Bioinspired Catalytic Metallofoldamers

Project Information

Foldmetcat

Grant agreement ID: 835080

DOI 10.3030/835080

EC signature date 9 April 2019

Start date 1 September 2019

End date 28 February 2025

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 2 500 000,00

EU contribution € 2 500 000,00

Coordinated by

FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA
Spain

Publications

Peer reviewed articles (21)

Assembly of Complex 1,4-Cycloheptadienes by (4+3) Cycloaddition of Rhodium (II) and Gold (II) Non-Acceptor Carbenes

Author(s): Helena Armengol-Relats, Mauro Mato, Antonio M. Echavarren
Published in: Angewandte Chemie International Edition, Issue 60/4, 2021, Page(s) 1916-1922, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202012092

On the Structure of Intermediates in Enyne Gold(I)‐Catalyzed Cyclizations: Formation of trans ‐Fused Bicyclo[5.1.0]octanes as a Case Study

Author(s): Imma Escofet, Helena Armengol‐Relats, Hanna Bruss, Maria Besora, Antonio M. Echavarren
Published in: Chemistry – A European Journal, Issue 26/67, 2020, Page(s) 15738-15745, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202004237

Buchwald‐Type Ligands on Gold(I) Catalysis

Author(s): Giuseppe Zuccarello, Margherita Zanini, Antonio M. Echavarren
Published in: Israel Journal of Chemistry, Issue 60/3-4, 2020, Page(s) 360-372, ISSN 0021-2148
Publisher: Laser Pages Publishing Ltd.
DOI: 10.1002/ijch.201900179

The Puzzling Structure of the Key Intermediates in Gold(I) Catalyzed Cyclizations of Enynes and Allenenes.

Author(s): Eduardo García-Padilla; Imma Escofet; Feliu Maseras; Antonio M. Echavarren
Published in: ChemPlusChem, 2023, ISSN 2192-6506
Publisher: Wiley-VCH Verlag
DOI: 10.1002/cplu.202300502

Hydrogen-Bonded Matched Ion Pair Gold(I) Catalysis

Author(s): Alex Martí; Gala Ogalla; Antonio M. Echavarren
Published in: ACS Catalysis, 2023, Page(s) 10217-10223, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.3c02638

Gold(I)-Catalyzed Intermolecular Aryloxyvinylation with Acetylene Gas

Author(s): Tania Medina-Gil; Anna Sadurní; L. Anders Hammarback; Antonio M. Echavarren
Published in: ACS Catalysis, 2023, Page(s) 10751-10755, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.3c02461

Gold-catalyzed Synthesis of Small Rings

Author(s): Mauro Mato; Allegra Franchino; Cristina García-Morales; Antonio M. Echavarren
Published in: Chemical Reviews, Issue 121, 2021, Page(s) 8613-8684, ISSN 0009-2665
Publisher: American Chemical Society
DOI: 10.1021/acs.chemrev.0c00697

Small Gold(I) and Gold(I)–Silver(I) Clusters by C−Si Auration

Author(s): Xiao‐Li Pei, Ana Pereira, Ekaterina S. Smirnova, Antonio M. Echavarren
Published in: Chemistry – A European Journal, Issue 26/32, 2020, Page(s) 7309-7313, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202001509

H-Bonded Counterion-Directed Enantioselective Au(I) Catalysis

Author(s): Allegra Franchino, Alex Martí, Antonio M. Echavarren
Published in: Journal of the American Chemical Society, Issue 144, 2022, Page(s) 3497-3509, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c11978

Enantioselective Alkoxycyclization of 1,6‐Enynes with Gold(I)‐Cavitands: Total Synthesis of Mafaicheenamine C

Author(s): Inmaculada Martín‐Torres, Gala Ogalla, Jin‐Ming Yang, Antonia Rinaldi, Antonio M. Echavarren
Published in: Angewandte Chemie International Edition, Issue 60/17, 2021, Page(s) 9339-9344, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202017035

Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(i) Catalysts.

Author(s): Ulysse Caniparoli, Imma Escofet, Antonio M. Echavarren
Published in: ACS Catalysis, Issue 12, 2022, Page(s) 3317-3322, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.1c05827

Silver-Free Au(I) Catalysis Enabled by Bifunctional Urea- and Squaramide-Phosphine Ligands via H-Bonding.

Author(s): Allegra Franchino; Àlex Martí; Stefano Nejrotti; Antonio M. Echavarren
Published in: Chemistry A European Journal, Issue 27, 2021, Page(s) 11989-11996, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202101751

New-Generation Ligand Design for the Gold-Catalyzed Asymmetric Activation of Alkynes

Author(s): Giuseppe Zuccarello; Imma Escofet; Ulysse Caniparoli; Antonio M. Echavarren
Published in: Chempluschem, Issue 2021, 2021, Page(s) 1283-1296, ISSN 2192-6506
Publisher: Wiley-VCH Verlag
DOI: 10.1002/cplu.202100232

Acetylene as a Dicarbene Equivalent for Gold(I) Catalysis: Total Synthesis of Waitziacuminone in One Step

Author(s): Dagmar Scharnagel, Imma Escofet, Helena Armengol‐Relats, M. Elena Orbe, J. Nepomuk Korber, Antonio M. Echavarren
Published in: Angewandte Chemie International Edition, Issue 59/12, 2020, Page(s) 4888-4891, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201915895

H-Bonded Counterion-Directed Catalysis: Enantioselective Gold(i)-Catalyzed Additon to 2-Alkynyl Enones as a Case Study.

Author(s): Martí, A; Montesinos, M; Franchino, A; Echavarren, A.M
Published in: European Journal of Organic Chemistry, Issue 1434193X, 2022, Page(s) e202200518, ISSN 1434-193X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejoc.202200518

Silver-Free Catalysis with Gold(I) Chloride Complexes

Author(s): Allegra Franchino, Marc Montesinos-Magraner, Antonio M. Echavarren
Published in: Bulletin of the chemical society of Japan, Issue 94, 2021, Page(s) 1099-1117, ISSN 0009-2673
Publisher: Chemical Society of Japan/Nippon Kagakukai
DOI: 10.1246/bcsj.20200358

Assembling Complex Structures through Cascade and Cycloaddition Processes via Non-Acceptor Gold or Rhodium Carbenes

Author(s): Helena Armengol-Relats; Mauro Mato; Imma Escofet; Antonio M. Echavarren
Published in: Synthesis, Issue 53, 2021, Page(s) 3991-4003, ISSN 0039-7881
Publisher: Georg Thieme Verlag
DOI: 10.1055/a-1535-3215

Gold(I)-Catalyzed 1,6-Enyne Single-Cleavage Rearrangements: The Complete Picture

Author(s): Eduardo García-Padilla; Feliu Maseras; Antonio M. Echavarren
Published in: ACS Organic and Inorganic Au, 2023, ISSN 2694-247X
Publisher: American Chemical Society
DOI: 10.1021/acsorginorgau.3c00028

Rh(II)-Catalyzed Alkynylcyclopropanation of Alkenes by Decarbenation of Alkynylcycloheptatrienes.

Author(s): Mauro Mato; Marc Montesinos-Magraner; Arnau R. Sugranyes; Antonio M. Echavarren
Published in: Journal of the American Chemical Society, Issue 143, 2021, Page(s) 10760-10769, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c05422

Chiral Auxiliary Approach for Gold(I)-Catalyzed Cyclizations

Author(s): Cataffo, Andrea; Peña-López, Miguel; Pedrazzani, Riccardo; Echavarren, Antonio M.
Published in: Angewandte Chemie International Edition, 2023, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202312874

Enantioselective Catalysis with Pyrrolidinyl Gold(I) Complexes: DFT and NEST Analysis of the Chiral Binding Pocket.

Author(s): Giuseppe Zuccarello; Leonardo J. Nannini; Ana Arroyo-Bondía; Nicolás Fincias; Isabel Arranz; Alba H. Pérez-Jimen; Matthias Peeters; Inmaculada Martín-Torres; Anna Sadurní; Víctor García-Vázquez; Yufei Wang; Mariia S. Kirillova; Marc Montesinos-Magraner; Ulysse Caniparoli; Gonzalo D. Núñez; Feliu Maseras; Maria Besora; Imma Escofet; Antonio M. Echavarren
Published in: JACS AU, 2023, Page(s) 1742-1754, ISSN 2691-3704
Publisher: American Chemical Society
DOI: 10.1021/jacsau.3c00159