Bioinspired Catalytic Metallofoldamers

Project Information

Foldmetcat

Grant agreement ID: 835080

DOI

10.3030/835080

Project closed

EC signature date 9 April 2019

Start date 1 September 2019

End date 28 February 2025

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 2 500 000,00

EU contribution

€ 2 500 000,00

Coordinated by

FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA
Spain

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (25)

Assembly of Complex 1,4-Cycloheptadienes by (4+3) Cycloaddition of Rhodium (II) and Gold (II) Non-Acceptor Carbenes

Author(s): Helena Armengol-Relats, Mauro Mato, Antonio M. Echavarren
Published in: Angewandte Chemie International Edition, Issue 60/4, 2021, Page(s) 1916-1922, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202012092

The Journey for the Synthesis of Large Acenes

Author(s): Antonio M. Echavarren, Laura Lerena, Rafal Zuzak, Szymon Godlewski
Published in: Chemistry – A European Journal, 2024, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202402122

On the Structure of Intermediates in Enyne Gold(I)‐Catalyzed Cyclizations: Formation of trans ‐Fused Bicyclo[5.1.0]octanes as a Case Study

Author(s): Imma Escofet, Helena Armengol‐Relats, Hanna Bruss, Maria Besora, Antonio M. Echavarren
Published in: Chemistry – A European Journal, Issue 26/67, 2020, Page(s) 15738-15745, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202004237

Buchwald‐Type Ligands on Gold(I) Catalysis

Author(s): Giuseppe Zuccarello, Margherita Zanini, Antonio M. Echavarren
Published in: Israel Journal of Chemistry, Issue 60/3-4, 2020, Page(s) 360-372, ISSN 0021-2148
Publisher: Laser Pages Publishing Ltd.
DOI: 10.1002/ijch.201900179

The Puzzling Structure of the Key Intermediates in Gold(I) Catalyzed Cyclizations of Enynes and Allenenes.

Author(s): Eduardo García-Padilla; Imma Escofet; Feliu Maseras; Antonio M. Echavarren
Published in: ChemPlusChem, 2023, ISSN 2192-6506
Publisher: Wiley-VCH Verlag
DOI: 10.1002/cplu.202300502

Hydrogen-Bonded Matched Ion Pair Gold(I) Catalysis

Author(s): Alex Martí; Gala Ogalla; Antonio M. Echavarren
Published in: ACS Catalysis, 2023, Page(s) 10217-10223, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.3c02638

Gold(I)-Catalyzed Intermolecular Aryloxyvinylation with Acetylene Gas

Author(s): Tania Medina-Gil; Anna Sadurní; L. Anders Hammarback; Antonio M. Echavarren
Published in: ACS Catalysis, 2023, Page(s) 10751-10755, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.3c02461

Synthesis of Daucane Natural Products Enabled by a Gold(I)-Catalyzed Tandem Cycloisomerization/(4 + 3) Cycloaddition

Author(s): Àlex Martí, Helena Armengol-Relats, Anna Sadurní, Miquel À. Pérez-Puigdomènech, Antonio M. Echavarren
Published in: Organic Letters, 2025, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.4c04542

Gold-catalyzed Synthesis of Small Rings

Author(s): Mauro Mato; Allegra Franchino; Cristina García-Morales; Antonio M. Echavarren
Published in: Chemical Reviews, Issue 121, 2021, Page(s) 8613-8684, ISSN 0009-2665
Publisher: American Chemical Society
DOI: 10.1021/acs.chemrev.0c00697

Practical Synthesis of Chiral Ferrocenenylphosphino-Gold(I) Catalysts and NEST Analysis of the Enantioinduction

Author(s): Pablo Mora, Imma Escofet, Maria Besora, Federica Cester Bonati, Antonio M. Echavarren
Published in: ACS Catalysis, 2025, Page(s) 2342-2350, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.4c07495

Small Gold(I) and Gold(I)–Silver(I) Clusters by C−Si Auration

Author(s): Xiao‐Li Pei, Ana Pereira, Ekaterina S. Smirnova, Antonio M. Echavarren
Published in: Chemistry – A European Journal, Issue 26/32, 2020, Page(s) 7309-7313, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202001509

H-Bonded Counterion-Directed Enantioselective Au(I) Catalysis

Author(s): Allegra Franchino, Alex Martí, Antonio M. Echavarren
Published in: Journal of the American Chemical Society, Issue 144, 2022, Page(s) 3497-3509, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c11978

Enantioselective Alkoxycyclization of 1,6‐Enynes with Gold(I)‐Cavitands: Total Synthesis of Mafaicheenamine C

Author(s): Inmaculada Martín‐Torres, Gala Ogalla, Jin‐Ming Yang, Antonia Rinaldi, Antonio M. Echavarren
Published in: Angewandte Chemie International Edition, Issue 60/17, 2021, Page(s) 9339-9344, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202017035

Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(i) Catalysts.

Author(s): Ulysse Caniparoli, Imma Escofet, Antonio M. Echavarren
Published in: ACS Catalysis, Issue 12, 2022, Page(s) 3317-3322, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.1c05827

Silver-Free Au(I) Catalysis Enabled by Bifunctional Urea- and Squaramide-Phosphine Ligands via H-Bonding.

Author(s): Allegra Franchino; Àlex Martí; Stefano Nejrotti; Antonio M. Echavarren
Published in: Chemistry A European Journal, Issue 27, 2021, Page(s) 11989-11996, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202101751

"""Three-Component Gold(I)-Catalyzed Alkoxyvinylation"""

Author(s): L. Anders Hammarback; Tania Medina-Gil; Anna Sadurní; Antonio M. Echavarren
Published in: Organic Letters, 2024, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.4c02102

New-Generation Ligand Design for the Gold-Catalyzed Asymmetric Activation of Alkynes

Author(s): Giuseppe Zuccarello; Imma Escofet; Ulysse Caniparoli; Antonio M. Echavarren
Published in: Chempluschem, Issue 2021, 2021, Page(s) 1283-1296, ISSN 2192-6506
Publisher: Wiley-VCH Verlag
DOI: 10.1002/cplu.202100232

Acetylene as a Dicarbene Equivalent for Gold(I) Catalysis: Total Synthesis of Waitziacuminone in One Step

Author(s): Dagmar Scharnagel, Imma Escofet, Helena Armengol‐Relats, M. Elena Orbe, J. Nepomuk Korber, Antonio M. Echavarren
Published in: Angewandte Chemie International Edition, Issue 59/12, 2020, Page(s) 4888-4891, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201915895

H-Bonded Counterion-Directed Catalysis: Enantioselective Gold(i)-Catalyzed Additon to 2-Alkynyl Enones as a Case Study.

Author(s): Martí, A; Montesinos, M; Franchino, A; Echavarren, A.M
Published in: European Journal of Organic Chemistry, Issue 1434193X, 2022, Page(s) e202200518, ISSN 1434-193X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejoc.202200518

Silver-Free Catalysis with Gold(I) Chloride Complexes

Author(s): Allegra Franchino, Marc Montesinos-Magraner, Antonio M. Echavarren
Published in: Bulletin of the chemical society of Japan, Issue 94, 2021, Page(s) 1099-1117, ISSN 0009-2673
Publisher: Chemical Society of Japan/Nippon Kagakukai
DOI: 10.1246/bcsj.20200358

Assembling Complex Structures through Cascade and Cycloaddition Processes via Non-Acceptor Gold or Rhodium Carbenes

Author(s): Helena Armengol-Relats; Mauro Mato; Imma Escofet; Antonio M. Echavarren
Published in: Synthesis, Issue 53, 2021, Page(s) 3991-4003, ISSN 0039-7881
Publisher: Georg Thieme Verlag
DOI: 10.1055/a-1535-3215

Gold(I)-Catalyzed 1,6-Enyne Single-Cleavage Rearrangements: The Complete Picture

Author(s): Eduardo García-Padilla; Feliu Maseras; Antonio M. Echavarren
Published in: ACS Organic and Inorganic Au, 2023, ISSN 2694-247X
Publisher: American Chemical Society
DOI: 10.1021/acsorginorgau.3c00028

Rh(II)-Catalyzed Alkynylcyclopropanation of Alkenes by Decarbenation of Alkynylcycloheptatrienes.

Author(s): Mauro Mato; Marc Montesinos-Magraner; Arnau R. Sugranyes; Antonio M. Echavarren
Published in: Journal of the American Chemical Society, Issue 143, 2021, Page(s) 10760-10769, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c05422

Chiral Auxiliary Approach for Gold(I)-Catalyzed Cyclizations

Author(s): Cataffo, Andrea; Peña-López, Miguel; Pedrazzani, Riccardo; Echavarren, Antonio M.
Published in: Angewandte Chemie International Edition, 2023, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202312874

Enantioselective Catalysis with Pyrrolidinyl Gold(I) Complexes: DFT and NEST Analysis of the Chiral Binding Pocket.

Author(s): Giuseppe Zuccarello; Leonardo J. Nannini; Ana Arroyo-Bondía; Nicolás Fincias; Isabel Arranz; Alba H. Pérez-Jimen; Matthias Peeters; Inmaculada Martín-Torres; Anna Sadurní; Víctor García-Vázquez; Yufei Wang; Mariia S. Kirillova; Marc Montesinos-Magraner; Ulysse Caniparoli; Gonzalo D. Núñez; Feliu Maseras; Maria Besora; Imma Escofet; Antonio M. Echavarren
Published in: JACS AU, 2023, Page(s) 1742-1754, ISSN 2691-3704
Publisher: American Chemical Society
DOI: 10.1021/jacsau.3c00159