Objectif The main goal of this proposed project is the synthesis of new hybrid π-conjugated polymers for industrial use, which conductive and optical properties could be fine tuneable by the proper anionic metallacarboranes as doping agents. To achieve our goals two directions were chosen. In the first part we would like to investigate the effect of different boron clusters ([Co(C2B9HnX11-n)2]- X=Cl, Br, I) as doping agents on the conductive and photoluminescence properties of the poly(3,4-ethylenedioxythiophene) (PEDOT). Preliminary results suggest that the earlier used [Co(C2B9H11)2]- doping anion is redoxactive, thus it has a big influence on the formation and the properties of the polymer. Our expectation is that the halogen analogues ([Co(C2B9HnX11-n)2]-=Cl, Br, I) cover a wide range of redoxpotential, thus we can easily modify the properties of the new materials. During the second part we would like to tune both the conductive and photoluminescence properties of the poly(p-phenylene vinylene) (PPV). For this purpose different co-polymer planed to synthetized, which containing different amount of non-doped and self-doped monomer units. (In case of the self-doped polymer the doping anion is covalently linked to the monomer unit). We expect that the ratio of the non-doped and the self-doped has a strong influence both the conductive and photoluminescent properties, moreover the two different properties will be altered by the inclusion of functional side groups. Champ scientifique natural scienceschemical sciencesorganic chemistryorganic acidsnatural scienceschemical sciencespolymer sciencesnatural scienceschemical sciencesinorganic chemistryhalogensnatural scienceschemical sciencesinorganic chemistrymetalloidsnatural sciencesmathematicsapplied mathematicsmathematical model Programme(s) H2020-EU.1.3. - EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions Main Programme H2020-EU.1.3.2. - Nurturing excellence by means of cross-border and cross-sector mobility Thème(s) MSCA-IF-2016 - Individual Fellowships Appel à propositions H2020-MSCA-IF-2016 Voir d’autres projets de cet appel Régime de financement MSCA-IF-EF-ST - Standard EF Coordinateur AGENCIA ESTATAL CONSEJO SUPERIOR DE INVESTIGACIONES CIENTIFICAS Contribution nette de l'UE € 170 121,60 Adresse CALLE SERRANO 117 28006 Madrid Espagne Voir sur la carte Région Comunidad de Madrid Comunidad de Madrid Madrid Type d’activité Research Organisations Liens Contacter l’organisation Opens in new window Site web Opens in new window Participation aux programmes de R&I de l'UE Opens in new window Réseau de collaboration HORIZON Opens in new window Coût total € 170 121,60
