Metal-Mediated Methods for the Functionalization of White Phosphorus (P4)

Project Information

FunctionalP4

Grant agreement ID: 772299

DOI 10.3030/772299

Project closed

EC signature date 19 December 2017

Start date 1 September 2018

End date 31 August 2023

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 955 846,25

EU contribution € 1 955 846,25

Coordinated by

UNIVERSITAET REGENSBURG
Germany

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Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (28)

Hydrostannylation of Red Phosphorus: A Convenient Route to Monophosphines

Author(s): Jose Cammarata; Daniel J. Scott; Robert Wolf
Published in: Chemistry – A European Journal, Issue 2, 2022, Page(s) e202202456, ISSN 1521-3765
Publisher: Wiley-VCH
DOI: 10.1002/chem.202202456

Photocatalytic Arylation of P 4 and PH 3 : Reaction Development Through Mechanistic Insight

Author(s): Robin Rothfelder, Verena Streitferdt, Ulrich Lennert, Jose Cammarata, Daniel J. Scott, Kirsten Zeitler, Ruth M. Gschwind, Robert Wolf
Published in: Angewandte Chemie International Edition, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202110619

Aggregation and Degradation of White Phosphorus Mediated by N‐Heterocyclic Carbene Nickel(0) Complexes

Author(s): Gabriele Hierlmeier, Peter Coburger, Nicolaas P. Leest, Bas Bruin, Robert Wolf
Published in: Angewandte Chemie International Edition, Issue 59/33, 2020, Page(s) 14148-14153, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202004020

Diphosphorus Release and Heterocumulene Oligomerisation by Nickel Complexes

Author(s): Hierlmeier, Gabriele; Wolf, Robert
Published in: European Journal of Inorganic Chemistry, Issue 30, 2022, Page(s) e202101057, ISSN 1099-0682
Publisher: Wiley-VCH
DOI: 10.1002/ejic.202101057

An unusual Ni 2 Si 2 P 8 cluster formed by complexation and thermolysis

Author(s): Christoph G. P. Ziegler, Clemens Taube, John A. Kelly, Gabriele Hierlmeier, Maria Uttendorfer, Jan J. Weigand, Robert Wolf
Published in: Chemical Communications, Issue 56/90, 2020, Page(s) 14071-14074, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cc05365a

Transition‐Metal‐Mediated Functionalization of White Phosphorus

Author(s): Christian M. Hoidn, Daniel J. Scott, Robert Wolf
Published in: Chemistry – A European Journal, Issue 27/6, 2021, Page(s) 1886-1902, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202001854

Photocatalytic stannylation of white phosphorus

Author(s): Marion Till, Jose Cammarata, Robert Wolf, Daniel J. Scott
Published in: Chemical Communications, 2023, ISSN 1364-548X
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2cc03474c

Synthesis of monophosphines directly from white phosphorus

Author(s): Daniel J. Scott, Jose Cammarata, Maximilian Schimpf, Robert Wolf
Published in: Nature Chemistry, 2021, ISSN 1755-4330
Publisher: Nature Publishing Group
DOI: 10.1038/s41557-021-00657-7

Di-tert-butyldiphosphatetrahedrane as a Source of 1,2-Diphosphacyclobutadiene Ligands.

Author(s): Gabriele Hierlmeier; Peter Coburger; Peter Coburger; Daniel J. Scott; Thomas M. Maier; Stefan Pelties; Robert Wolf; Daniel Pividori; Karsten Meyer; Nicolaas P. van Leest; Bas de Bruin
Published in: Chemistry – A European Journal, Issue 3, 2021, Page(s) 14936-14946, ISSN 1521-3765
Publisher: Wiley-VCH
DOI: 10.1002/chem.202102335

Coordination chemistry of elemental phosphorus

Author(s): Leonardo Giusti, Vanessa R. Landaeta, Matteo Vanni, John A. Kelly, Robert Wolf, Maria Caporali
Published in: Coordination Chemistry Reviews, Issue 441, 2021, Page(s) 213927, ISSN 0010-8545
Publisher: Elsevier BV
DOI: 10.1016/j.ccr.2021.213927

Photochemical transformation of chlorobenzenes and white phosphorus into arylphosphines and phosphonium salts

Author(s): Till, Marion; Streitferdt, Verena; Scott, Daniel J.; Mende, Michael; Gschwind, Ruth M.; Wolf, Robert
Published in: Chemical Communications, Issue 19, 2022, Page(s) 1100-1103, ISSN 1364-548X
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1cc05691c

Bulking up Cp^BIG: A Penta-Terphenyl Cyclopentadienyl Ligand

Author(s): Robert Wolf; Gabriele Hierlmeier
Published in: Bulking up CpBIG: A Penta-Terphenyl Cyclopentadienyl Ligand, Issue 13, 2022, Page(s) 776–784, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.2c00009

Versatile Visible‐Light‐Driven Synthesis of Asymmetrical Phosphines and Phosphonium Salts

Author(s): Percia Beatrice Arockiam, Ulrich Lennert, Christina Graf, Robin Rothfelder, Daniel J. Scott, Tillmann G. Fischer, Kirsten Zeitler, Robert Wolf
Published in: Chemistry – A European Journal, Issue 26/69, 2020, Page(s) 16374-16382, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202002646

Low-Valence Anionic α-Diimine Iron Complexes: Synthesis, Characterization, and Catalytic Hydroboration Studies

Author(s): Thomas M. Maier, Martin Gawron, Peter Coburger, Michael Bodensteiner, Robert Wolf, Nicolaas P. van Leest, Bas de Bruin, Serhiy Demeshko, Franc Meyer
Published in: Inorganic Chemistry, Issue 59/21, 2020, Page(s) 16035-16052, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c02606

Isomerism and Biradical Character of Tetrapnictide Dianions: A Computational Study

Author(s): Peter Coburger, Robert Wolf, Hansjörg Grützmacher
Published in: European Journal of Inorganic Chemistry, Issue 2020/37, 2020, Page(s) 3580-3586, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.202000422

Synthesis and Characterization of Bidentate Isonitrile Iron Complexes

Author(s): Marion Till, John A. Kelly, Christoph G. P. Ziegler, Robert Wolf, Tianao Guo, Mark R. Ringenberg, Eugen Lutsker, Oliver Reiser
Published in: Organometallics, 2021, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.1c00042

Synthesis of a Cyclic Co 2 Sn 2 Cluster Using a Co – Synthon

Author(s): Christian M. Hoidn, Christian Rödl, Madison L. McCrea-Hendrick, Theresa Block, Rainer Pöttgen, Andreas W. Ehlers, Philip P. Power, Robert Wolf
Published in: Journal of the American Chemical Society, Issue 140/41, 2018, Page(s) 13195-13199, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.8b08517

Direct catalytic transformation of white phosphorus into arylphosphines and phosphonium salts

Author(s): Ulrich Lennert, Percia Beatrice Arockiam, Verena Streitferdt, Daniel J. Scott, Christian Rödl, Ruth M. Gschwind, Robert Wolf
Published in: Nature Catalysis, Issue 2/12, 2019, Page(s) 1101-1106, ISSN 2520-1158
Publisher: Nature Research
DOI: 10.1038/s41929-019-0378-4

[3+2] Fragmentation of a Pentaphosphido Ligand by Cyanide

Author(s): Christian M. Hoidn, Thomas M. Maier, Karolina Trabitsch, Jan J. Weigand, Robert Wolf
Published in: Angewandte Chemie International Edition, Issue 58/52, 2019, Page(s) 18931-18936, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201908744

Iron-Gallium and Cobalt-Gallium Tetraphosphido Complexes

Author(s): Christoph G. P. Ziegler, Felix Hennersdorf, Jan J. Weigand, Robert Wolf
Published in: Zeitschrift für anorganische und allgemeine Chemie, 2020, ISSN 0044-2313
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/zaac.201900351

Di‐ tert ‐butyldiphosphatetrahedrane: Catalytic Synthesis of the Elusive Phosphaalkyne Dimer

Author(s): Gabriele Hierlmeier, Peter Coburger, Michael Bodensteiner, Robert Wolf
Published in: Angewandte Chemie International Edition, Issue 58/47, 2019, Page(s) 16918-16922, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201910505

Functionalization of Pentaphosphorus Cations by Complexation

Author(s): Anup K. Adhikari, Christoph G. P. Ziegler, Kai Schwedtmann, Clemens Taube, Jan. J. Weigand, Robert Wolf
Published in: Angewandte Chemie International Edition, Issue 58/51, 2019, Page(s) 18584-18590, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201908998

Construction of alkyl-substituted pentaphosphido ligands in the coordination sphere of cobalt

Author(s): Christoph G. P. Ziegler, Thomas M. Maier, Stefan Pelties, Clemens Taube, Felix Hennersdorf, Andreas W. Ehlers, Jan J. Weigand, Robert Wolf
Published in: Chemical Science, Issue 10/5, 2019, Page(s) 1302-1308, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8sc04745f

Transition-Metal-Stabilized Heavy Tetraphospholide Anions

Author(s): John A. Kelly; Verena Streitferdt; Maria Dimitrova; Franz F. Westermair; Ruth M. Gschwind; Raphael J. F. Berger; Robert Wolf
Published in: Transition-Metal-Stabilized Heavy Tetraphospholide Anions, Issue 6, 2022, Page(s) 20434–20441, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c08754

Low-oxidation state cobalt–magnesium complexes: ion-pairing and reactivity

Author(s): John A. Kelly, Johannes Gramüller, Ruth M. Gschwind, Robert Wolf
Published in: Dalton Transactions, Issue 50/39, 2021, Page(s) 13985-13992, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1dt02621f

Di- tert -butyldiphosphatetrahedrane as a building block for phosphaalkenes and phosphirenes

Author(s): Gabriele Hierlmeier, Maria K. Uttendorfer, Robert Wolf
Published in: Chemical Communications, Issue 57/19, 2021, Page(s) 2356-2359, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cc07103j

Activation of Di‐ tert ‐butyldiphosphatetrahedrane: Access to ( t BuCP) n ( n= 2, 4) Ligand Frameworks by P−C Bond Cleavage

Author(s): Gabriele Hierlmeier, Robert Wolf
Published in: Angewandte Chemie International Edition, Issue 60/12, 2021, Page(s) 6435-6440, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202015680

Synthesis of a carborane-substituted bis(phosphanido) cobaltate( i ), ligand substitution, and unusual P 4 fragmentation

Author(s): Peter Coburger, Julia Leitl, Daniel J. Scott, Gabriele Hierlmeier, Ilya G. Shenderovich, Evamarie Hey-Hawkins, Robert Wolf
Published in: Chemical Science, Issue 12/33, 2021, Page(s) 11225-11235, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1sc02948g