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Molecular dIffusion of organiCs in secondaRy Organic aeroSols and impaCts On Particle chEmistry

Project description

Improving climate prediction

Secondary organic aerosol (SOA) constitutes the main type of particulate matter found in the troposphere and is generated from the organic transformation of various compounds. The experimental characterisation and theoretical description of SOA is technically challenging given the complex reactions implicated in its formation. More importantly, since it plays a central role in air quality, atmospheric chemistry and climate, it is essential to understand how SOA components diffuse within particles. In this context, the EU-funded MICROSCOPE project will combine innovative instrumentation as well as experimental and modelling work to measure diffusion coefficients of organic molecules within SOA under tropospheric-relevant temperatures. The project's findings are expected to improve our ability to predict air quality and future climate.

Objective

Molecular diffusion of organics within secondary organic aerosol (SOA), a main class of tropospheric particles, controls predictions of particle mass, size, mixing state, and cloud formation properties, thus SOA’s role for air quality, atmospheric chemistry and climate. Despite that, measurements of diffusion coefficients of organics in SOA at low, tropospheric relevant temperatures (T) are largely missing.
The objectives of MICROSCOPE are to directly measure diffusion coefficients of organic molecules in SOA particles at T < 290 K, improve parametrizations used to estimate diffusion, test predictions of diffusivity in atmospheric models and assess the impacts on particle chemistry, by the combination of development of innovative instrumentation, experimental and modelling work.
Measuring diffusion coefficients as a function of water activity (aw) and temperature, will be achieved by developing a new flow cell with simultaneous and in-situ T and aw-control for rectangular area fluorescence recovery after photobleaching measurements. The chemical composition of the SOA samples will be determined using high-resolution mass spectrometry, with the goal to improve existing parametrizations used to estimate the diffusion of organics in SOA and derive new ones that directly relate chemical composition to diffusion coefficients. The new T and aw-dependent parametrization will be used along with model output to verify if tropospheric mixing times of organics in SOA particles are < 1 h. Finally, the impact of diffusion of organics on SOA particle reactivity and chemistry will be determined through measuring the degradation rates of peroxides within SOA particles, using aerosol flow tube and X-ray microscopy experiments.
By combining the expertise of two research groups in North America and Europe, state-of-the-art laboratory facilities, and small and large-scale instrumentation, both the scientific as well as the training goals of this action will be reached.

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Programme(s)

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Topic(s)

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Funding Scheme

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MSCA-IF - Marie Skłodowska-Curie Individual Fellowships (IF)

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Call for proposal

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(opens in new window) H2020-MSCA-IF-2019

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Coordinator

PAUL SCHERRER INSTITUT
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 247 606,08
Address
FORSCHUNGSTRASSE 111
5232 VILLIGEN PSI
Switzerland

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Region
Schweiz/Suisse/Svizzera Nordwestschweiz Aargau
Activity type
Research Organisations
Links
Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 247 606,08

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