Metal-Mediated Methods for the Functionalization of White Phosphorus (P4)

Informazioni relative al progetto

FunctionalP4

ID dell’accordo di sovvenzione: 772299

DOI 10.3030/772299

Progetto chiuso

Data della firma CE 19 Dicembre 2017

Data di avvio 1 Settembre 2018

Data di completamento 31 Agosto 2023

Finanziato da

• EXCELLENT SCIENCE - European Research Council (ERC)

Costo totale € 1 955 846,25

Contributo UE € 1 955 846,25

Coordinato da

UNIVERSITAET REGENSBURG
Germany

Pubblicazioni

Peer reviewed articles (28)

Hydrostannylation of Red Phosphorus: A Convenient Route to Monophosphines

Autori: Jose Cammarata; Daniel J. Scott; Robert Wolf
Pubblicato in: Chemistry – A European Journal, Numero 2, 2022, Pagina/e e202202456, ISSN 1521-3765
Editore: Wiley-VCH
DOI: 10.1002/chem.202202456

Photocatalytic Arylation of P 4 and PH 3 : Reaction Development Through Mechanistic Insight

Autori: Robin Rothfelder, Verena Streitferdt, Ulrich Lennert, Jose Cammarata, Daniel J. Scott, Kirsten Zeitler, Ruth M. Gschwind, Robert Wolf
Pubblicato in: Angewandte Chemie International Edition, 2021, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202110619

Aggregation and Degradation of White Phosphorus Mediated by N‐Heterocyclic Carbene Nickel(0) Complexes

Autori: Gabriele Hierlmeier, Peter Coburger, Nicolaas P. Leest, Bas Bruin, Robert Wolf
Pubblicato in: Angewandte Chemie International Edition, Numero 59/33, 2020, Pagina/e 14148-14153, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202004020

Diphosphorus Release and Heterocumulene Oligomerisation by Nickel Complexes

Autori: Hierlmeier, Gabriele; Wolf, Robert
Pubblicato in: European Journal of Inorganic Chemistry, Numero 30, 2022, Pagina/e e202101057, ISSN 1099-0682
Editore: Wiley-VCH
DOI: 10.1002/ejic.202101057

An unusual Ni 2 Si 2 P 8 cluster formed by complexation and thermolysis

Autori: Christoph G. P. Ziegler, Clemens Taube, John A. Kelly, Gabriele Hierlmeier, Maria Uttendorfer, Jan J. Weigand, Robert Wolf
Pubblicato in: Chemical Communications, Numero 56/90, 2020, Pagina/e 14071-14074, ISSN 1359-7345
Editore: Royal Society of Chemistry
DOI: 10.1039/d0cc05365a

Transition‐Metal‐Mediated Functionalization of White Phosphorus

Autori: Christian M. Hoidn, Daniel J. Scott, Robert Wolf
Pubblicato in: Chemistry – A European Journal, Numero 27/6, 2021, Pagina/e 1886-1902, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202001854

Photocatalytic stannylation of white phosphorus

Autori: Marion Till, Jose Cammarata, Robert Wolf, Daniel J. Scott
Pubblicato in: Chemical Communications, 2023, ISSN 1364-548X
Editore: Royal Society of Chemistry
DOI: 10.1039/d2cc03474c

Synthesis of monophosphines directly from white phosphorus

Autori: Daniel J. Scott, Jose Cammarata, Maximilian Schimpf, Robert Wolf
Pubblicato in: Nature Chemistry, 2021, ISSN 1755-4330
Editore: Nature Publishing Group
DOI: 10.1038/s41557-021-00657-7

Di-tert-butyldiphosphatetrahedrane as a Source of 1,2-Diphosphacyclobutadiene Ligands.

Autori: Gabriele Hierlmeier; Peter Coburger; Peter Coburger; Daniel J. Scott; Thomas M. Maier; Stefan Pelties; Robert Wolf; Daniel Pividori; Karsten Meyer; Nicolaas P. van Leest; Bas de Bruin
Pubblicato in: Chemistry – A European Journal, Numero 3, 2021, Pagina/e 14936-14946, ISSN 1521-3765
Editore: Wiley-VCH
DOI: 10.1002/chem.202102335

Coordination chemistry of elemental phosphorus

Autori: Leonardo Giusti, Vanessa R. Landaeta, Matteo Vanni, John A. Kelly, Robert Wolf, Maria Caporali
Pubblicato in: Coordination Chemistry Reviews, Numero 441, 2021, Pagina/e 213927, ISSN 0010-8545
Editore: Elsevier BV
DOI: 10.1016/j.ccr.2021.213927

Photochemical transformation of chlorobenzenes and white phosphorus into arylphosphines and phosphonium salts

Autori: Till, Marion; Streitferdt, Verena; Scott, Daniel J.; Mende, Michael; Gschwind, Ruth M.; Wolf, Robert
Pubblicato in: Chemical Communications, Numero 19, 2022, Pagina/e 1100-1103, ISSN 1364-548X
Editore: Royal Society of Chemistry
DOI: 10.1039/d1cc05691c

Bulking up Cp^BIG: A Penta-Terphenyl Cyclopentadienyl Ligand

Autori: Robert Wolf; Gabriele Hierlmeier
Pubblicato in: Bulking up CpBIG: A Penta-Terphenyl Cyclopentadienyl Ligand, Numero 13, 2022, Pagina/e 776–784, ISSN 0276-7333
Editore: American Chemical Society
DOI: 10.1021/acs.organomet.2c00009

Versatile Visible‐Light‐Driven Synthesis of Asymmetrical Phosphines and Phosphonium Salts

Autori: Percia Beatrice Arockiam, Ulrich Lennert, Christina Graf, Robin Rothfelder, Daniel J. Scott, Tillmann G. Fischer, Kirsten Zeitler, Robert Wolf
Pubblicato in: Chemistry – A European Journal, Numero 26/69, 2020, Pagina/e 16374-16382, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202002646

Low-Valence Anionic α-Diimine Iron Complexes: Synthesis, Characterization, and Catalytic Hydroboration Studies

Autori: Thomas M. Maier, Martin Gawron, Peter Coburger, Michael Bodensteiner, Robert Wolf, Nicolaas P. van Leest, Bas de Bruin, Serhiy Demeshko, Franc Meyer
Pubblicato in: Inorganic Chemistry, Numero 59/21, 2020, Pagina/e 16035-16052, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c02606

Isomerism and Biradical Character of Tetrapnictide Dianions: A Computational Study

Autori: Peter Coburger, Robert Wolf, Hansjörg Grützmacher
Pubblicato in: European Journal of Inorganic Chemistry, Numero 2020/37, 2020, Pagina/e 3580-3586, ISSN 1434-1948
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.202000422

Synthesis and Characterization of Bidentate Isonitrile Iron Complexes

Autori: Marion Till, John A. Kelly, Christoph G. P. Ziegler, Robert Wolf, Tianao Guo, Mark R. Ringenberg, Eugen Lutsker, Oliver Reiser
Pubblicato in: Organometallics, 2021, ISSN 0276-7333
Editore: American Chemical Society
DOI: 10.1021/acs.organomet.1c00042

Synthesis of a Cyclic Co 2 Sn 2 Cluster Using a Co – Synthon

Autori: Christian M. Hoidn, Christian Rödl, Madison L. McCrea-Hendrick, Theresa Block, Rainer Pöttgen, Andreas W. Ehlers, Philip P. Power, Robert Wolf
Pubblicato in: Journal of the American Chemical Society, Numero 140/41, 2018, Pagina/e 13195-13199, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.8b08517

Direct catalytic transformation of white phosphorus into arylphosphines and phosphonium salts

Autori: Ulrich Lennert, Percia Beatrice Arockiam, Verena Streitferdt, Daniel J. Scott, Christian Rödl, Ruth M. Gschwind, Robert Wolf
Pubblicato in: Nature Catalysis, Numero 2/12, 2019, Pagina/e 1101-1106, ISSN 2520-1158
Editore: Nature Research
DOI: 10.1038/s41929-019-0378-4

[3+2] Fragmentation of a Pentaphosphido Ligand by Cyanide

Autori: Christian M. Hoidn, Thomas M. Maier, Karolina Trabitsch, Jan J. Weigand, Robert Wolf
Pubblicato in: Angewandte Chemie International Edition, Numero 58/52, 2019, Pagina/e 18931-18936, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201908744

Iron-Gallium and Cobalt-Gallium Tetraphosphido Complexes

Autori: Christoph G. P. Ziegler, Felix Hennersdorf, Jan J. Weigand, Robert Wolf
Pubblicato in: Zeitschrift für anorganische und allgemeine Chemie, 2020, ISSN 0044-2313
Editore: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/zaac.201900351

Di‐ tert ‐butyldiphosphatetrahedrane: Catalytic Synthesis of the Elusive Phosphaalkyne Dimer

Autori: Gabriele Hierlmeier, Peter Coburger, Michael Bodensteiner, Robert Wolf
Pubblicato in: Angewandte Chemie International Edition, Numero 58/47, 2019, Pagina/e 16918-16922, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201910505

Functionalization of Pentaphosphorus Cations by Complexation

Autori: Anup K. Adhikari, Christoph G. P. Ziegler, Kai Schwedtmann, Clemens Taube, Jan. J. Weigand, Robert Wolf
Pubblicato in: Angewandte Chemie International Edition, Numero 58/51, 2019, Pagina/e 18584-18590, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201908998

Construction of alkyl-substituted pentaphosphido ligands in the coordination sphere of cobalt

Autori: Christoph G. P. Ziegler, Thomas M. Maier, Stefan Pelties, Clemens Taube, Felix Hennersdorf, Andreas W. Ehlers, Jan J. Weigand, Robert Wolf
Pubblicato in: Chemical Science, Numero 10/5, 2019, Pagina/e 1302-1308, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/c8sc04745f

Transition-Metal-Stabilized Heavy Tetraphospholide Anions

Autori: John A. Kelly; Verena Streitferdt; Maria Dimitrova; Franz F. Westermair; Ruth M. Gschwind; Raphael J. F. Berger; Robert Wolf
Pubblicato in: Transition-Metal-Stabilized Heavy Tetraphospholide Anions, Numero 6, 2022, Pagina/e 20434–20441, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.2c08754

Low-oxidation state cobalt–magnesium complexes: ion-pairing and reactivity

Autori: John A. Kelly, Johannes Gramüller, Ruth M. Gschwind, Robert Wolf
Pubblicato in: Dalton Transactions, Numero 50/39, 2021, Pagina/e 13985-13992, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/d1dt02621f

Di- tert -butyldiphosphatetrahedrane as a building block for phosphaalkenes and phosphirenes

Autori: Gabriele Hierlmeier, Maria K. Uttendorfer, Robert Wolf
Pubblicato in: Chemical Communications, Numero 57/19, 2021, Pagina/e 2356-2359, ISSN 1359-7345
Editore: Royal Society of Chemistry
DOI: 10.1039/d0cc07103j

Activation of Di‐ tert ‐butyldiphosphatetrahedrane: Access to ( t BuCP) n ( n= 2, 4) Ligand Frameworks by P−C Bond Cleavage

Autori: Gabriele Hierlmeier, Robert Wolf
Pubblicato in: Angewandte Chemie International Edition, Numero 60/12, 2021, Pagina/e 6435-6440, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202015680

Synthesis of a carborane-substituted bis(phosphanido) cobaltate( i ), ligand substitution, and unusual P 4 fragmentation

Autori: Peter Coburger, Julia Leitl, Daniel J. Scott, Gabriele Hierlmeier, Ilya G. Shenderovich, Evamarie Hey-Hawkins, Robert Wolf
Pubblicato in: Chemical Science, Numero 12/33, 2021, Pagina/e 11225-11235, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/d1sc02948g