Heterometallic Rings for Future Electronics

Project Information

Herifuel

Grant agreement ID: 786734

DOI

10.3030/786734

Project closed

EC signature date 24 April 2018

Start date 1 September 2018

End date 31 May 2024

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 2 477 003,00

EU contribution

€ 2 477 003,00

Coordinated by

THE UNIVERSITY OF MANCHESTER
United Kingdom

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (34)

Sensitivity enhancement of a high-resolution negative-tone nonchemically amplified metal organic photoresist for extreme ultraviolet lithography

Author(s): Scott M. Lewis, Hayden R. Alty, Michaela Vockenhuber, Guy A. DeRose, Antonio Fernandez-Mato, Dimitrios Kazazis, Paul L. Winpenny, Richard Grindell, Grigore A. Timco, Axel Scherer, Yasin Ekinci, Richard E. P. Winpenny
Published in: Journal of Micro/Nanopatterning, Materials, and Metrology, Issue 21, 2024, ISSN 2708-8340
Publisher: IEEE
DOI: 10.1117/1.jmm.21.4.041404

Templating metallocycles with a macrocycle: synthesis, structures and magnetic studies of {Cr₁₁M₂} complexes

Author(s): Rajeh Alotaibi, Adam Brookfield, Jonathan M. Fowler, George F. S. Whitehead, Selena J. Lockyer, Grigore A. Timco, David Collison, Jürgen Schnack, Richard E. P. Winpenny
Published in: Dalton Transactions, Issue 52, 2024, Page(s) 20-23, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2dt03368b

Five-Spin Supramolecule for Simulating Quantum Decoherence of Bell States

Author(s): Selena J. Lockyer, Alessandro Chiesa, Adam Brookfield, Grigore A. Timco, George F. S. Whitehead, Eric J. L. McInnes, Stefano Carretta, Richard E. P. Winpenny
Published in: Journal of the American Chemical Society, Issue 144, 2023, Page(s) 16086-16092, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c06384

Thermally Stable Terbium(II) and Dysprosium(II) Bis-amidinate Complexes

Author(s): Peng-Bo Jin, Qian-Cheng Luo, Gemma K. Gransbury, Iñigo J. Vitorica-Yrezabal, Tomáš Hajdu, Ilya Strashnov, Eric J. L. McInnes, Richard E. P. Winpenny, Nicholas F. Chilton, David P. Mills, Yan-Zhen Zheng
Published in: Journal of the American Chemical Society, Issue 145, 2023, Page(s) 27993-28009, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c07978

Close Encounters of the Weak Kind: Investigations of Electron–Electron Interactions between Dissimilar Spins in Hybrid Rotaxanes

Author(s): Selena J. Lockyer, Alistair J. Fielding, George F. S. Whitehead, Grigore A. Timco, Richard E. P. Winpenny, Eric J. L. McInnes
Published in: Journal of the American Chemical Society, Issue 141/37, 2019, Page(s) 14633-14642, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.9b05590

Nanoscale Patterning of Zinc Oxide from Zinc Acetate Using Electron Beam Lithography for the Preparation of Hard Lithographic Masks

Author(s): Ahmad Chaker, Hayden R. Alty, Peng Tian, Anastasios Kotsovinos, Grigore A. Timco, Christopher A. Muryn, Scott M. Lewis, Richard E. P. Winpenny
Published in: ACS Applied Nano Materials, Issue 4/1, 2021, Page(s) 406-413, ISSN 2574-0970
Publisher: American Chemical Society
DOI: 10.1021/acsanm.0c02756

Structural characterisation and dynamics of a paramagnetic {Cr₁₂Ni₃} seahorse in non-crystalline phases

Author(s): Niklas Geue, Emily Hicks, Selena J. Lockyer, Selina Nawaz, Olivia Churchill, George F. S. Whitehead, Grigore A. Timco, Neil A. Burton, Perdita E. Barran, Richard E. P. Winpenny
Published in: Physical Chemistry Chemical Physics, Issue 27, 2025, Page(s) 5616-5622, ISSN 1463-9076
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4cp04498c

Disassembly Mechanisms and Energetics of Polymetallic Rings and Rotaxanes

Author(s): Niklas Geue, Tom S. Bennett, Alexandra-Ana-Maria Arama, Lennart A. I. Ramakers, George F. S. Whitehead, Grigore A. Timco, P. B. Armentrout, Eric J. L. McInnes, Neil A. Burton, Richard E. P. Winpenny, Perdita E. Barran
Published in: Journal of the American Chemical Society, Issue 144, 2023, Page(s) 22528-22539, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c07522

Decorating polymer beads with 1014 inorganic-organic [2]rotaxanes as shown by spin counting

Author(s): Deepak Asthana, Dean Thomas, Selena J. Lockyer, Adam Brookfield, Grigore A. Timco, Iñigo J. Vitorica-Yrezabal, George F. S. Whitehead, Eric J. L. McInnes, David Collison, David A. Leigh, Richard E. P. Winpenny
Published in: Communications Chemistry, Issue 5, 2022, ISSN 2399-3669
Publisher: Springer Science and Business Media LLC
DOI: 10.1038/s42004-022-00689-1

Electron Paramagnetic Resonance Spectra of Pentagonal Bipyramidal Gadolinium Complexes

Author(s): Jonatan B. Petersen, You-Song Ding, Sandeep Gupta, Aditya Borah, Eric J. L. McInnes, Yan-Zhen Zheng, Ramaswamy Murugavel, Richard E. P. Winpenny
Published in: Inorganic Chemistry, Issue 62, 2023, Page(s) 8435-8441, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.3c01227

Mononuclear Dysprosium Alkoxide and Aryloxide Single‐Molecule Magnets

Author(s): Vijay S. Parmar, David P. Mills, Richard E. P. Winpenny
Published in: Chemistry – A European Journal, Issue 27/28, 2021, Page(s) 7625-7645, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202100085

Adduct Ions as Diagnostic Probes of Metallosupramolecular Complexes Using Ion Mobility Mass Spectrometry

Author(s): Niklas Geue, Tom S. Bennett, Lennart A. I. Ramakers, Grigore A. Timco, Eric J. L. McInnes, Neil A. Burton, P. B. Armentrout, Richard E. P. Winpenny, Perdita E. Barran
Published in: Inorganic Chemistry, Issue 62, 2023, Page(s) 2672-2679, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.2c03698

Probing Relaxation Dynamics in Five‐Coordinate Dysprosium Single‐Molecule Magnets

Author(s): Vijay S. Parmar, Fabrizio Ortu, Xiaozhou Ma, Nicholas F. Chilton, Rodolphe Clérac, David P. Mills, Richard E. P. Winpenny
Published in: Chemistry – A European Journal, Issue 26/35, 2020, Page(s) 7774-7778, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202001235

Ion Mobility Mass Spectrometry for Large Synthetic Molecules: Expanding the Analytical Toolbox

Author(s): Niklas Geue, Richard E. P. Winpenny, Perdita E. Barran
Published in: Journal of the American Chemical Society, Issue 146, 2024, Page(s) 8800-8819, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.4c00354

Two‐ and Three‐Spin Hybrid Inorganic‐Organic [2]Rotaxanes Containing Metallated Salen Groups

Author(s): Tom S. Bennett, Selena J. Lockyer, Deepak Asthana, George F. S. Whitehead, Inigo J. Vitorica‐Yrezabal, Grigore A. Timco, Richard E. P. Winpenny, Eric J. L. McInnes
Published in: Chemistry – An Asian Journal, Issue 19, 2024, ISSN 1861-4728
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/asia.202400641

Magnetic exchange interactions in symmetric lanthanide dimetallics

Author(s): Marcus J. Giansiracusa, Susan Al-Badran, Andreas K. Kostopoulos, George F. S. Whitehead, Eric J. L. McInnes, David Collison, Richard E. P. Winpenny, Nicholas F. Chilton
Published in: Inorganic Chemistry Frontiers, Issue 7/20, 2020, Page(s) 3909-3918, ISSN 2052-1553
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0qi00854k

The Synthesis and Characterisation of a Molecular Sea‐Serpent: Studies of a {Cr 24 Cu 7 } Chain

Author(s): Rajeh Alotaibi, Jonathan M. Fowler, Selena J. Lockyer, Grigore A. Timco, David Collison, Jürgen Schnack, Richard E. P. Winpenny
Published in: Angewandte Chemie International Edition, Issue 60/17, 2021, Page(s) 9489-9492, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202015731

Characterizing X-Ray and Solution State Conformations for a Model Qubit System: {Cr₇Ni} Ring Rotaxanes on a Mixed Metal Triangle

Author(s): Lubomir Loci, Selena J. Lockyer, Tom S. Bennett, Ciarán J. Rogers, Adam Brookfield, Grigore A. Timco, George F. S. Whitehead, Selina Nawaz, Jack J. Miller, Richard E. P. Winpenny, Alice M. Bowen
Published in: Inorganic Chemistry, Issue 63, 2024, Page(s) 22880-22891, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c03919

One-, two- and three-dimensional interlocked polymers based on hybrid inorganic–organic rotaxanes

Author(s): Selena J. Lockyer, George F. S. Whitehead, Grigore A. Timco, Eric J. L. McInnes, Richard E. P. Winpenny
Published in: Chemical Communications, Issue 60, 2024, Page(s) 10124-10127, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4cc03566f

Synthesis and characterization of heterometallic rings templated through alkylammonium or imidazolium cations

Author(s): Rajeh Alotaibi, Amy Booth, Edmund Little, Adam Brookfield, Amritroop Achari, Selena J. Lockyer, Grigore A. Timco, George F. S. Whitehead, Iñigo J. Vitórica-Yrezábal, Nicholas F. Chilton, Rahul R. Nair, David Collison, Richard E. P. Winpenny
Published in: Dalton Transactions, Issue 52, 2024, Page(s) 7473-7481, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3dt00982c

Modelling Conformational Flexibility in a Spectrally Addressable Molecular Multi‐Qubit Model System

Author(s): Ciarán J. Rogers, Deepak Asthana, Adam Brookfield, Alessandro Chiesa, Grigore A. Timco, David Collison, Louise S. Natrajan, Stefano Carretta, Richard E. P. Winpenny, Alice M. Bowen
Published in: Angewandte Chemie International Edition, Issue 61, 2023, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202207947

A large barrier single-molecule magnet without magnetic memory

Author(s): Marcus J. Giansiracusa, Susan Al-Badran, Andreas K. Kostopoulos, George F. S. Whitehead, David Collison, Floriana Tuna, Richard E. P. Winpenny, Nicholas F. Chilton
Published in: Dalton Transactions, Issue 48/29, 2019, Page(s) 10795-10798, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9dt01791g

Targeting Molecular Quantum Memory with Embedded Error Correction

Author(s): Selena Lockyer, Alessandro Chiesa, Grigore A. Timco, Thomas M Bennett, Inigo Vitorica-Yrzebal, Eric J L McInnes, Stefano Carretta, Richard E. P. Winpenny
Published in: Chemical Science, 2021, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1sc01506k

Negative Tone Metallic Organic Resists with Improved Sensitivity for Plasma Etching: Implications for Silicon Nanostructure Fabrication and Photomask Production

Author(s): Ahmad Chaker, Hayden A. Alty, Paul Winpenny, George F. S. Whitehead, Grigore A. Timco, Scott M. Lewis, Richard E. P. Winpenny
Published in: ACS Applied Nano Materials, Issue 5, 2023, Page(s) 17538-17543, ISSN 2574-0970
Publisher: American Chemical Society
DOI: 10.1021/acsanm.2c02986

Single Isomer Heterometallic {Cr^III₆M^II₂} Rings Templated by Tetramethylammonium

Author(s): Rajeh Alotaibi, Edmund Little, Jonathan M. Fowler, Adam Brookfield, Ralph W. Adams, Amritroop Achari, Grigore A. Timco, George F. S. Whitehead, Nicholas F. Chilton, Rahul R. Nair, David Collison, Richard E. P. Winpenny
Published in: Inorganic Chemistry, Issue 60, 2023, Page(s) 15675-15685, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.1c02342

Structural characterisation methods for supramolecular chemistry that go beyond crystallography

Author(s): Niklas Geue, Richard E. P. Winpenny, Perdita E. Barran
Published in: Chemical Society Reviews, Issue 51, 2024, Page(s) 8-27, ISSN 0306-0012
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cs01550d

Studying Cation Exchange in {Cr7Co} Pseudorotaxanes: Preparatory Studies for Making Hybrid Molecular Machines

Author(s): Tom Bennett, Niklas Geue, Grigore Timco, George Whitehead, Inigo Vitorica-Yrezabal, Perdita Barran, Eric McInnes, Richard Winpenny
Published in: Chemistry A European Journal, 2023, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.26434/chemrxiv-2023-bc339

Conformational Landscapes and Energetics of Carbon Nanohoops and their Ring-in-Ring Complexes

Author(s): Niklas Geue, Markus Freiberger, Stefan Frühwald, Andreas Görling, Thomas Drewello, Perdita E. Barran
Published in: The Journal of Physical Chemistry Letters, Issue 15, 2024, Page(s) 6805-6811, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.4c01270

Control and Transferability of Magnetic Interactions in Supramolecular Structures: Trimers of {Cr₇Ni} Antiferromagnetic Rings

Author(s): Selena J. Lockyer, Deepak Asthana, George F. S. Whitehead, Inigo J. Vitorica‐Yrezabal, Grigore. A. Timco, Eric J. L. McInnes, Richard E. P. Winpenny
Published in: Chemistry – A European Journal, Issue 29, 2024, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202302360

Experimental realisation of multi-qubit gates using electron paramagnetic resonance

Author(s): Edmund J. Little, Jacob Mrozek, Ciarán J. Rogers, Junjie Liu, Eric J. L. McInnes, Alice M. Bowen, Arzhang Ardavan, Richard E. P. Winpenny
Published in: Nature Communications, Issue 14, 2023, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-023-42169-7

Weak Exchange Interactions in Multispin Systems: EPR Studies of Metalloporphyrins Decorated with {Cr₇Ni} Rings

Author(s): Fabio Santanni, Edmund Little, Selena J. Lockyer, George F. S. Whitehead, Eric J. L. McInnes, Grigore A. Timco, Alice M. Bowen, Roberta Sessoli, Richard E. P. Winpenny
Published in: Inorganic Chemistry, Issue 63, 2024, Page(s) 15460-15466, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c01248

Formation and characterization of polymetallic {CrxMy} rings in vacuo

Author(s): Niklas Geue, Grigore A. Timco, George F. S. Whitehead, Eric J. L. McInnes, Neil A. Burton, Richard E. P. Winpenny, Perdita E. Barran
Published in: Nature Synthesis, Issue 2, 2023, Page(s) 926-936, ISSN 2731-0582
Publisher: Springer Science and Business Media LLC
DOI: 10.1038/s44160-023-00383-7

Conformational Flexibility of Hybrid [3]- and [4]-Rotaxanes

Author(s): Selena J. Lockyer, Selina Nawaz, Adam Brookfield, Alistair J. Fielding, Inigo J. Vitorica-Yrezabal, Grigore A. Timco, Neil A. Burton, Alice M. Bowen, Richard E. P. Winpenny, Eric J. L. McInnes
Published in: Journal of the American Chemical Society, Issue 142/37, 2020, Page(s) 15941-15949, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.0c06547

Gold( i ) bridged dimeric and trimeric heterometallic {Cr 7 Ni}-based qubit systems and their characterization

Author(s): Deepak Asthana, Selena J. Lockyer, Selina Nawaz, Robert J. Woolfson, Grigore A. Timco, Christopher A. Muryn, Iñigo J. Vitorica-Yrezabal, David Collison, Neil A. Burton, Richard E. P. Winpenny
Published in: Dalton Transactions, Issue 50/12, 2021, Page(s) 4390-4395, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1dt00150g

Other (2)

A Ring of Rotaxanes: Studies of a Large Paramagnetic Assembly in Solution

Author(s): Richard Winpenny, Tom Bennett, Selina Nawaz, Deepak Asthana, Selena Lockyer, George Whitehead, Inigo Vitorica-Yrezabal, Grigore Timco, Neil Burton, Eric McInnes
Published in: Chemistry Archive, 2023
Publisher: American Chemical Society (ACS)
DOI: 10.26434/chemrxiv-2023-h8jrr

Disassembly Mechanisms and Energetics of Polymetallic Rings and Rotaxanes with Ion Mobility Mass Spectrometry

Author(s): Niklas Geue, Tom S. Bennett, Alexandra A. Arama, Lennart A.I. Ramakers, George F.S. Whitehead, Grigore A. Timco, Peter B. Armentrout, Eric J.L. McInnes, Neil A. Burton, Richard E.P. Winpenny, Perdita E. Barran
Published in: Chemistry Archive, 2023
Publisher: American Chemical Society (ACS)
DOI: 10.26434/chemrxiv-2022-8vs90