Multifunctional Spin Crossover Materials

Deliverables

Two scientific papers on the topic of WP3

One scientific paper on the topic of WP4

Two scientific papers on the topic of WP2.
One scientific paper on the topic of WP5

One scientific paper on the topic of WP5

Two scientific papers on the topic of WP1
Internet website

Project internet website

Progress Report 1

Report on the progress in the implementation of the project during the 1st year.

Reports from the visit describing ‘training through research of WP4.

Reports from the visit describing training through research of WP4

Reports from the visit describing ‘training through research' of WP3.

Reports from the visit describing training through research of WP3

Reports from the visit describing ‘training through research’ of WP1.
Reports from the visit describing ‘training through research' of WP5.

Reports from the visit describing training through research of WP5

Reports from the visit describing ‘training through research’ of WP2.

Progress report 2

Report on the progress of the project during the third year of the project.

Report on ethics

Report on the management of all possible ethical issues related to the project

Publications

Pressure gradient effect on spin-crossover materials: Experiment vs theory

Author(s): Ionela Rusu, Ioan Cozmin Manolache-Rusu, Andrei Diaconu, Oleg Palamarciuc, Il’ya A. Gural'skiy, Gabor Molnar, and Aurelian Rotaru
Published in: Journal of Applied Physics, 2021, ISSN 0021-8979
Publisher: American Institute of Physics
DOI: 10.1063/5.0042582

Crystal structure of {N1,N3-bis[(1-benzyl-1H-1,2,3-triazol-4-yl)methylidene]-2,2-dimethylpropane-1,3-diamine}bis(thiocyanato-κN)iron(II)

Author(s): Znovjyak, Kateryna; Seredyuk, Maksym; Malinkin, Sergey O.; Shova, Sergiu; Soliev, Lutfullo
Published in: Acta Crystallographica Section E, Issue 13, 2020, ISSN 2056-9890
Publisher: IUCr
DOI: 10.1107/S2056989020012608

Effect of Guest Molecules on Spin Transition Temperature in Loaded Hofmann-Like Clathrates with Improved Porosity

Author(s): Lucía Piñeiro-López,Maksym Seredyuk,M. Carmen Muñoz,José A. Real
Published in: European Journal of Inorganic Chemistry, 2020, Page(s) 764-769, ISSN 1099-0682
Publisher: Wiley-VCH GmbH
DOI: 10.1002/ejic.201901347

Ligand substitution effects on the charge transport properties of the spin crossover complex [Fe(Htrz)1+y−x(trz)2−y(NH2trz)x](BF4)y·nH2O

Author(s): Soroceanu, Ion; Lupu, Simona-Lacramioara; Rusu, Ionela; Piedrahita-Bello, Mario; Salmon, Lionel; Molnár, Gábor; Demont, Philippe; Bousseksou, Azzedine; Rotaru, Aurelian
Published in: Journal of Physics: Condensed Matter, Issue 3, 2020, ISSN 0953-8984
Publisher: Institute of Physics Publishing
DOI: 10.1088/1361-648X/ab7ba2

Crystal structure of the mixed methanol and ethanol solvate of bis{3,4,5-trimethoxy-N′-[1-(pyridin-2-yl)ethylidene]benzohydrazidato}zinc(II)

Author(s): Znovjyak, Kateryna; Fritsky, Igor O.; Sliva, Tatiana Y.; Amirkhanov, Vladimir M.; Seredyuk, Maksym
Published in: Acta Crystallographica Section E, Issue 2, 2020, ISSN 2056-9890
Publisher: IUCr
DOI: 10.1107/S2056989020000857

Thermochromic Meltable Materials with Reverse Spin Transition Controlled by Chemical Design

Author(s): Valverde-Muñoz F.-J., Seredyuk M., Muñoz M. C., Molnár G., Bibik Y. S., Real J. A.
Published in: Angewandte Chemie, International Edition, Issue 59 (42), 2020, Page(s) 18632-18638, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202006453

Sequential Activation of Molecular and Macroscopic Spin-State Switching within the Hysteretic Region Following Pulsed Light Excitation

Author(s): Karl Ridier,William Nicolazzi,Lionel Salmon,Gábor Molnár,Azzedine Bousseksou
Published in: Advanced Materials, 2021, ISSN 0935-9648
Publisher: United Nations Industrial Developement Organization
DOI: 10.1002/adma.202105468

Mechano-electric coupling in P(VDF–TrFE)/spin crossover composites

Author(s): Piedrahita-Bello, Mario; Martin, Baptiste; Salmon, Lionel; Molnár, Gábor; Demont, Philippe; Bousseksou, Azzedine
Published in: Journal of Materials Chemistry C, Issue 4, 2020, ISSN 2050-7534
Publisher: Royal Society of Chemistry
DOI: 10.1039/D0TC00780C

4D printing with spin-crossover polymer composites

Author(s): Mario Piedrahita-Bello, José Elias Angulo-Cervera, Rémi Courson, Gábor Molnár, Laurent Malaquin, Christophe Thibault, Bertrand Tondu, Lionel Salmon and Azzedine Bousseksou
Published in: Journal of Materials Chemistry C, 2020, ISSN 2050-7534
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0tc01532f

Direct Synthesis of Spin-Crossover Complexes: An Unexpectedly Revealed New Iron-Triazolic Structure

Author(s): Valerii Y. Sirenko,Olesia I. Kucheriv,Dr. Aurelian Rotaru,Prof. Dr. Igor O. Fritsky,Dr. Il'ya A. Gural'skiy
Published in: European Journal of Inorganic Chemistry, 2020, Page(s) 4523-4531, ISSN 1099-0682
Publisher: Wiley-VCH GmbH
DOI: 10.1002/ejic.202000848

Crystal structure of poly[bis(μ-2-bromopyrazine)tetra-μ2-cyanido-dicopper(I)iron(II)]: a bimetallic metal-organic framework

Author(s): Kucheriv, Olesia I.; Tokmenko, Inna I.; Matushko, Igor P.; Tsapyuk, Galyna G.; Gural'skiy, Il'ya A.
Published in: Acta Crystallographica Section E, Issue 2, 2018, ISSN 2056-9890
Publisher: IUCr
DOI: 10.1107/S2056989018016638

Crystal structure of (N1,N3-bis{[1-(4-methoxybenzyl)-1H-1,2,3-triazol-4-yl]methylidene}-2,2-dimethylpropane-1,3-diamine)bis(thiocyanato)iron(II)

Author(s): Znovjyak, Kateryna; Seredyuk, Maksym; Malinkin, Sergey O.; Golenya, Iryna A.; Sliva, Tatiana Y.; Shova, Sergiu; Mulloev, Nurullo U.
Published in: Acta Crystallographica Section E, Issue 18, 2021, ISSN 2056-9890
Publisher: IUCr
DOI: 10.1107/S2056989021003662

Crystal structure of poly[[di-aqua-tetra-μ2-cyanido-platinum(II)iron(II)] methanol 4/3-solvate]: a three-dimensional Hofmann clathrate analogue

Author(s): V. M. Hiiuk, V. Mykhailovych, S. Shova, I. A. Golenya and I. A. Gural'skiy
Published in: Acta Crystallographica Section E, 2022, ISSN 2056-9890
Publisher: IUCr
DOI: 10.1107/s2056989022000573

Finite Size Effects on the Switching Dynamics of Spin-Crossover Thin Films Photoexcited by a Femtosecond Laser Pulse

Author(s): Ridier, Karl; Bas, Alin-Ciprian; Shalabaeva, Victoria; Nicolazzi, William; Salmon, Lionel; Molnár, Gábor; Bousseksou, Azzedine; Lorenc, Maciej; Bertoni, Roman; Collet, Eric; Cailleau, Hervé
Published in: Advanced Materials, Issue 2, 2019, ISSN 0935-9648
Publisher: United Nations Industrial Developement Organization
DOI: 10.1002/adma.201901361

Resistance switching in large-area vertical junctions of the molecular spin crossover complex [Fe(HB(tz)3)2]: ON/OFF ratios and device stability

Author(s): Zhang, Yuteng; Séguy, Isabelle; Ridier, Karl; Shalabaeva, Victoria; Piedrahita-Bello, Mario; Rotaru, Aurelian; Salmon, Lionel; Molnár, Gábor; Bousseksou, Azzedine
Published in: Journal of Physics: Condensed Matter, Issue 1, 2020, ISSN 0953-8984
Publisher: Institute of Physics Publishing
DOI: 10.1088/1361-648X/ab741e

Phase Stability of Spin-Crossover Nanoparticles Investigated by Synchrotron Mössbauer Spectroscopy and Small-Angle Neutron Scattering

Author(s): Mikolasek, Mirko; Ridier, Karl; Bessas, Dimitrios; Cerantola, Valerio; Félix, Gautier; Chaboussant, Grégory; Piedrahita-Bello, Mario; Angulo-Cervera, Elias; Godard, Leá; Nicolazzi, William; Salmon, Lionel; Molnár, Gábor; Bousseksou, Azzedine
Published in: The Journal of Physical Chemistry Letters, Issue 3, 2019, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.9b00335

Crystal structure of catena -poly[[[tetraaquairon(II)]- trans -μ-1,2-bis(pyridin-4-yl)ethene-κ 2 N : N ′] bis( p -toluenesulfonate) methanol disolvate]

Author(s): Volodymyr M. Hiiuk, Diana D. Barakhty, Sergiu Shova, Ruslan A. Polunin, Il'ya A. Gural'skiy
Published in: Acta Crystallographica Section E Crystallographic Communications, Issue 73/12, 2017, Page(s) 1977-1980, ISSN 2056-9890
Publisher: International Union of Crystallography
DOI: 10.1107/s2056989017017054

Room temperature current modulation in large area electronic junctions of spin crossover thin films

Author(s): Victoria Shalabaeva, Karl Ridier, Sylvain Rat, Maria D. Manrique-Juarez, Lionel Salmon, Isabelle Séguy, Aurelian Rotaru, Gábor Molnár, Azzedine Bousseksou
Published in: Applied Physics Letters, Issue 112/1, 2018, Page(s) 013301, ISSN 0003-6951
Publisher: American Institute of Physics
DOI: 10.1063/1.5017458

Piezoresistive Effect in the [Fe(Htrz) 2 (trz)](BF 4 ) Spin Crossover Complex

Author(s): Andrei Diaconu, Simona-Lacramioara Lupu, Ionela Rusu, Ioan-Marian Risca, Lionel Salmon, Gábor Molnár, Azzedine Bousseksou, Philippe Demont, Aurelian Rotaru
Published in: The Journal of Physical Chemistry Letters, Issue 8/13, 2017, Page(s) 3147-3151, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.7b01111

Chiral and Racemic Spin Crossover Polymorphs in a Family of Mononuclear Iron(II) Compounds

Author(s): Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real
Published in: Inorganic Chemistry, Issue 56/21, 2017, Page(s) 13535-13546, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.7b02272

Pressure effect investigations on spin-crossover coordination compounds

Author(s): Ana B. Gaspar, Gábor Molnár, Aurelian Rotaru, Helena J. Shepherd
Published in: Comptes Rendus Chimie, Issue 21/12, 2018, Page(s) 1095-1120, ISSN 1631-0748
Publisher: Elsevier Masson
DOI: 10.1016/j.crci.2018.07.010

Room Temperature Hysteretic Spin Crossover in a New Cyanoheterometallic Framework

Author(s): Volodymyr M. Hiiuk, Sergiu Sova, Aurelian Rotaru, Vadim Ksenofontov, Igor O. Fritsky, Il'ya A. Gural'skiy
Published in: Chemical Communications, Issue 55, 2019, Page(s) 3359-3362, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8cc10260k

Crystal structure and magnetic properties of (tris{4-[1-(2-methoxyethyl)imidazol-2-yl]-3-azabut-3-enyl}amine)iron(II) bis(hexafluoridophosphate)

Author(s): Kateryna Znovjyak, Igor O. Fritsky, Iryna A. Golenya, Tatiana Y. Sliva, Matti Haukka
Published in: Acta Crystallographica Section E Crystallographic Communications, Issue 75/3, 2019, Page(s) 358-361, ISSN 2056-9890
Publisher: -
DOI: 10.1107/s2056989019001531

Very Long-Lived Photogenerated High-Spin Phase of a Multistable Spin-Crossover Molecular Material

Author(s): Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard
Published in: Journal of the American Chemical Society, Issue 140/40, 2018, Page(s) 12870-12876, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.8b06042

Discrimination between two memory channels by molecular alloying in a doubly bistable spin crossover material

Author(s): Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José Antonio A Real Cabezos
Published in: Chemical Science, Issue 10, 2019, Page(s) 3807–3816, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8sc05256e

Bilayer Thin Films That Combine Luminescent and Spin Crossover Properties for an Efficient and Reversible Fluorescence Switching

Author(s): Alin-Ciprian Bas, Xavier Thompson, Lionel Salmon, Christophe Thibault, Gábor Molnár, Oleg Palamarciuc, Lucie Routaboul, Azzedine Bousseksou
Published in: Magnetochemistry, Issue 5/2, 2019, Page(s) 28, ISSN 2312-7481
Publisher: MDPI
DOI: 10.3390/magnetochemistry5020028

Effects of solvent vapor annealing on the crystallinity and spin crossover properties of thin films of [Fe(HB(tz)3)2]

Author(s): Alin-Ciprian Bas, Victoria Shalabaeva, Xavier Thompson, Laure Vendier, Lionel Salmon, Christophe Thibault, Gábor Molnár, Lucie Routaboul, Azzedine Bousseksou
Published in: Comptes Rendus Chimie, Issue 22/6-7, 2019, Page(s) 525-533, ISSN 1631-0748
Publisher: Elsevier Masson
DOI: 10.1016/j.crci.2019.03.002

Crystal structure of catena -poly[[gold(I)-μ-cyanido-[diaquabis(2-phenylpyrazine)iron(II)]-μ-cyanido] dicyanidogold(I)]

Author(s): Olesia I. Kucheriv, Diana D. Barakhtii, Sergey O. Malinkin, Sergiu Shova, Il'ya A. Gural'skiy
Published in: Acta Crystallographica Section E Crystallographic Communications, Issue 75/8, 2019, Page(s) 1149-1152, ISSN 2056-9890
Publisher: International Union of Crystallography
DOI: 10.1107/s2056989019009678

Pyridazine-Supported Polymeric Cyanometallates with Spin Transitions

Author(s): Il'ya A. Gural'skiy, Sergii I. Shylin, Vadim Ksenofontov, Wolfgang Tremel
Published in: European Journal of Inorganic Chemistry, Issue 2019/42, 2019, Page(s) 4532-4537, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.201900782

Crystal structure and magnetic properties of bis[butyltris(1 H -pyrazol-1-yl)borato]iron(II)

Author(s): Maksym Seredyuk, Kateryna Znovjyak, Igor O. Fritsky, Tatiana Y. Sliva, Mykola S. Slobodyanik
Published in: Acta Crystallographica Section E Crystallographic Communications, Issue 75/9, 2019, Page(s) 1327-1330, ISSN 2056-9890
Publisher: Wiley
DOI: 10.1107/s2056989019011137

Spin crossover in 2D iron( ii ) phthalazine cyanometallic complexes

Author(s): Volodymyr M. Hiiuk, Sergiu Shova, Aurelian Rotaru, Alexander A. Golub, Igor O. Fritsky, Il'ya A. Gural'skiy
Published in: Dalton Transactions, Issue 49/16, 2020, Page(s) 5302-5311, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0dt00783h

Hofmann-Like Frameworks Fe(2-methylpyrazine) n [M(CN) 2 ] 2 (M = Au, Ag): Spin-Crossover Defined by the Precious Metal

Author(s): Sergii I. Shylin, Olesia I. Kucheriv, Sergiu Shova, Vadim Ksenofontov, Wolfgang Tremel, Il’ya A. Gural’skiy
Published in: Inorganic Chemistry, 2020, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c00627

Broad-Band Dielectric Spectroscopy Reveals Peak Values of Conductivity and Permittivity Switching upon Spin Crossover

Author(s): Ion Soroceanu, Adrian Graur, Eugen Coca, Lionel Salmon, Gabor Molnar, Philippe Demont, Azzedine Bousseksou, Aurelian Rotaru
Published in: The Journal of Physical Chemistry Letters, Issue 10/23, 2019, Page(s) 7391-7396, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.9b02678

Two-Step Spin Crossover in Hofmann-Type Coordination Polymers [Fe(2-phenylpyrazine)2{M(CN)2}2] (M = Ag, Au)

Author(s): Volodymyr M. Hiiuk, Sergii I. Shylin, Diana D. Barakhtii, Dmytro M. Korytko, Volodymyr O. Kotsyubynsky, Aurelian Rotaru, Sergiu Shova, and Il’ya A. Gural’skiy
Published in: Inorg. Chem., 2022, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.1c03302

Pathway selection as a tool for crystal defect engineering: A case study with a functional coordination polymer

Author(s): Abrishamkar, Afshin; Suárez–García, Salvio; Sevim, Semih; Sorrenti, Alessandro; Pons, Ramon; Liu, Shi-Xia; Decurtins, Silvio; Aromí, Guillem; Aguilà, David; Pané, Salvador; deMello, Andrew J.; Rotaru, Aurelian; Ruiz–Molina, Daniel; Puigmartí-Luis, Josep
Published in: Applied Materials Today, 2020, ISSN 2352-9407
Publisher: Elsevier
DOI: 10.1016/j.apmt.2020.100632

Guest induced reversible on–off switching of elastic frustration in a 3D spin crossover coordination polymer with room temperature hysteretic behaviour

Author(s): Piñeiro-López, Lucía; Valverde-Muñoz, Francisco-Javier; Trzop, Elzbieta; Muñoz, M. Carmen; Seredyuk, Maksym; Castells-Gil, Javier; da Silva, Iván; Martí-Gastaldo, Carlos; Collet, Eric; Real, José Antonio
Published in: Chemical Science, Issue 4, 2020, ISSN 2041-6539
Publisher: RSC
DOI: 10.1039/D0SC04420B

Thermodynamical aspects of the spin crossover phenomenon

Author(s): Nicolazzi, William; Bousseksou, Azzedine
Published in: Comptes Rendus Chimie, Issue 18, 2018, ISSN 1631-0748
Publisher: Elsevier Masson
DOI: 10.1016/j.crci.2018.10.003

Anomalous Pressure Effects on the Electrical Conductivity of the Spin Crossover Complex [Fe(pyrazine){Au(CN)2}2]

Author(s): Gheorghe, Andrei-Cristian; Bibik, Yurii S.; Kucheriv, Olesia I.; Barakhtii, Diana D.; Boicu, Marin-Vlad; Rusu, Ionela; Diaconu, Andrei; Gural'skiy, Il'ya A.; Molnár, Gábor; Rotaru, Aurelian
Published in: Magnetochemistry, Issue 21, 2020, Page(s) 31, ISSN 2312-7481
Publisher: MDPI
DOI: 10.3390/magnetochemistry6030031

Spin crossover in iron(ii) Hofmann clathrates analogues with 1,2,3-triazole

Author(s): Kuzevanova, Iryna S.; Kucheriv, Olesia I.; Hiiuk, Volodymyr M.; Naumova, Dina D.; Shova, Sergiu; Shylin, Sergii I.; Kotsyubynsky, Volodymyr O.; Rotaru, Aurelian; Fritsky, Igor O.; Gural'skiy, Il'ya A.
Published in: Dalton Trans., Issue 19, 2021, ISSN 1477-9234
Publisher: RSC
DOI: 10.1039/D1DT01544C

Colossal expansion and fast motion in spin-crossover@polymer actuators

Author(s): Piedrahita-Bello, Mario; Angulo-Cervera, José Elias; Enriquez-Cabrera, Alejandro; Molnár, Gábor; Tondu, Bertrand; Salmon, Lionel; Bousseksou, Azzedine
Published in: Materials Horizons, Issue 1, 2021, ISSN 2051-6355
Publisher: RSC
DOI: 10.1039/D1MH00966D

Unprecedented switching endurance affords for high-resolution surface temperature mapping using a spin-crossover film

Author(s): Karl Ridier, Alin-Ciprian Bas, Yuteng Zhang, Lucie Routaboul, Lionel Salmon, Gábor Molnár, Christian Bergaud & Azzedine Bousseksou
Published in: Nature Communications, 2020, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-020-17362-7

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