Project description
Synthesising a new class of 2D materials with chiral symmetry
Atomically thin nanomaterials offer a wide variety of chiral 3D shapes such as helices, twists and rolls when a force is applied on their surface. The goal of the EU-funded SENECA project is to create a new class of chiral nanostructures. To do so, it will use organic ligands that will bend and twist the surface of ultrathin nanosheets – 2D colloidal nanoplatelets – into complex shapes. The project will advance fundamental knowledge on nanoscale mechanics and provide a mechanistic framework for the synthetic chemistry of 2D materials. Thanks to their chiroptical properties, the newly synthesised nanomaterials are expected to find wide application in fields as diverse as nanoswimmers, photocatalysis and soft robotics.
Objective
Mechanical instabilities of thin sheets has long been exploited in Nature to create patterns and ensure vital functions such as stimuli responsiveness. By applying forces at the surface of thin objects, it is possible to create a wide variety of chiral 3D shapes such as helices, twists and rolls. Moreover, minute changes on these forces can induce dramatic shape-shifting between different geometries. Our goal is to use this general principle to establish a new class of chiral and addressable nanostructures that current synthetic strategies can not afford. Building on our pioneering results, i will use organic ligands at the surface of two dimensional colloidal nanoplatelets to bend and twist ultrathin nanosheets into complex shapes. We first aim at establishing generic synthetic principles for colloidal 2D materials. To do so, we will develop in situ scattering methods to get atomistic insight on their formation mechanism. We will then determine the link between surface chemistry, interfacial stress and conformation in a set of model systems. Based on these insights, we will design stimuli responsive surface ligands whose conformational change upon excitation by an external stimuli will impact the nanoparticle shape. Finally, understanding the nanoscale colloidal forces and geometric frustration between these new building blocks will enable the design of nanostructured solids made by out-of-equilibrium assembly. This research program will advance our fundamental knowledge on mechanics at the nanoscale and provide a mechanistic framework for synthetic chemistry of 2D materials. The nanoparticles that we will synthesize are expected to have broad applications due to their chiroptical properties and their stimuli responsive character in fields as diverse as nano-swimmers, detection of chiral bio-coumpounds, photo-catalysis, soft-robotic or sensors/actuators.
Fields of science (EuroSciVoc)
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
- natural sciences chemical sciences catalysis photocatalysis
- engineering and technology nanotechnology nano-materials two-dimensional nanostructures
- engineering and technology electrical engineering, electronic engineering, information engineering electronic engineering sensors
- natural sciences mathematics pure mathematics geometry
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Keywords
Project’s keywords as indicated by the project coordinator. Not to be confused with the EuroSciVoc taxonomy (Fields of science)
Project’s keywords as indicated by the project coordinator. Not to be confused with the EuroSciVoc taxonomy (Fields of science)
Programme(s)
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
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H2020-EU.1.1. - EXCELLENT SCIENCE - European Research Council (ERC)
MAIN PROGRAMME
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Topic(s)
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Funding Scheme
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
ERC-COG - Consolidator Grant
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Call for proposal
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
(opens in new window) ERC-2019-COG
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Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.
75794 PARIS
France
The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.