functional nanodevices in present technologies is mainly hampered by crucial unresolved issues like: a) reliability of RT experiments on molecular transistors; b) absence of controlled methodologies to deposit single molecules at specific sites; c) low conductance values and d) difficulties in achieving effective three-terminal devices (BJTs/FETs). Such hindrances involve the nature of the molecules, the absence of controlled deposition methodologies at the nanoscale and the poor stability/contacts between molecules and electrodes.
Stable two-terminal nanodevice based on few-layer graphene and containing a Curcuminoid molecule (CCMoid) that I made has shown reasonable molecular conductance at RT, where the CCMoid anchors to the electrodes by pi-pi stacking. The specific goals of Tmol4TRANS are: 1) to synthesize multifunctional molecules base on “T-shaped” CCMoids and Porphyrin derivatives (PPDs) allowing efficient attachments to electrodes; 2) to fabricate chemically functionalized hybrid graphene transistors; 3) to establish a reliable methodology for positioning the molecules between the electrodes; 4) to investigate the conductance enhancement of the final systems, and 5) to provide the possibility of spin-dependent transport properties by binding such molecules to magnetic metals. Here, the preparation of nanodevices involves feedback-controlled burning technique for the formation of the few-layer graphene electrodes (source/emitter and drain/collector) and the chemical functionalization of the gate/base, where T-shaped molecules will be fixed by click-chemistry. Tmol4TRANS would have a direct impact in Molecular Electronics and Spintronics, as well as in the broader scope of nanoelectronics.

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Programme(s)

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Topic(s)

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Funding Scheme

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ERC-COG - Consolidator Grant

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Call for proposal

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(opens in new window) ERC-2016-COG

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Host institution

AGENCIA ESTATAL CONSEJO SUPERIOR DE INVESTIGACIONES CIENTIFICAS
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 1 998 879,00
Address
CALLE SERRANO 117
28006 MADRID
Spain

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Region
Comunidad de Madrid Comunidad de Madrid Madrid
Activity type
Research Organisations
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 1 998 879,00

Beneficiaries (1)

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