Metal-Mediated Methods for the Functionalization of White Phosphorus (P4)

Project Information

FunctionalP4

Grant agreement ID: 772299

DOI

10.3030/772299

Project closed

EC signature date 19 December 2017

Start date 1 September 2018

End date 31 August 2023

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 955 846,25

EU contribution

€ 1 955 846,25

Coordinated by

UNIVERSITAET REGENSBURG
Germany

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (28)

Hydrostannylation of Red Phosphorus: A Convenient Route to Monophosphines

Author(s): Jose Cammarata; Daniel J. Scott; Robert Wolf
Published in: Chemistry – A European Journal, Issue 2, 2022, Page(s) e202202456, ISSN 1521-3765
Publisher: Wiley-VCH
DOI: 10.1002/chem.202202456

Photocatalytic Arylation of P 4 and PH 3 : Reaction Development Through Mechanistic Insight

Author(s): Robin Rothfelder, Verena Streitferdt, Ulrich Lennert, Jose Cammarata, Daniel J. Scott, Kirsten Zeitler, Ruth M. Gschwind, Robert Wolf
Published in: Angewandte Chemie International Edition, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202110619

Aggregation and Degradation of White Phosphorus Mediated by N‐Heterocyclic Carbene Nickel(0) Complexes

Author(s): Gabriele Hierlmeier, Peter Coburger, Nicolaas P. Leest, Bas Bruin, Robert Wolf
Published in: Angewandte Chemie International Edition, Issue 59/33, 2020, Page(s) 14148-14153, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202004020

Diphosphorus Release and Heterocumulene Oligomerisation by Nickel Complexes

Author(s): Hierlmeier, Gabriele; Wolf, Robert
Published in: European Journal of Inorganic Chemistry, Issue 30, 2022, Page(s) e202101057, ISSN 1099-0682
Publisher: Wiley-VCH
DOI: 10.1002/ejic.202101057

An unusual Ni 2 Si 2 P 8 cluster formed by complexation and thermolysis

Author(s): Christoph G. P. Ziegler, Clemens Taube, John A. Kelly, Gabriele Hierlmeier, Maria Uttendorfer, Jan J. Weigand, Robert Wolf
Published in: Chemical Communications, Issue 56/90, 2020, Page(s) 14071-14074, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cc05365a

Transition‐Metal‐Mediated Functionalization of White Phosphorus

Author(s): Christian M. Hoidn, Daniel J. Scott, Robert Wolf
Published in: Chemistry – A European Journal, Issue 27/6, 2021, Page(s) 1886-1902, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202001854

Photocatalytic stannylation of white phosphorus

Author(s): Marion Till, Jose Cammarata, Robert Wolf, Daniel J. Scott
Published in: Chemical Communications, 2023, ISSN 1364-548X
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2cc03474c

Synthesis of monophosphines directly from white phosphorus

Author(s): Daniel J. Scott, Jose Cammarata, Maximilian Schimpf, Robert Wolf
Published in: Nature Chemistry, 2021, ISSN 1755-4330
Publisher: Nature Publishing Group
DOI: 10.1038/s41557-021-00657-7

Di-tert-butyldiphosphatetrahedrane as a Source of 1,2-Diphosphacyclobutadiene Ligands.

Author(s): Gabriele Hierlmeier; Peter Coburger; Peter Coburger; Daniel J. Scott; Thomas M. Maier; Stefan Pelties; Robert Wolf; Daniel Pividori; Karsten Meyer; Nicolaas P. van Leest; Bas de Bruin
Published in: Chemistry – A European Journal, Issue 3, 2021, Page(s) 14936-14946, ISSN 1521-3765
Publisher: Wiley-VCH
DOI: 10.1002/chem.202102335

Coordination chemistry of elemental phosphorus

Author(s): Leonardo Giusti, Vanessa R. Landaeta, Matteo Vanni, John A. Kelly, Robert Wolf, Maria Caporali
Published in: Coordination Chemistry Reviews, Issue 441, 2021, Page(s) 213927, ISSN 0010-8545
Publisher: Elsevier BV
DOI: 10.1016/j.ccr.2021.213927

Photochemical transformation of chlorobenzenes and white phosphorus into arylphosphines and phosphonium salts

Author(s): Till, Marion; Streitferdt, Verena; Scott, Daniel J.; Mende, Michael; Gschwind, Ruth M.; Wolf, Robert
Published in: Chemical Communications, Issue 19, 2022, Page(s) 1100-1103, ISSN 1364-548X
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1cc05691c

Bulking up Cp^BIG: A Penta-Terphenyl Cyclopentadienyl Ligand

Author(s): Robert Wolf; Gabriele Hierlmeier
Published in: Bulking up CpBIG: A Penta-Terphenyl Cyclopentadienyl Ligand, Issue 13, 2022, Page(s) 776–784, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.2c00009

Versatile Visible‐Light‐Driven Synthesis of Asymmetrical Phosphines and Phosphonium Salts

Author(s): Percia Beatrice Arockiam, Ulrich Lennert, Christina Graf, Robin Rothfelder, Daniel J. Scott, Tillmann G. Fischer, Kirsten Zeitler, Robert Wolf
Published in: Chemistry – A European Journal, Issue 26/69, 2020, Page(s) 16374-16382, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202002646

Low-Valence Anionic α-Diimine Iron Complexes: Synthesis, Characterization, and Catalytic Hydroboration Studies

Author(s): Thomas M. Maier, Martin Gawron, Peter Coburger, Michael Bodensteiner, Robert Wolf, Nicolaas P. van Leest, Bas de Bruin, Serhiy Demeshko, Franc Meyer
Published in: Inorganic Chemistry, Issue 59/21, 2020, Page(s) 16035-16052, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c02606

Isomerism and Biradical Character of Tetrapnictide Dianions: A Computational Study

Author(s): Peter Coburger, Robert Wolf, Hansjörg Grützmacher
Published in: European Journal of Inorganic Chemistry, Issue 2020/37, 2020, Page(s) 3580-3586, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.202000422

Synthesis and Characterization of Bidentate Isonitrile Iron Complexes

Author(s): Marion Till, John A. Kelly, Christoph G. P. Ziegler, Robert Wolf, Tianao Guo, Mark R. Ringenberg, Eugen Lutsker, Oliver Reiser
Published in: Organometallics, 2021, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.1c00042

Synthesis of a Cyclic Co 2 Sn 2 Cluster Using a Co – Synthon

Author(s): Christian M. Hoidn, Christian Rödl, Madison L. McCrea-Hendrick, Theresa Block, Rainer Pöttgen, Andreas W. Ehlers, Philip P. Power, Robert Wolf
Published in: Journal of the American Chemical Society, Issue 140/41, 2018, Page(s) 13195-13199, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.8b08517

Direct catalytic transformation of white phosphorus into arylphosphines and phosphonium salts

Author(s): Ulrich Lennert, Percia Beatrice Arockiam, Verena Streitferdt, Daniel J. Scott, Christian Rödl, Ruth M. Gschwind, Robert Wolf
Published in: Nature Catalysis, Issue 2/12, 2019, Page(s) 1101-1106, ISSN 2520-1158
Publisher: Nature Research
DOI: 10.1038/s41929-019-0378-4

[3+2] Fragmentation of a Pentaphosphido Ligand by Cyanide

Author(s): Christian M. Hoidn, Thomas M. Maier, Karolina Trabitsch, Jan J. Weigand, Robert Wolf
Published in: Angewandte Chemie International Edition, Issue 58/52, 2019, Page(s) 18931-18936, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201908744

Iron-Gallium and Cobalt-Gallium Tetraphosphido Complexes

Author(s): Christoph G. P. Ziegler, Felix Hennersdorf, Jan J. Weigand, Robert Wolf
Published in: Zeitschrift für anorganische und allgemeine Chemie, 2020, ISSN 0044-2313
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/zaac.201900351

Di‐ tert ‐butyldiphosphatetrahedrane: Catalytic Synthesis of the Elusive Phosphaalkyne Dimer

Author(s): Gabriele Hierlmeier, Peter Coburger, Michael Bodensteiner, Robert Wolf
Published in: Angewandte Chemie International Edition, Issue 58/47, 2019, Page(s) 16918-16922, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201910505

Functionalization of Pentaphosphorus Cations by Complexation

Author(s): Anup K. Adhikari, Christoph G. P. Ziegler, Kai Schwedtmann, Clemens Taube, Jan. J. Weigand, Robert Wolf
Published in: Angewandte Chemie International Edition, Issue 58/51, 2019, Page(s) 18584-18590, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201908998

Construction of alkyl-substituted pentaphosphido ligands in the coordination sphere of cobalt

Author(s): Christoph G. P. Ziegler, Thomas M. Maier, Stefan Pelties, Clemens Taube, Felix Hennersdorf, Andreas W. Ehlers, Jan J. Weigand, Robert Wolf
Published in: Chemical Science, Issue 10/5, 2019, Page(s) 1302-1308, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8sc04745f

Transition-Metal-Stabilized Heavy Tetraphospholide Anions

Author(s): John A. Kelly; Verena Streitferdt; Maria Dimitrova; Franz F. Westermair; Ruth M. Gschwind; Raphael J. F. Berger; Robert Wolf
Published in: Transition-Metal-Stabilized Heavy Tetraphospholide Anions, Issue 6, 2022, Page(s) 20434–20441, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c08754

Low-oxidation state cobalt–magnesium complexes: ion-pairing and reactivity

Author(s): John A. Kelly, Johannes Gramüller, Ruth M. Gschwind, Robert Wolf
Published in: Dalton Transactions, Issue 50/39, 2021, Page(s) 13985-13992, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1dt02621f

Di- tert -butyldiphosphatetrahedrane as a building block for phosphaalkenes and phosphirenes

Author(s): Gabriele Hierlmeier, Maria K. Uttendorfer, Robert Wolf
Published in: Chemical Communications, Issue 57/19, 2021, Page(s) 2356-2359, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cc07103j

Activation of Di‐ tert ‐butyldiphosphatetrahedrane: Access to ( t BuCP) n ( n= 2, 4) Ligand Frameworks by P−C Bond Cleavage

Author(s): Gabriele Hierlmeier, Robert Wolf
Published in: Angewandte Chemie International Edition, Issue 60/12, 2021, Page(s) 6435-6440, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202015680

Synthesis of a carborane-substituted bis(phosphanido) cobaltate( i ), ligand substitution, and unusual P 4 fragmentation

Author(s): Peter Coburger, Julia Leitl, Daniel J. Scott, Gabriele Hierlmeier, Ilya G. Shenderovich, Evamarie Hey-Hawkins, Robert Wolf
Published in: Chemical Science, Issue 12/33, 2021, Page(s) 11225-11235, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1sc02948g