Dominating redox mechanisms in iron-mediated C-C bond formations: reactivity, new paradigms and applications

Project Information

DoReMI

Grant agreement ID: 852640

DOI

10.3030/852640

Project closed

EC signature date 31 October 2019

Start date 1 July 2020

End date 30 June 2025

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 398 620,00

EU contribution

€ 1 398 620,00

Coordinated by

CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS
France

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Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (12)

Mechanistic facets of the competition between cross-coupling and homocoupling in supporting ligand-free iron-mediated aryl–aryl bond formations

Author(s): Edouard Zhou; Pablo Chourreu; Nicolas Lefèvre; Mathieu Ahr; Lidie Rousseau; Christian Herrero; Eric Gayon; Gérard Cahiez; Guillaume Lefèvre
Published in: ACS Organic & Inorganic Au, Issue 1, 2022, ISSN 2694-247X
Publisher: ACS
DOI: 10.1021/acsorginorgau.2c00002

Bis-alkenyl compounds from group XIV elements (Si, Ge, Sn): synthesis, reactivity and applications.

Author(s): Roxane Arnaudy, Faycel Djebbar, Adrien Tintar, Guillaume Lefèvre
Published in: Synthesis, 2025, ISSN 0039-7881
Publisher: Georg Thieme Verlag
DOI: 10.1055/a-2650-0599

Thermally Stable Redox Noninnocent Bathocuproine-Iron Complex for Cycloaddition Reactions

Author(s): Mae Féo, Nikki J. Bakas, Aleksa Radović, William Parisot, Anne Clisson, Lise-Marie Chamoreau, Mansour Haddad, Virginie Ratovelomanana-Vidal, Michael L. Neidig*, and Guillaume Lefèvre*
Published in: ACS Catalysis, 2023, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.3c00353

Cation-Assisted Hydrosilylation of Alkynes Catalyzed by a Low-Valent Iron Complex Bearing Noninnocent Ligands

Author(s): Nicolas G.-Simonian, Mæ Féo, Clément Tanguy, Claire Troufflard, Guillaume Lefèvre
Published in: ACS Catalysis, Issue 14, 2024, Page(s) 12163-12172, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.4c03153

Influence of a Two-Fold Ligation Pattern on Iron-Mediated Aryl–Heteroaryl Cross-Electrophile Couplings

Author(s): Faycel Djebbar, Lise-Marie Chamoreau, Guillaume Lefèvre
Published in: JACS Au, Issue 5, 2025, Page(s) 2135-2147, ISSN 2691-3704
Publisher: American Chemical Society (ACS)
DOI: 10.1021/jacsau.5c00059

Divergent Fe-Mediated C–H Activation Paths Driven by Alkali Cations

Author(s): Vincent Wowk, Alexis K. Bauer, Aleksa Radovic, Lise-Marie Chamoreau, Michael L. Neidig, Guillaume Lefèvre
Published in: JACS Au, Issue 4, 2024, Page(s) 512-524, ISSN 2691-3704
Publisher: ACS
DOI: 10.1021/jacsau.3c00649

The crucial and multifaceted roles of main-group cations and their salts in iron-mediated cross-couplings

Author(s): Vincent Wowk; Guillaume Lefèvre
Published in: Dalton Transactions, Issue 1, 2022, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2dt00871h

A Solely Fe‐Catalyzed Sonogashira‐Type Coupling of non‐Activated Secondary Alkyl Iodides with Terminal Alkynes

Author(s): Fedor Zhurkin, William Parisot, Guillaume Lefèvre
Published in: Advanced Synthesis & Catalysis, Issue 366, 2024, Page(s) 1782-1787, ISSN 1615-4150
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/adsc.202301340

Relevance of Single-Transmetalated Resting States in Iron-Mediated Cross-Couplings: Unexpected Role of σ-Donating Additives

Author(s): Lidie Rousseau; Nadia Touati; Laurent Binet; Pierre Thuéry; Guillaume Lefèvre
Published in: Inorganic Chemistry, Issue 1, 2021, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.1c00518

The molecular-level effect of alkoxide additives in iron-catalyzed Kumada cross-coupling with simple ferric salts

Author(s): Nikki J. Bakas, Pablo Chourreu, Eric Gayon, Guillaume Lefèvre and Michael L. Neidig
Published in: Chem. Commun., 2023, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2cc06257g

Importance of Two-Electron Processes in Fe-Catalyzed Aryl-(hetero)aryl Cross-Couplings: Evidence of Fe0/FeII Couple Implication

Author(s): Vincent Wowk; Lidie Rousseau; Guillaume Lefèvre
Published in: "Organometallics, American Chemical Society, 2021, 40 (19), pp.3253-3266. ⟨10.1021/acs.organomet.1c00338⟩", Issue 1, 2021, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.1c00338

Ligand dynamics and reactivity of a non-innocent homoleptic iron complex (N,N)2Fe stabilized by phen-type ligands

Author(s): Mae Féo, Faycel Djebbar, Fedor Zhurkin, Laurent Binet, Nadia Touati, Matthew C. Leech, Kevin Lam, Eric Brémond and Guillaume Lefèvre
Published in: Journal of Organometallic Chemistry, 2023, ISSN 0022-328X
Publisher: Elsevier BV
DOI: 10.1016/j.jorganchem.2023.122796