Electrochemical scission of dinitrogen under ambient conditions

Información del proyecto

NitroScission

Identificador del acuerdo de subvención: 866402

DOI

10.3030/866402

Fecha de la firma de la CE 27 Febrero 2020

Fecha de inicio 1 Enero 2021

Fecha de finalización 31 Diciembre 2025

Financiado con arreglo a

• EXCELLENT SCIENCE - European Research Council (ERC)

Coste total

€ 2 744 880,00

Aportación de la UE

€ 2 744 880,00

Coordinado por

IMPERIAL COLLEGE OF SCIENCE TECHNOLOGY AND MEDICINE
United Kingdom

CORDIS proporciona enlaces a los documentos públicos y las publicaciones de los proyectos de los programas marco HORIZONTE.

Los enlaces a los documentos y las publicaciones de los proyectos del Séptimo Programa Marco, así como los enlaces a algunos tipos de resultados específicos, como conjuntos de datos y «software», se obtienen dinámicamente de OpenAIRE .

Publicaciones

Peer reviewed articles (24)

2022 Roadmap on Low Temperature CO2 reduction

Autores: Stephens, I.E.L.; Chan, Karen; Bagger, Alexander; Boettcher, Shannon W.; Bonin, Julien; Boutin, Etienne; Buckley, Aya;Buonsanti, Raffaella; Cave, Etosha; Chang, Xiaoxia; Chee, See Wee; da Silva, Alisson H. M.; De Luna, Phil; Einsle, Oliver; Endrődi, Balázs; Escribano, María Escudero; Ferreira de Araujo, Jorge V.; Figueiredo, Marta C.; Hahn, Christopher; Hansen, Kentaro U.;Haussener, Sophia; Hun
Publicado en: Journal of Physics Energy, 2022, ISSN 2515-7655
Editor: Institute of Physics
DOI: 10.1088/2515-7655/ac7823

An alternative to petrochemicals: biomass electrovalorization

Autores: Zamaan Mukadam, Soren B. Scott, Maria Magdalena Titirici, Ifan E. L. Stephens
Publicado en: Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Edición 382, 2024, ISSN 1364-503X
Editor: Royal Society of London
DOI: 10.1098/rsta.2023.0262

Near ambient N2 fixation on solid electrodes versus enzymes and homogeneous catalysts

Autores: Westhead, O; Barrio, J; Bagger, A; Murray, J; Rossmeisl, J; Titirici, M-M; Jervis, R; Fantuzzi, A Ashley, A; Stephens, IEL
Publicado en: Nature Reviews Chemistry, 2023, ISSN 2397-3358
Editor: Nature Research
DOI: 10.1038/s41570-023-00462-5

Nonaqueous Li-Mediated Nitrogen Reduction: Taking Control of Potentials

Autores: Romain Tort; Olivia Westhead; Matthew Spry; Bethan J. V. Davies; Mary P. Ryan; Maria-Magdalena Titirici; Ifan E. L. Stephens
Publicado en: ACS Energy Letters, Edición 2, 2023, ISSN 2380-8195
Editor: ACS
DOI: 10.1021/acsenergylett.2c02697

Water Increases the Faradaic Selectivity of Li-Mediated Nitrogen Reduction

Autores: Matthew Spry; Olivia Westhead; Romain Tort; Benjamin Moss; Yu Katayama; Maria-Magdalena Titirici; Ifan E. L. Stephens; Alexander Bagger
Publicado en: ACS Energy Letters, Edición 1, 2023, ISSN 2380-8195
Editor: ACS
DOI: 10.1021/acsenergylett.2c02792

Cooperative Effects Drive Water Oxidation Catalysis in Cobalt Electrocatalysts through the Destabilization of Intermediates

Autores: Benjamin Moss, Katrine Louise Svane, David Nieto-Castro, Reshma R. Rao, Soren B. Scott, Cindy Tseng, Michael Sachs, Anuj Pennathur, Caiwu Liang, Louise I. Oldham, Eva Mazzolini, Lole Jurado, Gopinathan Sankar, Stephen Parry, Veronica Celorrio, Jahan M. Dawlaty, Jan Rossmeisl, J. R. Galán-Mascarós, Ifan E. L. Stephens, James R. Durrant
Publicado en: Journal of the American Chemical Society, Edición 146, 2024, Página(s) 8915-8927, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/jacs.3c11651

Unraveling the reaction mechanisms for furfural electroreduction on copper

Autores: Sihang Liu; Zamaan Mukadam; Soren B. Scott; Saurav Ch. Sarma; Maria-Magdalena Titirici; Karen Chan; Nitish Govindarajan; Ifan E. L. Stephens; Georg Kastlunger
Publicado en: EES Catalysis, Edición 3, 2023, ISSN 2753-801X
Editor: Royal Society of Chemistry
DOI: 10.1039/d3ey00040k

Unravelling the effects of active site densities and energetics on the water oxidation activity of iridium oxides

Autores: Caiwu Liang, Reshma Rao, Karine Svane, Joseph Hadden, Benjamin Moss, Soren Scott, Michael Sachs, James Murawski, Adrian Frandsen, Jason Riley, Mary Ryan, James Durrant, Jan Rossmeisl, Ifan Stephens
Publicado en: Nature Catalysis, 2024, ISSN 2520-1158
Editor: Nature Wiley
DOI: 10.21203/rs.3.rs-2605628/v1

Electrochemical Nitrogen Reduction: The Energetic Distance to Lithium

Autores: Alexander Bagger, Romain Tort, Maria-Magdalena Titirici, Aron Walsh, Ifan E. L. Stephens
Publicado en: ACS Energy Letters, Edición 9, 2024, Página(s) 4947-4952, ISSN 2380-8195
Editor: American Chemical Society (ACS)
DOI: 10.1021/acsenergylett.4c01638

Furfural electrovalorisation using single-atom molecular catalysts

Autores: Zamaan Mukadam; Sihang Liu; Angus Pedersen; Jesús Barrio; Sarah Fearn; Saurav Ch. Sarma; Maria-Magdalena Titirici; Soren B. Scott; Ifan E. L. Stephens; Karen Chan; Stefano Mezzavilla
Publicado en: Energy & Environmental Science, Edición 1, 2023, ISSN 1754-5692
Editor: Royal Society of Chemistry
DOI: 10.1039/d3ee00551h

Spectroelectrochemical Analysis of the Water Oxidation Mechanism on Doped Nickel Oxides

Autores: Reshma R. Rao; Sacha Corby; Alberto Bucci; Miguel García-Tecedor; Camilo A. Mesa; Jan Rossmeisl; Sixto Giménez; Julio Lloret-Fillol; Ifan E. L. Stephens; James R. Durrant
Publicado en: Journal of the American Chemical Society, Edición 2, 2022, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/jacs.1c08152

The role of ion solvation in lithium mediated nitrogen reduction

Autores: O. Westhead; M. Spry; A. Bagger; Z. Shen; H. Yadegari; S. Favero; R. Tort; M. Titirici; M. P. Ryan; R. Jervis; Y. Katayama; A. Aguadero; A. Regoutz; A. Grimaud; I. E. L. Stephens
Publicado en: Journal of MAterials Chemistry A, Edición 11, 2023, ISSN 2050-7488
Editor: Royal Society of Chemistry
DOI: 10.1039/d2ta07686a

Role of Ni in PtNi Bimetallic Electrocatalysts for Hydrogen and Value-Added Chemicals Coproduction via Glycerol Electrooxidation

Autores: Hui Luo; Victor Y. Yukuhiro; Pablo S. Fernández; Jingyu Feng; Paul Thompson; Reshma R. Rao; Rongsheng Cai; Silvia Favero; Sarah J. Haigh; James R. Durrant; Ifan E. L. Stephens; Maria-Magdalena Titirici
Publicado en: ACS Catalysis, Edición 1, 2022, ISSN 2155-5435
Editor: American Chemical Society
DOI: 10.1021/acscatal.2c03907

Unraveling the Role of Particle Size and Nanostructuring on the Oxygen Evolution Activity of Fe-Doped NiO

Autores: Reshma R. Rao, Alberto Bucci, Sacha Corby, Benjamin Moss, Caiwu Liang, Aswin Gopakumar, Ifan E. L. Stephens, Julio Lloret-Fillol, James R. Durrant
Publicado en: ACS Catalysis, Edición 14, 2024, Página(s) 11389-11399, ISSN 2155-5435
Editor: American Chemical Society
DOI: 10.1021/acscatal.4c02329

How to Minimise Hydrogen Evolution on Carbon Based Materials?

Autores: Oates, R. P.; Murawski, J.; Hor, C.; Shen, X. Y.; Weber, D. J.; Oezaslan, M.; Shaffer, M. S. P.; Stephens, I. E. L
Publicado en: Journal of Electrochemical Society, 2022, ISSN 0013-4651
Editor: Electrochemical Society, Inc.
DOI: 10.1149/1945-7111/ac67f7

Probing Degradation in Lithium Ion Batteries with On‐Chip Electrochemistry Mass Spectrometry**

Autores: Daisy B. Thornton; Bethan J. V. Davies; Soren B. Scott; Ainara Aguadero; Mary P. Ryan; Ifan E. L. Stephens
Publicado en: Angewandte Chemie International Edition, Edición 3, 2024, ISSN 1521-3773
Editor: Wiley
DOI: 10.1002/ange.202315357

Is lithium the key for nitrogen electroreduction?

Autores: Westhead, Olivia; Jervis, Rhodri; Stephens, Ifan E. L.
Publicado en: Science, 2021, ISSN 1095-9203
Editor: Association for the Advancement of Science
DOI: 10.1126/science.abi8329

Metal coordination in C2N-like materials towards dual atom catalysts for oxygen reduction

Autores: Barrio, J.; Pedersen, A.;Feng, J. Y.;Sarma, S. C.; Wang, M. N.;Li, A. Y.; Yadegari, H.; Luo, H.;Ryan, M. P.; Titirici, M. M.; Stephens, I. E. L.
Publicado en: Journal of Materials Chemistry A, 2022, ISSN 2050-7488
Editor: Royal Society of Chemistry
DOI: 10.1039/d1ta09560a

Direct Electrosynthesis of an Amino Acid from a Biomass Derivative

Autores: Zamaan Mukadam, Sihang Liu, Soren B. Scott, Yuxiang Zhou, Georg Kastlunger, Mary P. Ryan, Maria Magdalena Titirici, Ifan E. L. Stephens
Publicado en: ACS Electrochemistry, Edición 1, 2025, Página(s) 699-708, ISSN 2997-0571
Editor: American Chemical Society (ACS)
DOI: 10.1021/acselectrochem.4c00171

A carbon cathode for lithium mediated electrochemical ammonia synthesis

Autores: Craig Burdis, Romain Tort, Anna Winiwarter, Johannes Rietbrock, Jesús Barrio, Maria Magdalena Titirici, Ifan E. L. Stephens
Publicado en: Energy & Environmental Science, Edición 18, 2025, Página(s) 5897-5901, ISSN 1754-5692
Editor: Royal Society of Chemistry
DOI: 10.1039/d4ee05669h

<i>In situ</i> spectroscopy reveals how water-driven SEI formation controls selectivity in Li-mediated N₂ reduction

Autores: Matthew Spry, Johannes Rietbrock, Olivia Westhead, Craig Burdis, Cindy Tseng, Asuka Morinaga, James O. Douglas, Michele Shelly Conroy, Yasuyuki Kondo, Yuki Yamada, Maria-Magdalena Titirici, Ifan E. L. Stephens, Yu Katayama
Publicado en: Energy &amp; Environmental Science, Edición 18, 2025, Página(s) 8414-8429, ISSN 1754-5692
Editor: Royal Society of Chemistry
DOI: 10.1039/d5ee01961c

Searching for the Rules of Electrochemical Nitrogen Fixation

Autores: Romain Tort; Alexander Bagger; Olivia Westhead; Yasuyuki Kondo; Artem Khobnya; Anna Winiwarter; Bethan J. V. Davies; Aron Walsh; Yu Katayama; Yuki Yamada; Mary P. Ryan; Maria-Magdalena Titirici; Ifan E. L. Stephens
Publicado en: 14513, Edición 4, 2023, ISSN 2155-5435
Editor: American Chemical Society
DOI: 10.1021/acscatal.3c03951

The origin of overpotential in lithium-mediated nitrogen reduction

Autores: O. Westhead; R. Tort; M. Spry; J. Rietbrock; R. Jervis; A. Grimaud; A. Bagger; I. E. L. Stephens
Publicado en: Faraday Discussions, Edición 1, 2023, ISSN 1359-6640
Editor: Royal Society of Chemistry
DOI: 10.1039/d2fd00156j

Methods for nitrogen activation by reduction and oxidation

Autores: Iriawan, H; Zamany, S; Zhang, X; Comer, B; Barrio, J; Chen, PMedford, A;Stephens, I; Chorkendorff, I;Shao-Horn, Y
Publicado en: Nature Reviews Methods Primers, 2021, ISSN 2662-8449
Editor: Springer Nature Limited
DOI: 10.1038/s43586-021-00053-y

Non-peer reviewed articles (1)

The Role of Ethanol in Lithium-Mediated Nitrogen Reduction

Autores: Olivia Westhead, Romain Tort, James O. Douglas, Michele Conroy, Bethan J. V. Davies, Anna Winiwarter, Aishah Faisal, Matthew Spry, Artem Khobnya, Mary P. Ryan, Maria-Magdalena Titirici, Rhodri Jervis, Ifan E. L. Stephens
Publicado en: Journal of the American Chemical Society, Edición 147, 2025, Página(s) 29687-29701, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/jacs.5c03389