Earth-Abundant Metals with Exclusively Achiral Ligands for Sustainable Chiral-at-Metal Catalysis

Project Information

EARTHCAM

Grant agreement ID: 883212

DOI

10.3030/883212

EC signature date 7 April 2020

Start date 1 January 2021

End date 31 December 2026

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 2 264 184,00

EU contribution

€ 2 264 184,00

Coordinated by

PHILIPPS UNIVERSITAET MARBURG
Germany

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (16)

Development of Chiral‐At‐Ruthenium Mesoionic Carbene Catalysts

Author(s): Nemrud Demirel, Paul Moths, Xiulan Xie, Sergei I. Ivlev, Eric Meggers
Published in: Chemistry – A European Journal, Issue 31, 2025, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202403792

Trading Symmetry for Stereoinduction in Tetradentate, non‐ <i>C</i> ₂ ‐Symmetric Fe(II)‐Complexes for Asymmetric Catalysis

Author(s): Philipp S. Steinlandt; Marcel Hemming; Xiulian Xie; Sergei I. Ivlev; Eric Meggers
Published in: Chemistry - A European Journal, 2023, Page(s) e202300267, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202300267

Enantioselective and Enantioconvergent Iron-Catalyzed C(sp3)-H Aminations to Chiral 2-Imidazolidinones

Author(s): Tianjiao Cui; Chen-Xi Ye; Jordan Thelemann; Daniel Jenisch; Eric Meggers
Published in: Chinese Journal of Chemistry, 2023, Page(s) 2065-2070, ISSN 1614-7065
Publisher: SIOC, CAS and Wiley-VCH GmbH
DOI: 10.1002/cjoc.202300162

Expedited synthesis of α-amino acids by single-step enantioselective α-amination of carboxylic acids

Author(s): Chen-Xi Ye; Drew R. Dansby; Shuming Chen; Eric Meggers
Published in: Nature Synthesis, 2023, ISSN 2731-0582
Publisher: Springer Nature
DOI: 10.1038/s44160-023-00267-w

Chiral-at-Iron Catalyst for Highly Enantioselective and Diastereoselective Hetero-Diels-Alder Reaction.

Author(s): Yubiao Hong; Tianjiao Cui; Sergei I. Ivlev; Xiulan Xie; Eric Meggers
Published in: Chemistry - A European Journal, Issue 09476539, 2021, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202100703

β³-Tryptophans by Iron-Catalyzed Enantioselective Amination of 3-Indolepropionic Acids

Author(s): Bing Zhou, Marisa I. Ih, Suyang Yao, Marcel Hemming, Sergei I. Ivlev, Shuming Chen, Eric Meggers
Published in: Organic Letters, Issue 26, 2024, Page(s) 8361-8365, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.4c03130

N-Boc-Protected α-Amino Acids by 1,3-Migratory Nitrene C(sp3)−H Insertion

Author(s): Bing Zhou; Chen-Xi Ye; Eric Meggers
Published in: European Journal of Organic Chemistry, 2023, Page(s) e202300296, ISSN 1099-0690
Publisher: Wiley-VCH GmbH
DOI: 10.1002/ejoc.202300296

Stereogenic-at-Iron Catalysts with a Chiral Tripodal Pentadentate Ligand

Author(s): Philipp S. Steinlandt; Xiulan Xie; Sergei I. Ivlev; Eric Meggers
Published in: ACS Catalysis, Issue 21555435, 2021, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.1c01675

Stereogenic-at-iron mesoionic carbene complex for enantioselective C–H amidation

Author(s): Nemrud Demirel, Mahiob Dawor, Greta Nadler, Sergei I. Ivlev, Eric Meggers
Published in: Chemical Science, Issue 15, 2024, Page(s) 15625-15631, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4sc03504f

Metal Stereogenicity in Asymmetric Transition Metal Catalysis

Author(s): Philipp S. Steinlandt; Lilu Zhang; Eric Meggers
Published in: Chemical Reviews, 2023, Page(s) 4764-4794, ISSN 0009-2665
Publisher: American Chemical Society
DOI: 10.1021/acs.chemrev.2c00724

Improving the Configurational Stability of Chiral-at-Iron Catalysts Containing Two <i>N</i>-(2-Pyridyl)-Substituted N-Heterocyclic Carbene Ligands

Author(s): Nemrud Demirel; Jakob Haber; Sergei I. Ivlev; Eric Meggers
Published in: Organometallics, 2022, Page(s) 3852-3860, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.2c00492

Chiral-at-metal catalysts: history, terminology, design, synthesis, and applications

Author(s): Lilu Zhang, Eric Meggers
Published in: Chemical Society Reviews, Issue 54, 2025, Page(s) 1986-2005, ISSN 0306-0012
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4cs01043d

Coordination-induced axial chirality controls the metal-centred configuration in a stereogenic-at-iron catalyst

Author(s): Benedikt Buchberger, Nemrud Demirel, Xiulan Xie, Sergei I. Ivlev, Eric Meggers
Published in: Chemical Communications, Issue 61, 2025, Page(s) 1894-1897, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4cc06227b

Design of Stereogenic-at-Iron Catalysts with a (3+2+1)-Ligand Sphere

Author(s): Dominik Baran; Lukas Hinterlang; Sergei I. Ivlev; Eric Meggers
Published in: European Journal of Inorganic Chemistry, 2023, Page(s) e202300148, ISSN 1099-0682
Publisher: John Wiley & Sons
DOI: 10.1002/ejic.202300148

Stereocontrolled 1,3-nitrogen migration to access chiral α-amino acids

Author(s): Chen-Xi Ye; Xiang Shen; Shuming Chen; Eric Meggers
Published in: Nature Chemistry, Issue 17554330, 2022, ISSN 1755-4330
Publisher: Nature Publishing Group
DOI: 10.1038/s41557-022-00895-3

α-Amino Acid Synthesis by 1,3-Nitrogen Migration: An Update

Author(s): Eric Meggers, Kuan Yin
Published in: Synthesis, Issue 56, 2024, Page(s) 2670-2680, ISSN 0039-7881
Publisher: Georg Thieme Verlag
DOI: 10.1055/s-0043-1775371