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High spatial resolution mapping of catalytic reactions on single nanoparticles

Objective

Catalytic nanoparticles are heterogeneous in their nature - and even within the simplest particles structural and compositional differences exist and affect the overall performances of a catalyst. Thus non-disruptive, detailed chemical information at the nanoscale is essential for understanding how surface properties direct the reactivity of these particles. Infrared spectroscopy offers a low-energy route towards conducting in-situ, high spatial resolution mapping of catalytic reactions on the surface of single nanoparticles, yielding the influence of various physiochemical properties on the catalytic reactivity.
In the project my team will employ recently developed Infrared nanospectroscopy measurements to provide high spatial resolution mapping of catalytic reactions on the surface of metallic nanoparticles, while using chemically active N-heterocyclic carbene molecules as indicators for surface reactivity. With this setup I will address fundamental questions in catalysis research and identify, on a single particle basis and under reaction conditions, the ways by which the size, structure, composition and metal-support interactions direct the reactivity of metallic nanoparticles in hydrogenation, oxidation and functionalization reactions. My research group demonstrated recently the feasibility of this novel approach by which structure-reactivity correlations were identified within single nanoparticles. Knowledge gained in this project will provide in-depth understanding of the basic elements that control the reactivity of heterogeneous catalysts and enable the development of optimized catalysts based on rational design. Moreover, one can foresee wide application potential for this experimental approach in various other research fields like batteries and fuel cells, in which high spatial resolution analysis of reactive surfaces is essential for understanding structure-reactivity correlations.

Fields of science (EuroSciVoc)

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Keywords

Project’s keywords as indicated by the project coordinator. Not to be confused with the EuroSciVoc taxonomy (Fields of science)

Programme(s)

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Topic(s)

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Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

ERC-STG - Starting Grant

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

(opens in new window) ERC-2018-STG

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Host institution

THE HEBREW UNIVERSITY OF JERUSALEM
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 1 846 009,00
Address
EDMOND J SAFRA CAMPUS GIVAT RAM
91904 JERUSALEM
Israel

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Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 1 846 009,00

Beneficiaries (1)

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