Multifunctional Spin Crossover Materials

Risultati finali

Two scientific papers on the topic of WP3

One scientific paper on the topic of WP4

Two scientific papers on the topic of WP2.
One scientific paper on the topic of WP5

One scientific paper on the topic of WP5

Two scientific papers on the topic of WP1
Internet website

Project internet website

Progress Report 1

Report on the progress in the implementation of the project during the 1st year.

Reports from the visit describing ‘training through research of WP4.

Reports from the visit describing training through research of WP4

Reports from the visit describing ‘training through research' of WP3.

Reports from the visit describing training through research of WP3

Reports from the visit describing ‘training through research’ of WP1.
Reports from the visit describing ‘training through research' of WP5.

Reports from the visit describing training through research of WP5

Reports from the visit describing ‘training through research’ of WP2.

Progress report 2

Report on the progress of the project during the third year of the project.

Report on ethics

Report on the management of all possible ethical issues related to the project

Pubblicazioni

Pressure gradient effect on spin-crossover materials: Experiment vs theory

Autori: Ionela Rusu, Ioan Cozmin Manolache-Rusu, Andrei Diaconu, Oleg Palamarciuc, Il’ya A. Gural'skiy, Gabor Molnar, and Aurelian Rotaru
Pubblicato in: Journal of Applied Physics, 2021, ISSN 0021-8979
Editore: American Institute of Physics
DOI: 10.1063/5.0042582

Crystal structure of {N1,N3-bis[(1-benzyl-1H-1,2,3-triazol-4-yl)methylidene]-2,2-dimethylpropane-1,3-diamine}bis(thiocyanato-κN)iron(II)

Autori: Znovjyak, Kateryna; Seredyuk, Maksym; Malinkin, Sergey O.; Shova, Sergiu; Soliev, Lutfullo
Pubblicato in: Acta Crystallographica Section E, Numero 13, 2020, ISSN 2056-9890
Editore: IUCr
DOI: 10.1107/S2056989020012608

Effect of Guest Molecules on Spin Transition Temperature in Loaded Hofmann-Like Clathrates with Improved Porosity

Autori: Lucía Piñeiro-López,Maksym Seredyuk,M. Carmen Muñoz,José A. Real
Pubblicato in: European Journal of Inorganic Chemistry, 2020, Pagina/e 764-769, ISSN 1099-0682
Editore: Wiley-VCH GmbH
DOI: 10.1002/ejic.201901347

Ligand substitution effects on the charge transport properties of the spin crossover complex [Fe(Htrz)1+y−x(trz)2−y(NH2trz)x](BF4)y·nH2O

Autori: Soroceanu, Ion; Lupu, Simona-Lacramioara; Rusu, Ionela; Piedrahita-Bello, Mario; Salmon, Lionel; Molnár, Gábor; Demont, Philippe; Bousseksou, Azzedine; Rotaru, Aurelian
Pubblicato in: Journal of Physics: Condensed Matter, Numero 3, 2020, ISSN 0953-8984
Editore: Institute of Physics Publishing
DOI: 10.1088/1361-648X/ab7ba2

Crystal structure of the mixed methanol and ethanol solvate of bis{3,4,5-trimethoxy-N′-[1-(pyridin-2-yl)ethylidene]benzohydrazidato}zinc(II)

Autori: Znovjyak, Kateryna; Fritsky, Igor O.; Sliva, Tatiana Y.; Amirkhanov, Vladimir M.; Seredyuk, Maksym
Pubblicato in: Acta Crystallographica Section E, Numero 2, 2020, ISSN 2056-9890
Editore: IUCr
DOI: 10.1107/S2056989020000857

Thermochromic Meltable Materials with Reverse Spin Transition Controlled by Chemical Design

Autori: Valverde-Muñoz F.-J., Seredyuk M., Muñoz M. C., Molnár G., Bibik Y. S., Real J. A.
Pubblicato in: Angewandte Chemie, International Edition, Numero 59 (42), 2020, Pagina/e 18632-18638, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202006453

Sequential Activation of Molecular and Macroscopic Spin-State Switching within the Hysteretic Region Following Pulsed Light Excitation

Autori: Karl Ridier,William Nicolazzi,Lionel Salmon,Gábor Molnár,Azzedine Bousseksou
Pubblicato in: Advanced Materials, 2021, ISSN 0935-9648
Editore: United Nations Industrial Developement Organization
DOI: 10.1002/adma.202105468

Mechano-electric coupling in P(VDF–TrFE)/spin crossover composites

Autori: Piedrahita-Bello, Mario; Martin, Baptiste; Salmon, Lionel; Molnár, Gábor; Demont, Philippe; Bousseksou, Azzedine
Pubblicato in: Journal of Materials Chemistry C, Numero 4, 2020, ISSN 2050-7534
Editore: Royal Society of Chemistry
DOI: 10.1039/D0TC00780C

4D printing with spin-crossover polymer composites

Autori: Mario Piedrahita-Bello, José Elias Angulo-Cervera, Rémi Courson, Gábor Molnár, Laurent Malaquin, Christophe Thibault, Bertrand Tondu, Lionel Salmon and Azzedine Bousseksou
Pubblicato in: Journal of Materials Chemistry C, 2020, ISSN 2050-7534
Editore: Royal Society of Chemistry
DOI: 10.1039/d0tc01532f

Direct Synthesis of Spin-Crossover Complexes: An Unexpectedly Revealed New Iron-Triazolic Structure

Autori: Valerii Y. Sirenko,Olesia I. Kucheriv,Dr. Aurelian Rotaru,Prof. Dr. Igor O. Fritsky,Dr. Il'ya A. Gural'skiy
Pubblicato in: European Journal of Inorganic Chemistry, 2020, Pagina/e 4523-4531, ISSN 1099-0682
Editore: Wiley-VCH GmbH
DOI: 10.1002/ejic.202000848

Crystal structure of poly[bis(μ-2-bromopyrazine)tetra-μ2-cyanido-dicopper(I)iron(II)]: a bimetallic metal-organic framework

Autori: Kucheriv, Olesia I.; Tokmenko, Inna I.; Matushko, Igor P.; Tsapyuk, Galyna G.; Gural'skiy, Il'ya A.
Pubblicato in: Acta Crystallographica Section E, Numero 2, 2018, ISSN 2056-9890
Editore: IUCr
DOI: 10.1107/S2056989018016638

Crystal structure of (N1,N3-bis{[1-(4-methoxybenzyl)-1H-1,2,3-triazol-4-yl]methylidene}-2,2-dimethylpropane-1,3-diamine)bis(thiocyanato)iron(II)

Autori: Znovjyak, Kateryna; Seredyuk, Maksym; Malinkin, Sergey O.; Golenya, Iryna A.; Sliva, Tatiana Y.; Shova, Sergiu; Mulloev, Nurullo U.
Pubblicato in: Acta Crystallographica Section E, Numero 18, 2021, ISSN 2056-9890
Editore: IUCr
DOI: 10.1107/S2056989021003662

Crystal structure of poly[[di-aqua-tetra-μ2-cyanido-platinum(II)iron(II)] methanol 4/3-solvate]: a three-dimensional Hofmann clathrate analogue

Autori: V. M. Hiiuk, V. Mykhailovych, S. Shova, I. A. Golenya and I. A. Gural'skiy
Pubblicato in: Acta Crystallographica Section E, 2022, ISSN 2056-9890
Editore: IUCr
DOI: 10.1107/s2056989022000573

Finite Size Effects on the Switching Dynamics of Spin-Crossover Thin Films Photoexcited by a Femtosecond Laser Pulse

Autori: Ridier, Karl; Bas, Alin-Ciprian; Shalabaeva, Victoria; Nicolazzi, William; Salmon, Lionel; Molnár, Gábor; Bousseksou, Azzedine; Lorenc, Maciej; Bertoni, Roman; Collet, Eric; Cailleau, Hervé
Pubblicato in: Advanced Materials, Numero 2, 2019, ISSN 0935-9648
Editore: United Nations Industrial Developement Organization
DOI: 10.1002/adma.201901361

Resistance switching in large-area vertical junctions of the molecular spin crossover complex [Fe(HB(tz)3)2]: ON/OFF ratios and device stability

Autori: Zhang, Yuteng; Séguy, Isabelle; Ridier, Karl; Shalabaeva, Victoria; Piedrahita-Bello, Mario; Rotaru, Aurelian; Salmon, Lionel; Molnár, Gábor; Bousseksou, Azzedine
Pubblicato in: Journal of Physics: Condensed Matter, Numero 1, 2020, ISSN 0953-8984
Editore: Institute of Physics Publishing
DOI: 10.1088/1361-648X/ab741e

Phase Stability of Spin-Crossover Nanoparticles Investigated by Synchrotron Mössbauer Spectroscopy and Small-Angle Neutron Scattering

Autori: Mikolasek, Mirko; Ridier, Karl; Bessas, Dimitrios; Cerantola, Valerio; Félix, Gautier; Chaboussant, Grégory; Piedrahita-Bello, Mario; Angulo-Cervera, Elias; Godard, Leá; Nicolazzi, William; Salmon, Lionel; Molnár, Gábor; Bousseksou, Azzedine
Pubblicato in: The Journal of Physical Chemistry Letters, Numero 3, 2019, ISSN 1948-7185
Editore: American Chemical Society
DOI: 10.1021/acs.jpclett.9b00335

Crystal structure of catena -poly[[[tetraaquairon(II)]- trans -μ-1,2-bis(pyridin-4-yl)ethene-κ 2 N : N ′] bis( p -toluenesulfonate) methanol disolvate]

Autori: Volodymyr M. Hiiuk, Diana D. Barakhty, Sergiu Shova, Ruslan A. Polunin, Il'ya A. Gural'skiy
Pubblicato in: Acta Crystallographica Section E Crystallographic Communications, Numero 73/12, 2017, Pagina/e 1977-1980, ISSN 2056-9890
Editore: International Union of Crystallography
DOI: 10.1107/s2056989017017054

Room temperature current modulation in large area electronic junctions of spin crossover thin films

Autori: Victoria Shalabaeva, Karl Ridier, Sylvain Rat, Maria D. Manrique-Juarez, Lionel Salmon, Isabelle Séguy, Aurelian Rotaru, Gábor Molnár, Azzedine Bousseksou
Pubblicato in: Applied Physics Letters, Numero 112/1, 2018, Pagina/e 013301, ISSN 0003-6951
Editore: American Institute of Physics
DOI: 10.1063/1.5017458

Piezoresistive Effect in the [Fe(Htrz) 2 (trz)](BF 4 ) Spin Crossover Complex

Autori: Andrei Diaconu, Simona-Lacramioara Lupu, Ionela Rusu, Ioan-Marian Risca, Lionel Salmon, Gábor Molnár, Azzedine Bousseksou, Philippe Demont, Aurelian Rotaru
Pubblicato in: The Journal of Physical Chemistry Letters, Numero 8/13, 2017, Pagina/e 3147-3151, ISSN 1948-7185
Editore: American Chemical Society
DOI: 10.1021/acs.jpclett.7b01111

Chiral and Racemic Spin Crossover Polymorphs in a Family of Mononuclear Iron(II) Compounds

Autori: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real
Pubblicato in: Inorganic Chemistry, Numero 56/21, 2017, Pagina/e 13535-13546, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.7b02272

Pressure effect investigations on spin-crossover coordination compounds

Autori: Ana B. Gaspar, Gábor Molnár, Aurelian Rotaru, Helena J. Shepherd
Pubblicato in: Comptes Rendus Chimie, Numero 21/12, 2018, Pagina/e 1095-1120, ISSN 1631-0748
Editore: Elsevier Masson
DOI: 10.1016/j.crci.2018.07.010

Room Temperature Hysteretic Spin Crossover in a New Cyanoheterometallic Framework

Autori: Volodymyr M. Hiiuk, Sergiu Sova, Aurelian Rotaru, Vadim Ksenofontov, Igor O. Fritsky, Il'ya A. Gural'skiy
Pubblicato in: Chemical Communications, Numero 55, 2019, Pagina/e 3359-3362, ISSN 1359-7345
Editore: Royal Society of Chemistry
DOI: 10.1039/c8cc10260k

Crystal structure and magnetic properties of (tris{4-[1-(2-methoxyethyl)imidazol-2-yl]-3-azabut-3-enyl}amine)iron(II) bis(hexafluoridophosphate)

Autori: Kateryna Znovjyak, Igor O. Fritsky, Iryna A. Golenya, Tatiana Y. Sliva, Matti Haukka
Pubblicato in: Acta Crystallographica Section E Crystallographic Communications, Numero 75/3, 2019, Pagina/e 358-361, ISSN 2056-9890
Editore: -
DOI: 10.1107/s2056989019001531

Very Long-Lived Photogenerated High-Spin Phase of a Multistable Spin-Crossover Molecular Material

Autori: Teresa Delgado, Antoine Tissot, Laure Guénée, Andreas Hauser, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, José Antonio Real, Sébastien Pillet, El-Eulmi Bendeif, Céline Besnard
Pubblicato in: Journal of the American Chemical Society, Numero 140/40, 2018, Pagina/e 12870-12876, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.8b06042

Discrimination between two memory channels by molecular alloying in a doubly bistable spin crossover material

Autori: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José Antonio A Real Cabezos
Pubblicato in: Chemical Science, Numero 10, 2019, Pagina/e 3807–3816, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/c8sc05256e

Bilayer Thin Films That Combine Luminescent and Spin Crossover Properties for an Efficient and Reversible Fluorescence Switching

Autori: Alin-Ciprian Bas, Xavier Thompson, Lionel Salmon, Christophe Thibault, Gábor Molnár, Oleg Palamarciuc, Lucie Routaboul, Azzedine Bousseksou
Pubblicato in: Magnetochemistry, Numero 5/2, 2019, Pagina/e 28, ISSN 2312-7481
Editore: MDPI
DOI: 10.3390/magnetochemistry5020028

Effects of solvent vapor annealing on the crystallinity and spin crossover properties of thin films of [Fe(HB(tz)3)2]

Autori: Alin-Ciprian Bas, Victoria Shalabaeva, Xavier Thompson, Laure Vendier, Lionel Salmon, Christophe Thibault, Gábor Molnár, Lucie Routaboul, Azzedine Bousseksou
Pubblicato in: Comptes Rendus Chimie, Numero 22/6-7, 2019, Pagina/e 525-533, ISSN 1631-0748
Editore: Elsevier Masson
DOI: 10.1016/j.crci.2019.03.002

Crystal structure of catena -poly[[gold(I)-μ-cyanido-[diaquabis(2-phenylpyrazine)iron(II)]-μ-cyanido] dicyanidogold(I)]

Autori: Olesia I. Kucheriv, Diana D. Barakhtii, Sergey O. Malinkin, Sergiu Shova, Il'ya A. Gural'skiy
Pubblicato in: Acta Crystallographica Section E Crystallographic Communications, Numero 75/8, 2019, Pagina/e 1149-1152, ISSN 2056-9890
Editore: International Union of Crystallography
DOI: 10.1107/s2056989019009678

Pyridazine-Supported Polymeric Cyanometallates with Spin Transitions

Autori: Il'ya A. Gural'skiy, Sergii I. Shylin, Vadim Ksenofontov, Wolfgang Tremel
Pubblicato in: European Journal of Inorganic Chemistry, Numero 2019/42, 2019, Pagina/e 4532-4537, ISSN 1434-1948
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.201900782

Crystal structure and magnetic properties of bis[butyltris(1 H -pyrazol-1-yl)borato]iron(II)

Autori: Maksym Seredyuk, Kateryna Znovjyak, Igor O. Fritsky, Tatiana Y. Sliva, Mykola S. Slobodyanik
Pubblicato in: Acta Crystallographica Section E Crystallographic Communications, Numero 75/9, 2019, Pagina/e 1327-1330, ISSN 2056-9890
Editore: Wiley
DOI: 10.1107/s2056989019011137

Spin crossover in 2D iron( ii ) phthalazine cyanometallic complexes

Autori: Volodymyr M. Hiiuk, Sergiu Shova, Aurelian Rotaru, Alexander A. Golub, Igor O. Fritsky, Il'ya A. Gural'skiy
Pubblicato in: Dalton Transactions, Numero 49/16, 2020, Pagina/e 5302-5311, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/d0dt00783h

Hofmann-Like Frameworks Fe(2-methylpyrazine) n [M(CN) 2 ] 2 (M = Au, Ag): Spin-Crossover Defined by the Precious Metal

Autori: Sergii I. Shylin, Olesia I. Kucheriv, Sergiu Shova, Vadim Ksenofontov, Wolfgang Tremel, Il’ya A. Gural’skiy
Pubblicato in: Inorganic Chemistry, 2020, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c00627

Broad-Band Dielectric Spectroscopy Reveals Peak Values of Conductivity and Permittivity Switching upon Spin Crossover

Autori: Ion Soroceanu, Adrian Graur, Eugen Coca, Lionel Salmon, Gabor Molnar, Philippe Demont, Azzedine Bousseksou, Aurelian Rotaru
Pubblicato in: The Journal of Physical Chemistry Letters, Numero 10/23, 2019, Pagina/e 7391-7396, ISSN 1948-7185
Editore: American Chemical Society
DOI: 10.1021/acs.jpclett.9b02678

Two-Step Spin Crossover in Hofmann-Type Coordination Polymers [Fe(2-phenylpyrazine)2{M(CN)2}2] (M = Ag, Au)

Autori: Volodymyr M. Hiiuk, Sergii I. Shylin, Diana D. Barakhtii, Dmytro M. Korytko, Volodymyr O. Kotsyubynsky, Aurelian Rotaru, Sergiu Shova, and Il’ya A. Gural’skiy
Pubblicato in: Inorg. Chem., 2022, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.1c03302

Pathway selection as a tool for crystal defect engineering: A case study with a functional coordination polymer

Autori: Abrishamkar, Afshin; Suárez–García, Salvio; Sevim, Semih; Sorrenti, Alessandro; Pons, Ramon; Liu, Shi-Xia; Decurtins, Silvio; Aromí, Guillem; Aguilà, David; Pané, Salvador; deMello, Andrew J.; Rotaru, Aurelian; Ruiz–Molina, Daniel; Puigmartí-Luis, Josep
Pubblicato in: Applied Materials Today, 2020, ISSN 2352-9407
Editore: Elsevier
DOI: 10.1016/j.apmt.2020.100632

Guest induced reversible on–off switching of elastic frustration in a 3D spin crossover coordination polymer with room temperature hysteretic behaviour

Autori: Piñeiro-López, Lucía; Valverde-Muñoz, Francisco-Javier; Trzop, Elzbieta; Muñoz, M. Carmen; Seredyuk, Maksym; Castells-Gil, Javier; da Silva, Iván; Martí-Gastaldo, Carlos; Collet, Eric; Real, José Antonio
Pubblicato in: Chemical Science, Numero 4, 2020, ISSN 2041-6539
Editore: RSC
DOI: 10.1039/D0SC04420B

Thermodynamical aspects of the spin crossover phenomenon

Autori: Nicolazzi, William; Bousseksou, Azzedine
Pubblicato in: Comptes Rendus Chimie, Numero 18, 2018, ISSN 1631-0748
Editore: Elsevier Masson
DOI: 10.1016/j.crci.2018.10.003

Anomalous Pressure Effects on the Electrical Conductivity of the Spin Crossover Complex [Fe(pyrazine){Au(CN)2}2]

Autori: Gheorghe, Andrei-Cristian; Bibik, Yurii S.; Kucheriv, Olesia I.; Barakhtii, Diana D.; Boicu, Marin-Vlad; Rusu, Ionela; Diaconu, Andrei; Gural'skiy, Il'ya A.; Molnár, Gábor; Rotaru, Aurelian
Pubblicato in: Magnetochemistry, Numero 21, 2020, Pagina/e 31, ISSN 2312-7481
Editore: MDPI
DOI: 10.3390/magnetochemistry6030031

Spin crossover in iron(ii) Hofmann clathrates analogues with 1,2,3-triazole

Autori: Kuzevanova, Iryna S.; Kucheriv, Olesia I.; Hiiuk, Volodymyr M.; Naumova, Dina D.; Shova, Sergiu; Shylin, Sergii I.; Kotsyubynsky, Volodymyr O.; Rotaru, Aurelian; Fritsky, Igor O.; Gural'skiy, Il'ya A.
Pubblicato in: Dalton Trans., Numero 19, 2021, ISSN 1477-9234
Editore: RSC
DOI: 10.1039/D1DT01544C

Colossal expansion and fast motion in spin-crossover@polymer actuators

Autori: Piedrahita-Bello, Mario; Angulo-Cervera, José Elias; Enriquez-Cabrera, Alejandro; Molnár, Gábor; Tondu, Bertrand; Salmon, Lionel; Bousseksou, Azzedine
Pubblicato in: Materials Horizons, Numero 1, 2021, ISSN 2051-6355
Editore: RSC
DOI: 10.1039/D1MH00966D

Unprecedented switching endurance affords for high-resolution surface temperature mapping using a spin-crossover film

Autori: Karl Ridier, Alin-Ciprian Bas, Yuteng Zhang, Lucie Routaboul, Lionel Salmon, Gábor Molnár, Christian Bergaud & Azzedine Bousseksou
Pubblicato in: Nature Communications, 2020, ISSN 2041-1723
Editore: Nature Publishing Group
DOI: 10.1038/s41467-020-17362-7

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