Metalloradical Catalysis - From Fundamental Studies to Applications

Project Information

MetalloRadiCat

Grant agreement ID: 864849

DOI

10.3030/864849

Project closed

EC signature date 13 January 2020

Start date 1 May 2020

End date 31 October 2025

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 2 000 000,00

EU contribution

€ 2 000 000,00

Coordinated by

RHEINISCH-WESTFAELISCHE TECHNISCHE HOCHSCHULE AACHEN
Germany

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (19)

Access to Cyclic N-Trifluoromethyl Ureas through Photocatalytic Activation of Carbamoyl Azides

Author(s): Samir Bouayad-Gervais Christian D.-T. Nielsen Abdurrahman Turksoy Theresa Sperger Kristina Deckers Franziska Schoenebeck
Published in: Journal of the American Chemical Society, Issue 114, 2022, Page(s) 6100 - 6106, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c02004

Modular and Selective Arylation of Aryl Germanes (C−GeEt 3 ) over C−Bpin, C−SiR 3 and Halogens Enabled by Light‐Activated Gold Catalysis

Author(s): Grant J. Sherborne, Avetik G. Gevondian, Ignacio Funes‐Ardoiz, Amit Dahiya, Christoph Fricke, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 59/36, 2020, Page(s) 15543-15548, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202005066

Rapid and Modular Access to Vinyl Cyclopropanes Enabled by Air-stable Palladium(I) Dimer Catalysis

Author(s): M. Mendel, L. Gnägi, U. Dabranskaya, F. Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 62/7, 2023, Page(s) e202211167, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202211167

Site-Selective Nitration of Aryl Germanes at Room Temperature

Author(s): Amit Dahiya; Avetik G. Gevondian; Aymane Selmani; Franziska Schoenebeck
Published in: Organic Letters, Issue 25, 2023, Page(s) 7209 - 7213, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.3c02822

Post-Transition-State Dynamic Effects in the Transmetalation of Pd(II)-F to Pd(II)-CF3

Author(s): Maoping Pu, Christian D.-T. Nielsen, Erdem Senol, Theresa Sperger, Franziska Schoenebeck
Published in: Journal of the American Chemical Society Au, Issue 4/1, 2024, Page(s) 263–275, ISSN 2691-3704
Publisher: ACS
DOI: 10.1021/jacsau.3c00724

Orthogonal Olefination with Organogermanes

Author(s): Amit Dahiya; Markus D. Schoetz; Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 62/43, 2023, Page(s) e202310380, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202310380

Access to N-Difluoromethyl Amides, (Thio)Carbamates, Ureas, and Formamides

Author(s): F. G. Zivkovic, G. Wycich, L. Liu, F. Schoenebeck
Published in: Journal of the American Chemical Society, Issue 146/2, 2024, Page(s) 1276–1281, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c13711

Orthogonal Stability and Reactivity of Aryl Germanes Enables Rapid and Selective (Multi)Halogenations

Author(s): Christoph Fricke, Kristina Deckers, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 59/42, 2020, Page(s) 18717-18722, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202008372

Catalysis with Palladium(I) Dimers

Author(s): Christoph Fricke, Theresa Sperger, Marvin Mendel, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 60/7, 2021, Page(s) 3355, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202011825

Triply Selective & Sequential Diversification at C_sp³: Expansion of Alkyl Germane Reactivity for C−C & C−Heteroatom Bond Formation

Author(s): Eric Ahrweiler; Markus D. Schoetz; Gurdeep Singh; Quentin P. Bindschaedler; Alba Sorroche; Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 63/16, 2024, Page(s) e202401545, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202401545

Selective Synthesis of Z -Silyl Enol Ethers via Ni-Catalyzed Remote Functionalization of Ketones

Author(s): Sinem Guven, Gourab Kundu, Andrea Weßels, Jas S. Ward, Kari Rissanen, Franziska Schoenebeck
Published in: Journal of the American Chemical Society, Issue 143/22, 2021, Page(s) 8375-8380, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c01797

Dynamic stereomutation of vinylcyclopropanes with metalloradicals

Author(s): Marvin Mendel, Teresa M. Karl, Jegor Hamm, Sherif J. Kaldas, Theresa Sperger, Bhaskar Mondal, Franziska Schoenebeck
Published in: Nature, Issue 631, 2024, Page(s) 80-86, ISSN 0028-0836
Publisher: Nature Publishing Group
DOI: 10.1038/s41586-024-07555-1

Recent Developments with Organogermanes: their Preparation and Application in Synthesis and Catalysis

Author(s): T. Rogova, E. Ahrweiler, M. D. Schoetz, F. Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 63/8, 2023, Page(s) e202314709, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202314709

N-CF3 Imidazolidin-2-one Derivatives via Photocatalytic and Silver-Catalyzed Cyclizations

Author(s): Abdurrahman Turksoy, Samir Bouayad-Gervais, Franziska Schoenebeck
Published in: Chemistry A European Journal, Issue 28/46, 2022, Page(s) e202201435, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202201435

A Next‐Generation Air‐Stable Palladium(I) Dimer Enables Olefin Migration and Selective C−C Coupling in Air

Author(s): Gourab Kundu, Theresa Sperger, Kari Rissanen, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 59/49, 2020, Page(s) 21930-21934, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202009115

Modularity in the Csp3 Space─Alkyl Germanes as Orthogonal Molecular Handles for Chemoselective Diversification

Author(s): Aymane Selmani Markus D. Schötz Adele E. Queen Franziska Schoenebeck
Published in: ACS Catalysis, Issue 12/9, 2022, Page(s) 4833 - 3839, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/acscatal.2c00852

Access to <i>N</i>‐Monofluoromethylated (Thio)Carbamates, Formamides, Alkynamides, and Related Derivatives

Author(s): Filip G. Zivkovic, Fritz Bahns, Che‐Ming Hsu, Franziska Schoenebeck
Published in: Angewandte Chemie International Edition, 2025, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202505478

Access to N-CF₃ Formamides by Reduction of N-CF₃ Carbamoyl Fluorides

Author(s): F. G. Zivkovic, C. D.-T. Nielsen, F. Schoenebeck
Published in: Angewandte Chemie International Edition, Issue 61/52, 2022, Page(s) e202213829, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202213829

Orthogonal C–O Bond Construction with Organogermanes

Author(s): Amit Dahiya; Avetik G. Gevondian; Franziska Schoenebeck
Published in: Journal of the American Chemical Society, Issue 145/14, 2023, Page(s) 7729–7735, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c01081