Multifunctional Spin Crossover Materials

Deliverables

Project internet website

Progress Report 1

Report on the progress in the implementation of the project during the 1st year.

Reports from the visit describing ‘training through research’ of WP1.

Reports from the visit describing ‘training through research’ of WP2.

Progress report 2

Report on the progress of the project during the third year of the project.

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Publications

Crystal structure of catena -poly[[[tetraaquairon(II)]- trans -μ-1,2-bis(pyridin-4-yl)ethene-κ 2 N : N ′] bis( p -toluenesulfonate) methanol disolvate]

Author(s): Volodymyr M. Hiiuk, Diana D. Barakhty, Sergiu Shova, Ruslan A. Polunin, Il'ya A. Gural'skiy
Published in: Acta Crystallographica Section E Crystallographic Communications, Issue 73/12, 2017, Page(s) 1977-1980, ISSN 2056-9890
DOI: 10.1107/s2056989017017054

Room temperature current modulation in large area electronic junctions of spin crossover thin films

Author(s): Victoria Shalabaeva, Karl Ridier, Sylvain Rat, Maria D. Manrique-Juarez, Lionel Salmon, Isabelle Séguy, Aurelian Rotaru, Gábor Molnár, Azzedine Bousseksou
Published in: Applied Physics Letters, Issue 112/1, 2018, Page(s) 013301, ISSN 0003-6951
DOI: 10.1063/1.5017458

Piezoresistive Effect in the [Fe(Htrz) 2 (trz)](BF 4 ) Spin Crossover Complex

Author(s): Andrei Diaconu, Simona-Lacramioara Lupu, Ionela Rusu, Ioan-Marian Risca, Lionel Salmon, Gábor Molnár, Azzedine Bousseksou, Philippe Demont, Aurelian Rotaru
Published in: The Journal of Physical Chemistry Letters, Issue 8/13, 2017, Page(s) 3147-3151, ISSN 1948-7185
DOI: 10.1021/acs.jpclett.7b01111

Chiral and Racemic Spin Crossover Polymorphs in a Family of Mononuclear Iron(II) Compounds

Author(s): Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real
Published in: Inorganic Chemistry, Issue 56/21, 2017, Page(s) 13535-13546, ISSN 0020-1669
DOI: 10.1021/acs.inorgchem.7b02272

Pressure effect investigations on spin-crossover coordination compounds

Author(s): Ana B. Gaspar, Gábor Molnár, Aurelian Rotaru, Helena J. Shepherd
Published in: Comptes Rendus Chimie, Issue 21/12, 2018, Page(s) 1095-1120, ISSN 1631-0748
DOI: 10.1016/j.crci.2018.07.010

Room Temperature Hysteretic Spin Crossover in a New Cyanoheterometallic Framework

Author(s): Volodymyr M. Hiiuk, Sergiu Sova, Aurelian Rotaru, Vadim Ksenofontov, Igor O. Fritsky, Il'ya A. Gural'skiy
Published in: Chemical Communications, Issue 55, 2019, Page(s) 3359-3362, ISSN 1359-7345
DOI: 10.1039/c8cc10260k

Crystal structure and magnetic properties of (tris{4-[1-(2-methoxyethyl)imidazol-2-yl]-3-azabut-3-enyl}amine)iron(II) bis(hexafluoridophosphate)

Author(s): Kateryna Znovjyak, Igor O. Fritsky, Iryna A. Golenya, Tatiana Y. Sliva, Matti Haukka
Published in: Acta Crystallographica Section E Crystallographic Communications, Issue 75/3, 2019, Page(s) 358-361, ISSN 2056-9890
DOI: 10.1107/s2056989019001531

Very Long-Lived Photogenerated High-Spin Phase of a Multistable Spin-Crossover Molecular Material

Author(s): Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard
Published in: Journal of the American Chemical Society, Issue 140/40, 2018, Page(s) 12870-12876, ISSN 0002-7863
DOI: 10.1021/jacs.8b06042

Discrimination between two memory channels by molecular alloying in a doubly bistable spin crossover material

Author(s): Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José Antonio A Real Cabezos
Published in: Chemical Science, Issue 10, 2019, Page(s) 3807–3816, ISSN 2041-6520
DOI: 10.1039/c8sc05256e

Bilayer Thin Films That Combine Luminescent and Spin Crossover Properties for an Efficient and Reversible Fluorescence Switching

Author(s): Alin-Ciprian Bas, Xavier Thompson, Lionel Salmon, Christophe Thibault, Gábor Molnár, Oleg Palamarciuc, Lucie Routaboul, Azzedine Bousseksou
Published in: Magnetochemistry, Issue 5/2, 2019, Page(s) 28, ISSN 2312-7481
DOI: 10.3390/magnetochemistry5020028

Effects of solvent vapor annealing on the crystallinity and spin crossover properties of thin films of [Fe(HB(tz)3)2]

Author(s): Alin-Ciprian Bas, Victoria Shalabaeva, Xavier Thompson, Laure Vendier, Lionel Salmon, Christophe Thibault, Gábor Molnár, Lucie Routaboul, Azzedine Bousseksou
Published in: Comptes Rendus Chimie, Issue 22/6-7, 2019, Page(s) 525-533, ISSN 1631-0748
DOI: 10.1016/j.crci.2019.03.002

Crystal structure of catena -poly[[gold(I)-μ-cyanido-[diaquabis(2-phenylpyrazine)iron(II)]-μ-cyanido] dicyanidogold(I)]

Author(s): Olesia I. Kucheriv, Diana D. Barakhtii, Sergey O. Malinkin, Sergiu Shova, Il'ya A. Gural'skiy
Published in: Acta Crystallographica Section E Crystallographic Communications, Issue 75/8, 2019, Page(s) 1149-1152, ISSN 2056-9890
DOI: 10.1107/s2056989019009678

Pyridazine-Supported Polymeric Cyanometallates with Spin Transitions

Author(s): Il'ya A. Gural'skiy, Sergii I. Shylin, Vadim Ksenofontov, Wolfgang Tremel
Published in: European Journal of Inorganic Chemistry, Issue 2019/42, 2019, Page(s) 4532-4537, ISSN 1434-1948
DOI: 10.1002/ejic.201900782

Crystal structure and magnetic properties of bis[butyltris(1 H -pyrazol-1-yl)borato]iron(II)

Author(s): Maksym Seredyuk, Kateryna Znovjyak, Igor O. Fritsky, Tatiana Y. Sliva, Mykola S. Slobodyanik
Published in: Acta Crystallographica Section E Crystallographic Communications, Issue 75/9, 2019, Page(s) 1327-1330, ISSN 2056-9890
DOI: 10.1107/s2056989019011137

Spin crossover in 2D iron( ii ) phthalazine cyanometallic complexes

Author(s): Volodymyr M. Hiiuk, Sergiu Shova, Aurelian Rotaru, Alexander A. Golub, Igor O. Fritsky, Il'ya A. Gural'skiy
Published in: Dalton Transactions, Issue 49/16, 2020, Page(s) 5302-5311, ISSN 1477-9226
DOI: 10.1039/d0dt00783h

Hofmann-Like Frameworks Fe(2-methylpyrazine) n [M(CN) 2 ] 2 (M = Au, Ag): Spin-Crossover Defined by the Precious Metal

Author(s): Sergii I. Shylin, Olesia I. Kucheriv, Sergiu Shova, Vadim Ksenofontov, Wolfgang Tremel, Il’ya A. Gural’skiy
Published in: Inorganic Chemistry, 2020, ISSN 0020-1669
DOI: 10.1021/acs.inorgchem.0c00627

Broad-Band Dielectric Spectroscopy Reveals Peak Values of Conductivity and Permittivity Switching upon Spin Crossover

Author(s): Ion Soroceanu, Adrian Graur, Eugen Coca, Lionel Salmon, Gabor Molnar, Philippe Demont, Azzedine Bousseksou, Aurelian Rotaru
Published in: The Journal of Physical Chemistry Letters, Issue 10/23, 2019, Page(s) 7391-7396, ISSN 1948-7185
DOI: 10.1021/acs.jpclett.9b02678

Deliverables

Publications

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