Design, implementation and production upscaling of novel, high-performance, cluster-based catalysts for CO2 hydrogenation

Información del proyecto

CATCHY

Identificador del acuerdo de subvención: 955650

DOI

10.3030/955650

Proyecto cerrado

Fecha de la firma de la CE 19 Agosto 2020

Fecha de inicio 1 Noviembre 2020

Fecha de finalización 28 Febrero 2025

Financiado con arreglo a

• EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions

Coste total

€ 3 729 508,56

Aportación de la UE

€ 3 729 508,56

Coordinado por

KATHOLIEKE UNIVERSITEIT LEUVEN
Belgium

CORDIS proporciona enlaces a los documentos públicos y las publicaciones de los proyectos de los programas marco HORIZONTE.

Los enlaces a los documentos y las publicaciones de los proyectos del Séptimo Programa Marco, así como los enlaces a algunos tipos de resultados específicos, como conjuntos de datos y «software», se obtienen dinámicamente de OpenAIRE .

Resultado final

Documents, reports (7)

NWT3

School on electronic structure theory completed (NWT3)

NWT5

CATCHY@ISSPIC 21 meeting (NWT5) completed

NWT1

Kick-off training events (NWT1) completed

NWT4

School on characterization of catalysts by x-rays (NWT4) completed

NWT6

Young researcher’s conference completed (NWT6)

NWT2

School on surface catalysis completed (NWT2)

NWT7

Career Launch final training event (NWT7) completed

Other (1)

positions advertised

14 ESR positions advertised (EURAXESS and other websites)

Websites, patent fillings, videos etc. (6)

presentations at conferences

Every ESR has presented results at an international conference

first papers

Every ESR has a first peer-reviewed paper accepted

website intranet and ESR specific info

ESR specific information on the CATCHY website and CATCHY intranet (or area with restricted access) ready

microdocs

Every ESR has made a microdoc /project video (outreach activity - OA2)

website online

CATCHY website publicly available

second papers

Second peer-reviewed paper obtained (accepted) by all ESRs

Publicaciones

Peer reviewed articles (27)

Magnetron Sputtering of Pure δ-Ni₅Ga₃ Thin Films for CO₂ Hydrogenation

Autores: Filippo Romeggio, Jonathan F. Schouenborg, Peter C. K. Vesborg, Ole Hansen, Jakob Kibsgaard, Ib Chorkendorff, Christian D. Damsgaard
Publicado en: ACS Catalysis, Edición 14, 2024, Página(s) 12592-12601, ISSN 2155-5435
Editor: American Chemical Society
DOI: 10.1021/acscatal.4c03345

High‐Pressure Cell for <i>In Situ</i> Grazing Incidence XAS Characterization of Model Catalysts on Planar Supports

Autores: Sumant Phadke, João Coroa, Imran Abbas, Jinlong Yin, Didier Grandjean, Ewald Janssens, Olga V. Safonova
Publicado en: Chemistry–Methods, Edición 4, 2024, Página(s) e202400014, ISSN 2628-9725
Editor: Wiley
DOI: 10.1002/cmtd.202400014

CO2 and H2 Activation on Zinc-Doped Copper Clusters

Autores: Bárbara Zamora, László Nyulászi, Tibor Höltzl
Publicado en: ChemPhysChem, Edición Vol. 25, Edición 1, 2024, Página(s) e202300409, ISSN 1439-4235
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/cphc.202300409

Water Splitting by C60-Supported Vanadium Single Atoms

Autores: Gao-Lei Hou, Tao Yang, Mengyang Li, Jan Vanbuel, Olga V. Lushchikova, Piero Ferrari, Joost M. Bakker, Ewald Janssens
Publicado en: Angewandte Chemie - International Edition, Edición Volume 60, Edición 52, 2022, Página(s) 27095-27101, ISSN 1433-7851
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202112398

Stability and Electronic Structure of Nitrogen-Doped Graphene-Supported Cu_<i>n</i> (<i>n</i> = 1–5) Clusters in Vacuum and under Electrochemical Conditions: Toward Sensor and Catalyst Design

Autores: Márton Guba, Tibor Höltzl
Publicado en: The Journal of Physical Chemistry C, Edición 128, 2024, Página(s) 4677-4686, ISSN 1932-7447
Editor: American Chemical Society
DOI: 10.1021/acs.jpcc.3c06475

Synergy or Antagonism? Exploring the Interplay of SnO₂ and an N-OMC Carbon Capture Medium for the Electrochemical CO₂ Reduction toward Formate

Autores: Kevin Van Daele, Deema Balalta, Saskia Hoekx, Robbe Jacops, Nick Daems, Thomas Altantzis, Deepak Pant, Tom Breugelmans
Publicado en: ACS Applied Energy Materials, Edición 7, 2024, Página(s) 5517-5527, ISSN 2574-0962
Editor: American Chemical Society
DOI: 10.1021/acsaem.4c00994

Recent advances in copper chalcogenides for CO2 electroreduction

Autores: Wenjian Hu, Didier Grandjean, Jan Vaes, Deepak Pant, Ewald Janssens
Publicado en: Physical Chemistry Chemical Physics, Edición 2023, Vol 25, 2023, Página(s) 30785-30799, ISSN 1463-9084
Editor: Royal Society of Chemistry
DOI: 10.1039/d3cp04170k

CO₂ activation by copper oxide clusters: size, composition, and charge state dependence

Autores: Pavol Mikolaj, Barbara Zamora Yusti, László Nyulászi, Joost M. Bakker, Tibor Höltzl, Sandra M. Lang
Publicado en: Physical Chemistry Chemical Physics, Edición 26, 2024, Página(s) 24126-24134, ISSN 1463-9076
Editor: Royal Society of Chemistry
DOI: 10.1039/d4cp02651a

Unveiling the role of C60-supported vanadium single atoms for catalytic overall water splitting

Autores: Mengyang Li, Tao Yang, Joost M. Bakker, Ewald Janssens, Gao-Lei Hou
Publicado en: Cell Reports Physical Science, Edición 2022, Vol 3, Edición 6, 2022, Página(s) 100910, ISSN 2666-3864
Editor: Cell Press
DOI: 10.1016/j.xcrp.2022.100910

Electrochemical Cell for <i>Operando</i> Grazing-Incidence X-ray Absorption Spectroscopic Studies of Low-Loaded Electrodes

Autores: Maximilian Winzely, Adam H. Clark, Justus S. Diercks, Olga Safonova, Peter Rüttimann, Paul M. Leidinger, Sumant Phadke, Thomas J. Schmidt, Juan Herranz
Publicado en: Analytical Chemistry, Edición 96, 2024, Página(s) 20454-20464, ISSN 0003-2700
Editor: American Chemical Society
DOI: 10.1021/acs.analchem.4c04233

IR spectroscopic characterization of the co-adsorption of CO2 and H2 onto cationic Cun+ clusters.

Autores: Olga V. Lushchikova; Máté Szalay; Hossein Tahmasbi; Ludo B. F. Juurlink; Jörg Meyer; Tibor Höltzl; Joost M. Bakker
Publicado en: Physical Chemistry Chemical Physics, Edición 2021, 23, 2021, Página(s) 26661-26673, ISSN 1463-9076
Editor: Royal Society of Chemistry
DOI: 10.1039/d1cp03119h

Co_3−<i>x</i>Fe_<i>x</i>O₄ inverse opals with tunable catalytic activity for high-performance overall water splitting

Autores: Thi Hong Trang Nguyen; Zviadi Zarkua; Chinnabathini Vana Chinnappa; Wenjian Hu; Sreeprasanth Pulinthanathu Sree; Didier Grandjean; Deepak Pant; Ewald Janssens
Publicado en: Nanoscale, Edición 2023, Vol 15, 2023, Página(s) 10306-10318, ISSN 2040-3372
Editor: Royal Society of Chemistry
DOI: 10.1039/d2nr07300e

Screening of transition metal doped copper clusters for CO 2 activation

Autores: Máté Szalay, Dániel Buzsáki, Júlia Barabás, Endre Faragó, Ewald Janssens, László Nyulászi, Tibor Höltzl
Publicado en: Physical Chemistry Chemical Physics, Edición 2021, 23, 2021, Página(s) 21738-21747, ISSN 1463-9076
Editor: Royal Society of Chemistry
DOI: 10.1039/d1cp02220b

Gas phase deposition of well-defined bimetallic gold-silver clusters for photocatalytic applications

Autores: Vana Chinnappa Chinnabathini; Fons Dingenen; Rituraj Borah; Imran Abbas; Johan van der Tol; Zviadi Zarkua; Francesco D'Acapito; Thi Hong Trang Nguyen; Peter Lievens; Didier Grandjean; Sammy W. Verbruggen; Ewald Janssens
Publicado en: Nanoscale, Edición 2023, 15, 2023, Página(s) 6696-6708, ISSN 2040-3372
Editor: Royal Chemical Society
DOI: 10.1039/d2nr07287d

Electrochemical restructuring of H₂O₂ activated copper selenide for CO₂ reduction

Autores: Wenjian Hu, Deema Balalta, Zhiyuan Chen, Imran Abbas, Jia Song, Balázs Barhács, Márton Guba, Tibor Höltzl, Francesco D'Acapito, Thomas Altantzis, Jan Vaes, Sara Bals, Didier Grandjean, Deepak Pant, Ewald Janssens
Publicado en: Nanoscale, Edición 17, 2025, Página(s) 17075-17085, ISSN 2040-3364
Editor: Royal Society of Chemistry
DOI: 10.1039/d5nr02511g

Scalable synthesis of Cu-cluster catalysts via spark ablation for the electrochemical conversion of CO2 to acetaldehyde

Autores: Cedric David Koolen, Jack Kirk Pedersen, Bernardus Zijlstra, Maximilian Winzely, Jie Zhang, Tobias V. Pfeiffer, Wilbert Vrijburg, Mo Li, Ayush Agarwal, Zohreh Akbari, Yasemen Kuddusi, Juan Herranz, Olga V. Safonova, Andreas Schmidt-Ott, Wen Luo, Andreas Zuettel
Publicado en: Nature Synthesis, Edición 4, 2025, Página(s) 336-346, ISSN 2731-0582
Editor: Springer Nature
DOI: 10.1038/s44160-024-00705-3

Stable mass-selected AuTiO_<i>x</i> nanoparticles for CO oxidation

Autores: Rikke Egeberg Tankard, Filippo Romeggio, Stefan Kei Akazawa, Alexander Krabbe, Olivia Fjord Sloth, Niklas Mørch Secher, Sofie Colding-Fagerholt, Stig Helveg, Richard Palmer, Christian Danvad Damsgaard, Jakob Kibsgaard, Ib Chorkendorff
Publicado en: Physical Chemistry Chemical Physics, Edición 26, 2024, Página(s) 9253-9263, ISSN 1463-9076
Editor: Royal Society of Chemistry
DOI: 10.1039/d4cp00211c

Gold Nanoparticles for CO2 Electroreduction: An Optimum Defined by Size and Shape

Autores: Esperanza Sedano Varo, Rikke Egeberg Tankard, Joakim Kryger-Baggesen, Joerg Jinschek, Stig Helveg, Ib Chorkendorff, Christian Danvad Damsgaard, and Jakob Kibsgaard
Publicado en: Journal of the American Chemical Society, Edición Vol. 146, Edición 3, 2024, Página(s) 2015-2023, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/jacs.3c10610

An experimental perspective on nanoparticle electrochemistry

Autores: Esperanza Sedano Varo, Rikke Egeberg Tankard, Julius Lucas Needham, Esteban Gioria, Filippo Romeggio, Ib Chorkendorff, Christian Danvad Damsgaard, Jakob Kibsgaard
Publicado en: Physical Chemistry Chemical Physics, Edición 26, 2024, Página(s) 17456-17466, ISSN 1463-9076
Editor: Royal Society of Chemistry
DOI: 10.1039/d4cp00889h

The influence of magnetic field on the cluster growth in a magnetron sputtering gas aggregation source

Autores: Joao Coroa, Giuseppe Sanzone, Tibor Höltzl, Hailin Sun, Ewald Janssens, Jinlong Yin
Publicado en: Surface and Coatings Technology, Edición 500, 2025, Página(s) 131892, ISSN 0257-8972
Editor: Elsevier BV
DOI: 10.1016/j.surfcoat.2025.131892

Spectroscopic investigation of size-dependent CO₂ binding on cationic copper clusters: analysis of the CO₂ asymmetric stretch

Autores: A. M. Reider, M. Szalay, J. Reichegger, J. Barabás, M. Schmidt, M. Kappe, T. Höltzl, P. Scheier, O. V. Lushchikova
Publicado en: Physical Chemistry Chemical Physics, Edición 26, 2024, Página(s) 20355-20364, ISSN 1463-9076
Editor: Royal Society of Chemistry
DOI: 10.1039/d4cp01797h

High pressure microreactor for minute amounts of catalyst on planar supports: A case study of CO2 hydrogenation over Pd0.25Zn0.75Ox nanoclusters

Autores: Imran Abbas, Filippo Romeggio, Kacper Pilarczyk, Simon Kuhn, Christian Danvad Damsgaard, Jakob Kibsgaard, Peter Lievens, Didier Grandjean, Ewald Janssens
Publicado en: Chemical Engineering Journal, Edición 503, 2025, Página(s) 158127, ISSN 1385-8947
Editor: Elsevier BV
DOI: 10.1016/j.cej.2024.158127

Tuning the degree of CO2 activation by carbon doping Cun− (n = 3–10) clusters: an IR spectroscopic study

Autores: Olga V. Lushchikova, Máté Szalay, Tibor Höltzl, Joost M. Bakker
Publicado en: Faraday Discussions, Edición 2023, Vol 242, 2022, Página(s) 252-268, ISSN 1359-6640
Editor: Royal Society of Chemistry
DOI: 10.1039/d2fd00128d

Nanostructuring copper thin film electrodes for CO₂ electroreduction to C₂₊ products

Autores: Dimitra Papamichail, Filippo Franceschini, Imran Abbas, Deema Balalta, Trang Thi Hong Nguyen, Deepak Pant, Sara Bals, Irene Taurino, Ewald Janssens, Didier Grandjean, Peter Lievens
Publicado en: Nanoscale, Edición 17, 2025, Página(s) 17745-17757, ISSN 2040-3364
Editor: Royal Society of Chemistry
DOI: 10.1039/d5nr01514f

C2 product formation in the CO2 electroreduction on boron-doped graphene anchored copper clusters

Autores: Tibor Höltzl; Ewald Janssens; Balázs Barhács
Publicado en: Physical Chemistry Chemical Physics, Edición 2022, 24, 2022, Página(s) 21417-21426, ISSN 1463-9076
Editor: Royal Society of Chemistry
DOI: 10.33774/chemrxiv-2021-l969j

Multistep CO2 Activation and Dissociation Mechanisms on PdxPt4–x Clusters in the Gas Phase

Autores: Renata Sechi, Tibor Höltzl
Publicado en: Journal of Physical Chemistry A, Edición 2023, Vol 127, Edición 21, 2023, Página(s) 4596-4608, ISSN 1089-5639
Editor: American Chemical Society
DOI: 10.1021/acs.jpca.2c08333

Room-Temperature Deposition of δ-Ni₅Ga₃ Thin Films and Nanoparticles via Magnetron Sputtering

Autores: Filippo Romeggio, Rasmus Bischoff, Clara B. Møller, Victor L. Jensen, Esteban Gioria, Rikke Egeberg Tankard, Rasmus S. Nielsen, Ole Hansen, Ib Chorkendorff, Jakob Kibsgaard, Christian D. Damsgaard
Publicado en: ACS Omega, Edición 9, 2024, Página(s) 49759-49766, ISSN 2470-1343
Editor: American Chemical Society
DOI: 10.1021/acsomega.4c08405

Other (2)

Scalable synthesis of Cu(-Ag) oxide clusters via spark ablation for the highly selective electrochemical conversion of CO2 to acetaldehyde

Autores: Cedric Koolen, Jack Pedersen, Bernardus Zijlstra, Maximilian Winzely, Jie Zhang, Tobias Pfeiffer, Wilbert Vrijburg, Mo Li, Ayush Agarwal, Zohreh Akbari, Yasemen Kuddusi, Juan Herranz, Olga Safonova, Andreas Schmidt-Ott, Wen Luo, Andreas Züttel
Publicado en: Research Square, 2025, ISSN 2693-5015
Editor: Research Square
DOI: 10.21203/rs.3.rs-3791391/v1

Quantum chemical and microkinetic study of H2 dissociation on Cu4 cluster in the gas phase

Autores: Tibor Höltzl, Máté Szalay
Publicado en: ChemRxiv, 2023
Editor: Cambridge University Press
DOI: 10.26434/chemrxiv-2023-90s5n

Derechos de propiedad intelectual

Registered design (1)

Mask and loading stage

Número de solicitud/publicación: RCD UANT0038EM01
Fecha: 2024-09-27
Solicitante(s): UNIVERSITEIT ANTWERPEN