Electrochemical scission of dinitrogen under ambient conditions

Informazioni relative al progetto

NitroScission

ID dell’accordo di sovvenzione: 866402

DOI

10.3030/866402

Data della firma CE 27 Febbraio 2020

Data di avvio 1 Gennaio 2021

Data di completamento 31 Dicembre 2025

Finanziato da

• EXCELLENT SCIENCE - European Research Council (ERC)

Costo totale

€ 2 744 880,00

Contributo UE

€ 2 744 880,00

Coordinato da

IMPERIAL COLLEGE OF SCIENCE TECHNOLOGY AND MEDICINE
United Kingdom

CORDIS fornisce collegamenti ai risultati finali pubblici e alle pubblicazioni dei progetti ORIZZONTE.

I link ai risultati e alle pubblicazioni dei progetti del 7° PQ, così come i link ad alcuni tipi di risultati specifici come dataset e software, sono recuperati dinamicamente da .OpenAIRE .

Pubblicazioni

Peer reviewed articles (24)

2022 Roadmap on Low Temperature CO2 reduction

Autori: Stephens, I.E.L.; Chan, Karen; Bagger, Alexander; Boettcher, Shannon W.; Bonin, Julien; Boutin, Etienne; Buckley, Aya;Buonsanti, Raffaella; Cave, Etosha; Chang, Xiaoxia; Chee, See Wee; da Silva, Alisson H. M.; De Luna, Phil; Einsle, Oliver; Endrődi, Balázs; Escribano, María Escudero; Ferreira de Araujo, Jorge V.; Figueiredo, Marta C.; Hahn, Christopher; Hansen, Kentaro U.;Haussener, Sophia; Hun
Pubblicato in: Journal of Physics Energy, 2022, ISSN 2515-7655
Editore: Institute of Physics
DOI: 10.1088/2515-7655/ac7823

An alternative to petrochemicals: biomass electrovalorization

Autori: Zamaan Mukadam, Soren B. Scott, Maria Magdalena Titirici, Ifan E. L. Stephens
Pubblicato in: Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Numero 382, 2024, ISSN 1364-503X
Editore: Royal Society of London
DOI: 10.1098/rsta.2023.0262

Near ambient N2 fixation on solid electrodes versus enzymes and homogeneous catalysts

Autori: Westhead, O; Barrio, J; Bagger, A; Murray, J; Rossmeisl, J; Titirici, M-M; Jervis, R; Fantuzzi, A Ashley, A; Stephens, IEL
Pubblicato in: Nature Reviews Chemistry, 2023, ISSN 2397-3358
Editore: Nature Research
DOI: 10.1038/s41570-023-00462-5

Nonaqueous Li-Mediated Nitrogen Reduction: Taking Control of Potentials

Autori: Romain Tort; Olivia Westhead; Matthew Spry; Bethan J. V. Davies; Mary P. Ryan; Maria-Magdalena Titirici; Ifan E. L. Stephens
Pubblicato in: ACS Energy Letters, Numero 2, 2023, ISSN 2380-8195
Editore: ACS
DOI: 10.1021/acsenergylett.2c02697

Water Increases the Faradaic Selectivity of Li-Mediated Nitrogen Reduction

Autori: Matthew Spry; Olivia Westhead; Romain Tort; Benjamin Moss; Yu Katayama; Maria-Magdalena Titirici; Ifan E. L. Stephens; Alexander Bagger
Pubblicato in: ACS Energy Letters, Numero 1, 2023, ISSN 2380-8195
Editore: ACS
DOI: 10.1021/acsenergylett.2c02792

Cooperative Effects Drive Water Oxidation Catalysis in Cobalt Electrocatalysts through the Destabilization of Intermediates

Autori: Benjamin Moss, Katrine Louise Svane, David Nieto-Castro, Reshma R. Rao, Soren B. Scott, Cindy Tseng, Michael Sachs, Anuj Pennathur, Caiwu Liang, Louise I. Oldham, Eva Mazzolini, Lole Jurado, Gopinathan Sankar, Stephen Parry, Veronica Celorrio, Jahan M. Dawlaty, Jan Rossmeisl, J. R. Galán-Mascarós, Ifan E. L. Stephens, James R. Durrant
Pubblicato in: Journal of the American Chemical Society, Numero 146, 2024, Pagina/e 8915-8927, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.3c11651

Unraveling the reaction mechanisms for furfural electroreduction on copper

Autori: Sihang Liu; Zamaan Mukadam; Soren B. Scott; Saurav Ch. Sarma; Maria-Magdalena Titirici; Karen Chan; Nitish Govindarajan; Ifan E. L. Stephens; Georg Kastlunger
Pubblicato in: EES Catalysis, Numero 3, 2023, ISSN 2753-801X
Editore: Royal Society of Chemistry
DOI: 10.1039/d3ey00040k

Unravelling the effects of active site densities and energetics on the water oxidation activity of iridium oxides

Autori: Caiwu Liang, Reshma Rao, Karine Svane, Joseph Hadden, Benjamin Moss, Soren Scott, Michael Sachs, James Murawski, Adrian Frandsen, Jason Riley, Mary Ryan, James Durrant, Jan Rossmeisl, Ifan Stephens
Pubblicato in: Nature Catalysis, 2024, ISSN 2520-1158
Editore: Nature Wiley
DOI: 10.21203/rs.3.rs-2605628/v1

Electrochemical Nitrogen Reduction: The Energetic Distance to Lithium

Autori: Alexander Bagger, Romain Tort, Maria-Magdalena Titirici, Aron Walsh, Ifan E. L. Stephens
Pubblicato in: ACS Energy Letters, Numero 9, 2024, Pagina/e 4947-4952, ISSN 2380-8195
Editore: American Chemical Society (ACS)
DOI: 10.1021/acsenergylett.4c01638

Furfural electrovalorisation using single-atom molecular catalysts

Autori: Zamaan Mukadam; Sihang Liu; Angus Pedersen; Jesús Barrio; Sarah Fearn; Saurav Ch. Sarma; Maria-Magdalena Titirici; Soren B. Scott; Ifan E. L. Stephens; Karen Chan; Stefano Mezzavilla
Pubblicato in: Energy & Environmental Science, Numero 1, 2023, ISSN 1754-5692
Editore: Royal Society of Chemistry
DOI: 10.1039/d3ee00551h

Spectroelectrochemical Analysis of the Water Oxidation Mechanism on Doped Nickel Oxides

Autori: Reshma R. Rao; Sacha Corby; Alberto Bucci; Miguel García-Tecedor; Camilo A. Mesa; Jan Rossmeisl; Sixto Giménez; Julio Lloret-Fillol; Ifan E. L. Stephens; James R. Durrant
Pubblicato in: Journal of the American Chemical Society, Numero 2, 2022, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.1c08152

The role of ion solvation in lithium mediated nitrogen reduction

Autori: O. Westhead; M. Spry; A. Bagger; Z. Shen; H. Yadegari; S. Favero; R. Tort; M. Titirici; M. P. Ryan; R. Jervis; Y. Katayama; A. Aguadero; A. Regoutz; A. Grimaud; I. E. L. Stephens
Pubblicato in: Journal of MAterials Chemistry A, Numero 11, 2023, ISSN 2050-7488
Editore: Royal Society of Chemistry
DOI: 10.1039/d2ta07686a

Role of Ni in PtNi Bimetallic Electrocatalysts for Hydrogen and Value-Added Chemicals Coproduction via Glycerol Electrooxidation

Autori: Hui Luo; Victor Y. Yukuhiro; Pablo S. Fernández; Jingyu Feng; Paul Thompson; Reshma R. Rao; Rongsheng Cai; Silvia Favero; Sarah J. Haigh; James R. Durrant; Ifan E. L. Stephens; Maria-Magdalena Titirici
Pubblicato in: ACS Catalysis, Numero 1, 2022, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.2c03907

Unraveling the Role of Particle Size and Nanostructuring on the Oxygen Evolution Activity of Fe-Doped NiO

Autori: Reshma R. Rao, Alberto Bucci, Sacha Corby, Benjamin Moss, Caiwu Liang, Aswin Gopakumar, Ifan E. L. Stephens, Julio Lloret-Fillol, James R. Durrant
Pubblicato in: ACS Catalysis, Numero 14, 2024, Pagina/e 11389-11399, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.4c02329

How to Minimise Hydrogen Evolution on Carbon Based Materials?

Autori: Oates, R. P.; Murawski, J.; Hor, C.; Shen, X. Y.; Weber, D. J.; Oezaslan, M.; Shaffer, M. S. P.; Stephens, I. E. L
Pubblicato in: Journal of Electrochemical Society, 2022, ISSN 0013-4651
Editore: Electrochemical Society, Inc.
DOI: 10.1149/1945-7111/ac67f7

Probing Degradation in Lithium Ion Batteries with On‐Chip Electrochemistry Mass Spectrometry**

Autori: Daisy B. Thornton; Bethan J. V. Davies; Soren B. Scott; Ainara Aguadero; Mary P. Ryan; Ifan E. L. Stephens
Pubblicato in: Angewandte Chemie International Edition, Numero 3, 2024, ISSN 1521-3773
Editore: Wiley
DOI: 10.1002/ange.202315357

Is lithium the key for nitrogen electroreduction?

Autori: Westhead, Olivia; Jervis, Rhodri; Stephens, Ifan E. L.
Pubblicato in: Science, 2021, ISSN 1095-9203
Editore: Association for the Advancement of Science
DOI: 10.1126/science.abi8329

Metal coordination in C2N-like materials towards dual atom catalysts for oxygen reduction

Autori: Barrio, J.; Pedersen, A.;Feng, J. Y.;Sarma, S. C.; Wang, M. N.;Li, A. Y.; Yadegari, H.; Luo, H.;Ryan, M. P.; Titirici, M. M.; Stephens, I. E. L.
Pubblicato in: Journal of Materials Chemistry A, 2022, ISSN 2050-7488
Editore: Royal Society of Chemistry
DOI: 10.1039/d1ta09560a

Direct Electrosynthesis of an Amino Acid from a Biomass Derivative

Autori: Zamaan Mukadam, Sihang Liu, Soren B. Scott, Yuxiang Zhou, Georg Kastlunger, Mary P. Ryan, Maria Magdalena Titirici, Ifan E. L. Stephens
Pubblicato in: ACS Electrochemistry, Numero 1, 2025, Pagina/e 699-708, ISSN 2997-0571
Editore: American Chemical Society (ACS)
DOI: 10.1021/acselectrochem.4c00171

A carbon cathode for lithium mediated electrochemical ammonia synthesis

Autori: Craig Burdis, Romain Tort, Anna Winiwarter, Johannes Rietbrock, Jesús Barrio, Maria Magdalena Titirici, Ifan E. L. Stephens
Pubblicato in: Energy & Environmental Science, Numero 18, 2025, Pagina/e 5897-5901, ISSN 1754-5692
Editore: Royal Society of Chemistry
DOI: 10.1039/d4ee05669h

<i>In situ</i> spectroscopy reveals how water-driven SEI formation controls selectivity in Li-mediated N₂ reduction

Autori: Matthew Spry, Johannes Rietbrock, Olivia Westhead, Craig Burdis, Cindy Tseng, Asuka Morinaga, James O. Douglas, Michele Shelly Conroy, Yasuyuki Kondo, Yuki Yamada, Maria-Magdalena Titirici, Ifan E. L. Stephens, Yu Katayama
Pubblicato in: Energy &amp; Environmental Science, Numero 18, 2025, Pagina/e 8414-8429, ISSN 1754-5692
Editore: Royal Society of Chemistry
DOI: 10.1039/d5ee01961c

Searching for the Rules of Electrochemical Nitrogen Fixation

Autori: Romain Tort; Alexander Bagger; Olivia Westhead; Yasuyuki Kondo; Artem Khobnya; Anna Winiwarter; Bethan J. V. Davies; Aron Walsh; Yu Katayama; Yuki Yamada; Mary P. Ryan; Maria-Magdalena Titirici; Ifan E. L. Stephens
Pubblicato in: 14513, Numero 4, 2023, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.3c03951

The origin of overpotential in lithium-mediated nitrogen reduction

Autori: O. Westhead; R. Tort; M. Spry; J. Rietbrock; R. Jervis; A. Grimaud; A. Bagger; I. E. L. Stephens
Pubblicato in: Faraday Discussions, Numero 1, 2023, ISSN 1359-6640
Editore: Royal Society of Chemistry
DOI: 10.1039/d2fd00156j

Methods for nitrogen activation by reduction and oxidation

Autori: Iriawan, H; Zamany, S; Zhang, X; Comer, B; Barrio, J; Chen, PMedford, A;Stephens, I; Chorkendorff, I;Shao-Horn, Y
Pubblicato in: Nature Reviews Methods Primers, 2021, ISSN 2662-8449
Editore: Springer Nature Limited
DOI: 10.1038/s43586-021-00053-y

Non-peer reviewed articles (1)

The Role of Ethanol in Lithium-Mediated Nitrogen Reduction

Autori: Olivia Westhead, Romain Tort, James O. Douglas, Michele Conroy, Bethan J. V. Davies, Anna Winiwarter, Aishah Faisal, Matthew Spry, Artem Khobnya, Mary P. Ryan, Maria-Magdalena Titirici, Rhodri Jervis, Ifan E. L. Stephens
Pubblicato in: Journal of the American Chemical Society, Numero 147, 2025, Pagina/e 29687-29701, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.5c03389