Metal-Mediated Methods for the Functionalization of White Phosphorus (P4)

Información del proyecto

FunctionalP4

Identificador del acuerdo de subvención: 772299

DOI 10.3030/772299

Proyecto cerrado

Fecha de la firma de la CE 19 Diciembre 2017

Fecha de inicio 1 Septiembre 2018

Fecha de finalización 31 Agosto 2023

Financiado con arreglo a

• EXCELLENT SCIENCE - European Research Council (ERC)

Coste total € 1 955 846,25

Aportación de la UE € 1 955 846,25

Coordinado por

UNIVERSITAET REGENSBURG
Germany

Publicaciones

Peer reviewed articles (28)

Hydrostannylation of Red Phosphorus: A Convenient Route to Monophosphines

Autores: Jose Cammarata; Daniel J. Scott; Robert Wolf
Publicado en: Chemistry – A European Journal, Edición 2, 2022, Página(s) e202202456, ISSN 1521-3765
Editor: Wiley-VCH
DOI: 10.1002/chem.202202456

Photocatalytic Arylation of P 4 and PH 3 : Reaction Development Through Mechanistic Insight

Autores: Robin Rothfelder, Verena Streitferdt, Ulrich Lennert, Jose Cammarata, Daniel J. Scott, Kirsten Zeitler, Ruth M. Gschwind, Robert Wolf
Publicado en: Angewandte Chemie International Edition, 2021, ISSN 1433-7851
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202110619

Aggregation and Degradation of White Phosphorus Mediated by N‐Heterocyclic Carbene Nickel(0) Complexes

Autores: Gabriele Hierlmeier, Peter Coburger, Nicolaas P. Leest, Bas Bruin, Robert Wolf
Publicado en: Angewandte Chemie International Edition, Edición 59/33, 2020, Página(s) 14148-14153, ISSN 1433-7851
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202004020

Diphosphorus Release and Heterocumulene Oligomerisation by Nickel Complexes

Autores: Hierlmeier, Gabriele; Wolf, Robert
Publicado en: European Journal of Inorganic Chemistry, Edición 30, 2022, Página(s) e202101057, ISSN 1099-0682
Editor: Wiley-VCH
DOI: 10.1002/ejic.202101057

An unusual Ni 2 Si 2 P 8 cluster formed by complexation and thermolysis

Autores: Christoph G. P. Ziegler, Clemens Taube, John A. Kelly, Gabriele Hierlmeier, Maria Uttendorfer, Jan J. Weigand, Robert Wolf
Publicado en: Chemical Communications, Edición 56/90, 2020, Página(s) 14071-14074, ISSN 1359-7345
Editor: Royal Society of Chemistry
DOI: 10.1039/d0cc05365a

Transition‐Metal‐Mediated Functionalization of White Phosphorus

Autores: Christian M. Hoidn, Daniel J. Scott, Robert Wolf
Publicado en: Chemistry – A European Journal, Edición 27/6, 2021, Página(s) 1886-1902, ISSN 0947-6539
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202001854

Photocatalytic stannylation of white phosphorus

Autores: Marion Till, Jose Cammarata, Robert Wolf, Daniel J. Scott
Publicado en: Chemical Communications, 2023, ISSN 1364-548X
Editor: Royal Society of Chemistry
DOI: 10.1039/d2cc03474c

Synthesis of monophosphines directly from white phosphorus

Autores: Daniel J. Scott, Jose Cammarata, Maximilian Schimpf, Robert Wolf
Publicado en: Nature Chemistry, 2021, ISSN 1755-4330
Editor: Nature Publishing Group
DOI: 10.1038/s41557-021-00657-7

Di-tert-butyldiphosphatetrahedrane as a Source of 1,2-Diphosphacyclobutadiene Ligands.

Autores: Gabriele Hierlmeier; Peter Coburger; Peter Coburger; Daniel J. Scott; Thomas M. Maier; Stefan Pelties; Robert Wolf; Daniel Pividori; Karsten Meyer; Nicolaas P. van Leest; Bas de Bruin
Publicado en: Chemistry – A European Journal, Edición 3, 2021, Página(s) 14936-14946, ISSN 1521-3765
Editor: Wiley-VCH
DOI: 10.1002/chem.202102335

Coordination chemistry of elemental phosphorus

Autores: Leonardo Giusti, Vanessa R. Landaeta, Matteo Vanni, John A. Kelly, Robert Wolf, Maria Caporali
Publicado en: Coordination Chemistry Reviews, Edición 441, 2021, Página(s) 213927, ISSN 0010-8545
Editor: Elsevier BV
DOI: 10.1016/j.ccr.2021.213927

Photochemical transformation of chlorobenzenes and white phosphorus into arylphosphines and phosphonium salts

Autores: Till, Marion; Streitferdt, Verena; Scott, Daniel J.; Mende, Michael; Gschwind, Ruth M.; Wolf, Robert
Publicado en: Chemical Communications, Edición 19, 2022, Página(s) 1100-1103, ISSN 1364-548X
Editor: Royal Society of Chemistry
DOI: 10.1039/d1cc05691c

Bulking up Cp^BIG: A Penta-Terphenyl Cyclopentadienyl Ligand

Autores: Robert Wolf; Gabriele Hierlmeier
Publicado en: Bulking up CpBIG: A Penta-Terphenyl Cyclopentadienyl Ligand, Edición 13, 2022, Página(s) 776–784, ISSN 0276-7333
Editor: American Chemical Society
DOI: 10.1021/acs.organomet.2c00009

Versatile Visible‐Light‐Driven Synthesis of Asymmetrical Phosphines and Phosphonium Salts

Autores: Percia Beatrice Arockiam, Ulrich Lennert, Christina Graf, Robin Rothfelder, Daniel J. Scott, Tillmann G. Fischer, Kirsten Zeitler, Robert Wolf
Publicado en: Chemistry – A European Journal, Edición 26/69, 2020, Página(s) 16374-16382, ISSN 0947-6539
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202002646

Low-Valence Anionic α-Diimine Iron Complexes: Synthesis, Characterization, and Catalytic Hydroboration Studies

Autores: Thomas M. Maier, Martin Gawron, Peter Coburger, Michael Bodensteiner, Robert Wolf, Nicolaas P. van Leest, Bas de Bruin, Serhiy Demeshko, Franc Meyer
Publicado en: Inorganic Chemistry, Edición 59/21, 2020, Página(s) 16035-16052, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c02606

Isomerism and Biradical Character of Tetrapnictide Dianions: A Computational Study

Autores: Peter Coburger, Robert Wolf, Hansjörg Grützmacher
Publicado en: European Journal of Inorganic Chemistry, Edición 2020/37, 2020, Página(s) 3580-3586, ISSN 1434-1948
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.202000422

Synthesis and Characterization of Bidentate Isonitrile Iron Complexes

Autores: Marion Till, John A. Kelly, Christoph G. P. Ziegler, Robert Wolf, Tianao Guo, Mark R. Ringenberg, Eugen Lutsker, Oliver Reiser
Publicado en: Organometallics, 2021, ISSN 0276-7333
Editor: American Chemical Society
DOI: 10.1021/acs.organomet.1c00042

Synthesis of a Cyclic Co 2 Sn 2 Cluster Using a Co – Synthon

Autores: Christian M. Hoidn, Christian Rödl, Madison L. McCrea-Hendrick, Theresa Block, Rainer Pöttgen, Andreas W. Ehlers, Philip P. Power, Robert Wolf
Publicado en: Journal of the American Chemical Society, Edición 140/41, 2018, Página(s) 13195-13199, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/jacs.8b08517

Direct catalytic transformation of white phosphorus into arylphosphines and phosphonium salts

Autores: Ulrich Lennert, Percia Beatrice Arockiam, Verena Streitferdt, Daniel J. Scott, Christian Rödl, Ruth M. Gschwind, Robert Wolf
Publicado en: Nature Catalysis, Edición 2/12, 2019, Página(s) 1101-1106, ISSN 2520-1158
Editor: Nature Research
DOI: 10.1038/s41929-019-0378-4

[3+2] Fragmentation of a Pentaphosphido Ligand by Cyanide

Autores: Christian M. Hoidn, Thomas M. Maier, Karolina Trabitsch, Jan J. Weigand, Robert Wolf
Publicado en: Angewandte Chemie International Edition, Edición 58/52, 2019, Página(s) 18931-18936, ISSN 1433-7851
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201908744

Iron-Gallium and Cobalt-Gallium Tetraphosphido Complexes

Autores: Christoph G. P. Ziegler, Felix Hennersdorf, Jan J. Weigand, Robert Wolf
Publicado en: Zeitschrift für anorganische und allgemeine Chemie, 2020, ISSN 0044-2313
Editor: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/zaac.201900351

Di‐ tert ‐butyldiphosphatetrahedrane: Catalytic Synthesis of the Elusive Phosphaalkyne Dimer

Autores: Gabriele Hierlmeier, Peter Coburger, Michael Bodensteiner, Robert Wolf
Publicado en: Angewandte Chemie International Edition, Edición 58/47, 2019, Página(s) 16918-16922, ISSN 1433-7851
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201910505

Functionalization of Pentaphosphorus Cations by Complexation

Autores: Anup K. Adhikari, Christoph G. P. Ziegler, Kai Schwedtmann, Clemens Taube, Jan. J. Weigand, Robert Wolf
Publicado en: Angewandte Chemie International Edition, Edición 58/51, 2019, Página(s) 18584-18590, ISSN 1433-7851
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201908998

Construction of alkyl-substituted pentaphosphido ligands in the coordination sphere of cobalt

Autores: Christoph G. P. Ziegler, Thomas M. Maier, Stefan Pelties, Clemens Taube, Felix Hennersdorf, Andreas W. Ehlers, Jan J. Weigand, Robert Wolf
Publicado en: Chemical Science, Edición 10/5, 2019, Página(s) 1302-1308, ISSN 2041-6520
Editor: Royal Society of Chemistry
DOI: 10.1039/c8sc04745f

Transition-Metal-Stabilized Heavy Tetraphospholide Anions

Autores: John A. Kelly; Verena Streitferdt; Maria Dimitrova; Franz F. Westermair; Ruth M. Gschwind; Raphael J. F. Berger; Robert Wolf
Publicado en: Transition-Metal-Stabilized Heavy Tetraphospholide Anions, Edición 6, 2022, Página(s) 20434–20441, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/jacs.2c08754

Low-oxidation state cobalt–magnesium complexes: ion-pairing and reactivity

Autores: John A. Kelly, Johannes Gramüller, Ruth M. Gschwind, Robert Wolf
Publicado en: Dalton Transactions, Edición 50/39, 2021, Página(s) 13985-13992, ISSN 1477-9226
Editor: Royal Society of Chemistry
DOI: 10.1039/d1dt02621f

Di- tert -butyldiphosphatetrahedrane as a building block for phosphaalkenes and phosphirenes

Autores: Gabriele Hierlmeier, Maria K. Uttendorfer, Robert Wolf
Publicado en: Chemical Communications, Edición 57/19, 2021, Página(s) 2356-2359, ISSN 1359-7345
Editor: Royal Society of Chemistry
DOI: 10.1039/d0cc07103j

Activation of Di‐ tert ‐butyldiphosphatetrahedrane: Access to ( t BuCP) n ( n= 2, 4) Ligand Frameworks by P−C Bond Cleavage

Autores: Gabriele Hierlmeier, Robert Wolf
Publicado en: Angewandte Chemie International Edition, Edición 60/12, 2021, Página(s) 6435-6440, ISSN 1433-7851
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202015680

Synthesis of a carborane-substituted bis(phosphanido) cobaltate( i ), ligand substitution, and unusual P 4 fragmentation

Autores: Peter Coburger, Julia Leitl, Daniel J. Scott, Gabriele Hierlmeier, Ilya G. Shenderovich, Evamarie Hey-Hawkins, Robert Wolf
Publicado en: Chemical Science, Edición 12/33, 2021, Página(s) 11225-11235, ISSN 2041-6520
Editor: Royal Society of Chemistry
DOI: 10.1039/d1sc02948g