Heterometallic Rings for Future Electronics

Informazioni relative al progetto

Herifuel

ID dell’accordo di sovvenzione: 786734

DOI

10.3030/786734

Progetto chiuso

Data della firma CE 24 Aprile 2018

Data di avvio 1 Settembre 2018

Data di completamento 31 Maggio 2024

Finanziato da

• EXCELLENT SCIENCE - European Research Council (ERC)

Costo totale

€ 2 477 003,00

Contributo UE

€ 2 477 003,00

Coordinato da

THE UNIVERSITY OF MANCHESTER
United Kingdom

CORDIS fornisce collegamenti ai risultati finali pubblici e alle pubblicazioni dei progetti ORIZZONTE.

I link ai risultati e alle pubblicazioni dei progetti del 7° PQ, così come i link ad alcuni tipi di risultati specifici come dataset e software, sono recuperati dinamicamente da .OpenAIRE .

Pubblicazioni

Peer reviewed articles (34)

Sensitivity enhancement of a high-resolution negative-tone nonchemically amplified metal organic photoresist for extreme ultraviolet lithography

Autori: Scott M. Lewis, Hayden R. Alty, Michaela Vockenhuber, Guy A. DeRose, Antonio Fernandez-Mato, Dimitrios Kazazis, Paul L. Winpenny, Richard Grindell, Grigore A. Timco, Axel Scherer, Yasin Ekinci, Richard E. P. Winpenny
Pubblicato in: Journal of Micro/Nanopatterning, Materials, and Metrology, Numero 21, 2024, ISSN 2708-8340
Editore: IEEE
DOI: 10.1117/1.jmm.21.4.041404

Templating metallocycles with a macrocycle: synthesis, structures and magnetic studies of {Cr₁₁M₂} complexes

Autori: Rajeh Alotaibi, Adam Brookfield, Jonathan M. Fowler, George F. S. Whitehead, Selena J. Lockyer, Grigore A. Timco, David Collison, Jürgen Schnack, Richard E. P. Winpenny
Pubblicato in: Dalton Transactions, Numero 52, 2024, Pagina/e 20-23, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/d2dt03368b

Five-Spin Supramolecule for Simulating Quantum Decoherence of Bell States

Autori: Selena J. Lockyer, Alessandro Chiesa, Adam Brookfield, Grigore A. Timco, George F. S. Whitehead, Eric J. L. McInnes, Stefano Carretta, Richard E. P. Winpenny
Pubblicato in: Journal of the American Chemical Society, Numero 144, 2023, Pagina/e 16086-16092, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.2c06384

Thermally Stable Terbium(II) and Dysprosium(II) Bis-amidinate Complexes

Autori: Peng-Bo Jin, Qian-Cheng Luo, Gemma K. Gransbury, Iñigo J. Vitorica-Yrezabal, Tomáš Hajdu, Ilya Strashnov, Eric J. L. McInnes, Richard E. P. Winpenny, Nicholas F. Chilton, David P. Mills, Yan-Zhen Zheng
Pubblicato in: Journal of the American Chemical Society, Numero 145, 2023, Pagina/e 27993-28009, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.3c07978

Close Encounters of the Weak Kind: Investigations of Electron–Electron Interactions between Dissimilar Spins in Hybrid Rotaxanes

Autori: Selena J. Lockyer, Alistair J. Fielding, George F. S. Whitehead, Grigore A. Timco, Richard E. P. Winpenny, Eric J. L. McInnes
Pubblicato in: Journal of the American Chemical Society, Numero 141/37, 2019, Pagina/e 14633-14642, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.9b05590

Nanoscale Patterning of Zinc Oxide from Zinc Acetate Using Electron Beam Lithography for the Preparation of Hard Lithographic Masks

Autori: Ahmad Chaker, Hayden R. Alty, Peng Tian, Anastasios Kotsovinos, Grigore A. Timco, Christopher A. Muryn, Scott M. Lewis, Richard E. P. Winpenny
Pubblicato in: ACS Applied Nano Materials, Numero 4/1, 2021, Pagina/e 406-413, ISSN 2574-0970
Editore: American Chemical Society
DOI: 10.1021/acsanm.0c02756

Structural characterisation and dynamics of a paramagnetic {Cr₁₂Ni₃} seahorse in non-crystalline phases

Autori: Niklas Geue, Emily Hicks, Selena J. Lockyer, Selina Nawaz, Olivia Churchill, George F. S. Whitehead, Grigore A. Timco, Neil A. Burton, Perdita E. Barran, Richard E. P. Winpenny
Pubblicato in: Physical Chemistry Chemical Physics, Numero 27, 2025, Pagina/e 5616-5622, ISSN 1463-9076
Editore: Royal Society of Chemistry
DOI: 10.1039/d4cp04498c

Disassembly Mechanisms and Energetics of Polymetallic Rings and Rotaxanes

Autori: Niklas Geue, Tom S. Bennett, Alexandra-Ana-Maria Arama, Lennart A. I. Ramakers, George F. S. Whitehead, Grigore A. Timco, P. B. Armentrout, Eric J. L. McInnes, Neil A. Burton, Richard E. P. Winpenny, Perdita E. Barran
Pubblicato in: Journal of the American Chemical Society, Numero 144, 2023, Pagina/e 22528-22539, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.2c07522

Decorating polymer beads with 1014 inorganic-organic [2]rotaxanes as shown by spin counting

Autori: Deepak Asthana, Dean Thomas, Selena J. Lockyer, Adam Brookfield, Grigore A. Timco, Iñigo J. Vitorica-Yrezabal, George F. S. Whitehead, Eric J. L. McInnes, David Collison, David A. Leigh, Richard E. P. Winpenny
Pubblicato in: Communications Chemistry, Numero 5, 2022, ISSN 2399-3669
Editore: Springer Science and Business Media LLC
DOI: 10.1038/s42004-022-00689-1

Electron Paramagnetic Resonance Spectra of Pentagonal Bipyramidal Gadolinium Complexes

Autori: Jonatan B. Petersen, You-Song Ding, Sandeep Gupta, Aditya Borah, Eric J. L. McInnes, Yan-Zhen Zheng, Ramaswamy Murugavel, Richard E. P. Winpenny
Pubblicato in: Inorganic Chemistry, Numero 62, 2023, Pagina/e 8435-8441, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.3c01227

Mononuclear Dysprosium Alkoxide and Aryloxide Single‐Molecule Magnets

Autori: Vijay S. Parmar, David P. Mills, Richard E. P. Winpenny
Pubblicato in: Chemistry – A European Journal, Numero 27/28, 2021, Pagina/e 7625-7645, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202100085

Adduct Ions as Diagnostic Probes of Metallosupramolecular Complexes Using Ion Mobility Mass Spectrometry

Autori: Niklas Geue, Tom S. Bennett, Lennart A. I. Ramakers, Grigore A. Timco, Eric J. L. McInnes, Neil A. Burton, P. B. Armentrout, Richard E. P. Winpenny, Perdita E. Barran
Pubblicato in: Inorganic Chemistry, Numero 62, 2023, Pagina/e 2672-2679, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.2c03698

Probing Relaxation Dynamics in Five‐Coordinate Dysprosium Single‐Molecule Magnets

Autori: Vijay S. Parmar, Fabrizio Ortu, Xiaozhou Ma, Nicholas F. Chilton, Rodolphe Clérac, David P. Mills, Richard E. P. Winpenny
Pubblicato in: Chemistry – A European Journal, Numero 26/35, 2020, Pagina/e 7774-7778, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202001235

Ion Mobility Mass Spectrometry for Large Synthetic Molecules: Expanding the Analytical Toolbox

Autori: Niklas Geue, Richard E. P. Winpenny, Perdita E. Barran
Pubblicato in: Journal of the American Chemical Society, Numero 146, 2024, Pagina/e 8800-8819, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.4c00354

Two‐ and Three‐Spin Hybrid Inorganic‐Organic [2]Rotaxanes Containing Metallated Salen Groups

Autori: Tom S. Bennett, Selena J. Lockyer, Deepak Asthana, George F. S. Whitehead, Inigo J. Vitorica‐Yrezabal, Grigore A. Timco, Richard E. P. Winpenny, Eric J. L. McInnes
Pubblicato in: Chemistry – An Asian Journal, Numero 19, 2024, ISSN 1861-4728
Editore: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/asia.202400641

Magnetic exchange interactions in symmetric lanthanide dimetallics

Autori: Marcus J. Giansiracusa, Susan Al-Badran, Andreas K. Kostopoulos, George F. S. Whitehead, Eric J. L. McInnes, David Collison, Richard E. P. Winpenny, Nicholas F. Chilton
Pubblicato in: Inorganic Chemistry Frontiers, Numero 7/20, 2020, Pagina/e 3909-3918, ISSN 2052-1553
Editore: Royal Society of Chemistry
DOI: 10.1039/d0qi00854k

The Synthesis and Characterisation of a Molecular Sea‐Serpent: Studies of a {Cr 24 Cu 7 } Chain

Autori: Rajeh Alotaibi, Jonathan M. Fowler, Selena J. Lockyer, Grigore A. Timco, David Collison, Jürgen Schnack, Richard E. P. Winpenny
Pubblicato in: Angewandte Chemie International Edition, Numero 60/17, 2021, Pagina/e 9489-9492, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202015731

Characterizing X-Ray and Solution State Conformations for a Model Qubit System: {Cr₇Ni} Ring Rotaxanes on a Mixed Metal Triangle

Autori: Lubomir Loci, Selena J. Lockyer, Tom S. Bennett, Ciarán J. Rogers, Adam Brookfield, Grigore A. Timco, George F. S. Whitehead, Selina Nawaz, Jack J. Miller, Richard E. P. Winpenny, Alice M. Bowen
Pubblicato in: Inorganic Chemistry, Numero 63, 2024, Pagina/e 22880-22891, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c03919

One-, two- and three-dimensional interlocked polymers based on hybrid inorganic–organic rotaxanes

Autori: Selena J. Lockyer, George F. S. Whitehead, Grigore A. Timco, Eric J. L. McInnes, Richard E. P. Winpenny
Pubblicato in: Chemical Communications, Numero 60, 2024, Pagina/e 10124-10127, ISSN 1359-7345
Editore: Royal Society of Chemistry
DOI: 10.1039/d4cc03566f

Synthesis and characterization of heterometallic rings templated through alkylammonium or imidazolium cations

Autori: Rajeh Alotaibi, Amy Booth, Edmund Little, Adam Brookfield, Amritroop Achari, Selena J. Lockyer, Grigore A. Timco, George F. S. Whitehead, Iñigo J. Vitórica-Yrezábal, Nicholas F. Chilton, Rahul R. Nair, David Collison, Richard E. P. Winpenny
Pubblicato in: Dalton Transactions, Numero 52, 2024, Pagina/e 7473-7481, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/d3dt00982c

Modelling Conformational Flexibility in a Spectrally Addressable Molecular Multi‐Qubit Model System

Autori: Ciarán J. Rogers, Deepak Asthana, Adam Brookfield, Alessandro Chiesa, Grigore A. Timco, David Collison, Louise S. Natrajan, Stefano Carretta, Richard E. P. Winpenny, Alice M. Bowen
Pubblicato in: Angewandte Chemie International Edition, Numero 61, 2023, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202207947

A large barrier single-molecule magnet without magnetic memory

Autori: Marcus J. Giansiracusa, Susan Al-Badran, Andreas K. Kostopoulos, George F. S. Whitehead, David Collison, Floriana Tuna, Richard E. P. Winpenny, Nicholas F. Chilton
Pubblicato in: Dalton Transactions, Numero 48/29, 2019, Pagina/e 10795-10798, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/c9dt01791g

Targeting Molecular Quantum Memory with Embedded Error Correction

Autori: Selena Lockyer, Alessandro Chiesa, Grigore A. Timco, Thomas M Bennett, Inigo Vitorica-Yrzebal, Eric J L McInnes, Stefano Carretta, Richard E. P. Winpenny
Pubblicato in: Chemical Science, 2021, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/d1sc01506k

Negative Tone Metallic Organic Resists with Improved Sensitivity for Plasma Etching: Implications for Silicon Nanostructure Fabrication and Photomask Production

Autori: Ahmad Chaker, Hayden A. Alty, Paul Winpenny, George F. S. Whitehead, Grigore A. Timco, Scott M. Lewis, Richard E. P. Winpenny
Pubblicato in: ACS Applied Nano Materials, Numero 5, 2023, Pagina/e 17538-17543, ISSN 2574-0970
Editore: American Chemical Society
DOI: 10.1021/acsanm.2c02986

Single Isomer Heterometallic {Cr^III₆M^II₂} Rings Templated by Tetramethylammonium

Autori: Rajeh Alotaibi, Edmund Little, Jonathan M. Fowler, Adam Brookfield, Ralph W. Adams, Amritroop Achari, Grigore A. Timco, George F. S. Whitehead, Nicholas F. Chilton, Rahul R. Nair, David Collison, Richard E. P. Winpenny
Pubblicato in: Inorganic Chemistry, Numero 60, 2023, Pagina/e 15675-15685, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.1c02342

Structural characterisation methods for supramolecular chemistry that go beyond crystallography

Autori: Niklas Geue, Richard E. P. Winpenny, Perdita E. Barran
Pubblicato in: Chemical Society Reviews, Numero 51, 2024, Pagina/e 8-27, ISSN 0306-0012
Editore: Royal Society of Chemistry
DOI: 10.1039/d0cs01550d

Studying Cation Exchange in {Cr7Co} Pseudorotaxanes: Preparatory Studies for Making Hybrid Molecular Machines

Autori: Tom Bennett, Niklas Geue, Grigore Timco, George Whitehead, Inigo Vitorica-Yrezabal, Perdita Barran, Eric McInnes, Richard Winpenny
Pubblicato in: Chemistry A European Journal, 2023, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.26434/chemrxiv-2023-bc339

Conformational Landscapes and Energetics of Carbon Nanohoops and their Ring-in-Ring Complexes

Autori: Niklas Geue, Markus Freiberger, Stefan Frühwald, Andreas Görling, Thomas Drewello, Perdita E. Barran
Pubblicato in: The Journal of Physical Chemistry Letters, Numero 15, 2024, Pagina/e 6805-6811, ISSN 1948-7185
Editore: American Chemical Society
DOI: 10.1021/acs.jpclett.4c01270

Control and Transferability of Magnetic Interactions in Supramolecular Structures: Trimers of {Cr₇Ni} Antiferromagnetic Rings

Autori: Selena J. Lockyer, Deepak Asthana, George F. S. Whitehead, Inigo J. Vitorica‐Yrezabal, Grigore. A. Timco, Eric J. L. McInnes, Richard E. P. Winpenny
Pubblicato in: Chemistry – A European Journal, Numero 29, 2024, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202302360

Experimental realisation of multi-qubit gates using electron paramagnetic resonance

Autori: Edmund J. Little, Jacob Mrozek, Ciarán J. Rogers, Junjie Liu, Eric J. L. McInnes, Alice M. Bowen, Arzhang Ardavan, Richard E. P. Winpenny
Pubblicato in: Nature Communications, Numero 14, 2023, ISSN 2041-1723
Editore: Nature Publishing Group
DOI: 10.1038/s41467-023-42169-7

Weak Exchange Interactions in Multispin Systems: EPR Studies of Metalloporphyrins Decorated with {Cr₇Ni} Rings

Autori: Fabio Santanni, Edmund Little, Selena J. Lockyer, George F. S. Whitehead, Eric J. L. McInnes, Grigore A. Timco, Alice M. Bowen, Roberta Sessoli, Richard E. P. Winpenny
Pubblicato in: Inorganic Chemistry, Numero 63, 2024, Pagina/e 15460-15466, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c01248

Formation and characterization of polymetallic {CrxMy} rings in vacuo

Autori: Niklas Geue, Grigore A. Timco, George F. S. Whitehead, Eric J. L. McInnes, Neil A. Burton, Richard E. P. Winpenny, Perdita E. Barran
Pubblicato in: Nature Synthesis, Numero 2, 2023, Pagina/e 926-936, ISSN 2731-0582
Editore: Springer Science and Business Media LLC
DOI: 10.1038/s44160-023-00383-7

Conformational Flexibility of Hybrid [3]- and [4]-Rotaxanes

Autori: Selena J. Lockyer, Selina Nawaz, Adam Brookfield, Alistair J. Fielding, Inigo J. Vitorica-Yrezabal, Grigore A. Timco, Neil A. Burton, Alice M. Bowen, Richard E. P. Winpenny, Eric J. L. McInnes
Pubblicato in: Journal of the American Chemical Society, Numero 142/37, 2020, Pagina/e 15941-15949, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.0c06547

Gold( i ) bridged dimeric and trimeric heterometallic {Cr 7 Ni}-based qubit systems and their characterization

Autori: Deepak Asthana, Selena J. Lockyer, Selina Nawaz, Robert J. Woolfson, Grigore A. Timco, Christopher A. Muryn, Iñigo J. Vitorica-Yrezabal, David Collison, Neil A. Burton, Richard E. P. Winpenny
Pubblicato in: Dalton Transactions, Numero 50/12, 2021, Pagina/e 4390-4395, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/d1dt00150g

Other (2)

A Ring of Rotaxanes: Studies of a Large Paramagnetic Assembly in Solution

Autori: Richard Winpenny, Tom Bennett, Selina Nawaz, Deepak Asthana, Selena Lockyer, George Whitehead, Inigo Vitorica-Yrezabal, Grigore Timco, Neil Burton, Eric McInnes
Pubblicato in: Chemistry Archive, 2023
Editore: American Chemical Society (ACS)
DOI: 10.26434/chemrxiv-2023-h8jrr

Disassembly Mechanisms and Energetics of Polymetallic Rings and Rotaxanes with Ion Mobility Mass Spectrometry

Autori: Niklas Geue, Tom S. Bennett, Alexandra A. Arama, Lennart A.I. Ramakers, George F.S. Whitehead, Grigore A. Timco, Peter B. Armentrout, Eric J.L. McInnes, Neil A. Burton, Richard E.P. Winpenny, Perdita E. Barran
Pubblicato in: Chemistry Archive, 2023
Editore: American Chemical Society (ACS)
DOI: 10.26434/chemrxiv-2022-8vs90