Design, implementation and production upscaling of novel, high-performance, cluster-based catalysts for CO2 hydrogenation

Informazioni relative al progetto

CATCHY

ID dell’accordo di sovvenzione: 955650

DOI

10.3030/955650

Progetto chiuso

Data della firma CE 19 Agosto 2020

Data di avvio 1 Novembre 2020

Data di completamento 28 Febbraio 2025

Finanziato da

• EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions

Costo totale

€ 3 729 508,56

Contributo UE

€ 3 729 508,56

Coordinato da

KATHOLIEKE UNIVERSITEIT LEUVEN
Belgium

CORDIS fornisce collegamenti ai risultati finali pubblici e alle pubblicazioni dei progetti ORIZZONTE.

I link ai risultati e alle pubblicazioni dei progetti del 7° PQ, così come i link ad alcuni tipi di risultati specifici come dataset e software, sono recuperati dinamicamente da .OpenAIRE .

Risultati finali

Documents, reports (7)

NWT3

School on electronic structure theory completed (NWT3)

NWT5

CATCHY@ISSPIC 21 meeting (NWT5) completed

NWT1

Kick-off training events (NWT1) completed

NWT4

School on characterization of catalysts by x-rays (NWT4) completed

NWT6

Young researcher’s conference completed (NWT6)

NWT2

School on surface catalysis completed (NWT2)

NWT7

Career Launch final training event (NWT7) completed

Other (1)

positions advertised

14 ESR positions advertised (EURAXESS and other websites)

Websites, patent fillings, videos etc. (6)

presentations at conferences

Every ESR has presented results at an international conference

first papers

Every ESR has a first peer-reviewed paper accepted

website intranet and ESR specific info

ESR specific information on the CATCHY website and CATCHY intranet (or area with restricted access) ready

microdocs

Every ESR has made a microdoc /project video (outreach activity - OA2)

website online

CATCHY website publicly available

second papers

Second peer-reviewed paper obtained (accepted) by all ESRs

Pubblicazioni

Peer reviewed articles (36)

Magnetron Sputtering of Pure δ-Ni₅Ga₃ Thin Films for CO₂ Hydrogenation

Autori: Filippo Romeggio, Jonathan F. Schouenborg, Peter C. K. Vesborg, Ole Hansen, Jakob Kibsgaard, Ib Chorkendorff, Christian D. Damsgaard
Pubblicato in: ACS Catalysis, Numero 14, 2024, Pagina/e 12592-12601, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.4c03345

High‐Pressure Cell for <i>In Situ</i> Grazing Incidence XAS Characterization of Model Catalysts on Planar Supports

Autori: Sumant Phadke, João Coroa, Imran Abbas, Jinlong Yin, Didier Grandjean, Ewald Janssens, Olga V. Safonova
Pubblicato in: Chemistry–Methods, Numero 4, 2024, Pagina/e e202400014, ISSN 2628-9725
Editore: Wiley
DOI: 10.1002/cmtd.202400014

CO2 and H2 Activation on Zinc-Doped Copper Clusters

Autori: Bárbara Zamora, László Nyulászi, Tibor Höltzl
Pubblicato in: ChemPhysChem, Numero Vol. 25, Numero 1, 2024, Pagina/e e202300409, ISSN 1439-4235
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/cphc.202300409

Water Splitting by C60-Supported Vanadium Single Atoms

Autori: Gao-Lei Hou, Tao Yang, Mengyang Li, Jan Vanbuel, Olga V. Lushchikova, Piero Ferrari, Joost M. Bakker, Ewald Janssens
Pubblicato in: Angewandte Chemie - International Edition, Numero Volume 60, Numero 52, 2022, Pagina/e 27095-27101, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202112398

Stability and Electronic Structure of Nitrogen-Doped Graphene-Supported Cu_<i>n</i> (<i>n</i> = 1–5) Clusters in Vacuum and under Electrochemical Conditions: Toward Sensor and Catalyst Design

Autori: Márton Guba, Tibor Höltzl
Pubblicato in: The Journal of Physical Chemistry C, Numero 128, 2024, Pagina/e 4677-4686, ISSN 1932-7447
Editore: American Chemical Society
DOI: 10.1021/acs.jpcc.3c06475

Water dehydrogenation and H2O/CO2 co-adsorption on small gas-phase CuxOy+ (x = 2,3; y = 0–2) clusters

Autori: Pavol Mikolaj, Thorsten M. Bernhardt, Sandra M. Lang
Pubblicato in: Applied Catalysis A: General, Numero 706, 2025, Pagina/e 120485, ISSN 0926-860X
Editore: Elsevier BV
DOI: 10.1016/j.apcata.2025.120485

CO₂ Hydrogenation on Gas-Phase Palladium–Zinc Bimetallic Clusters

Autori: Bárbara Zamora Yusti, Eszter Makkos, Ewald Janssens, László Nyulászi, Tibor Höltzl
Pubblicato in: ACS Omega, Numero 10, 2025, Pagina/e 44234-44247, ISSN 2470-1343
Editore: American Chemical Society (ACS)
DOI: 10.1021/acsomega.5c05712

Synergy or Antagonism? Exploring the Interplay of SnO₂ and an N-OMC Carbon Capture Medium for the Electrochemical CO₂ Reduction toward Formate

Autori: Kevin Van Daele, Deema Balalta, Saskia Hoekx, Robbe Jacops, Nick Daems, Thomas Altantzis, Deepak Pant, Tom Breugelmans
Pubblicato in: ACS Applied Energy Materials, Numero 7, 2024, Pagina/e 5517-5527, ISSN 2574-0962
Editore: American Chemical Society
DOI: 10.1021/acsaem.4c00994

Recent advances in copper chalcogenides for CO2 electroreduction

Autori: Wenjian Hu, Didier Grandjean, Jan Vaes, Deepak Pant, Ewald Janssens
Pubblicato in: Physical Chemistry Chemical Physics, Numero 2023, Vol 25, 2023, Pagina/e 30785-30799, ISSN 1463-9084
Editore: Royal Society of Chemistry
DOI: 10.1039/d3cp04170k

Mechanistic Insights into the Electroreduction of Carbon Dioxide to Formate on Palladium

Autori: Maximilian Winzely, Deema Balalta, Adam H. Clark, Tommaso Iarocci, Paul M. Leidinger, Davide Masiello, Meriem Fikry, Tym de Wild, Maximilian Georgi, Sara Bals, Thomas J. Schmidt, Juan Herranz
Pubblicato in: ACS Catalysis, Numero 15, 2025, Pagina/e 17065-17077, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.5c04052

CO₂ activation by copper oxide clusters: size, composition, and charge state dependence

Autori: Pavol Mikolaj, Barbara Zamora Yusti, László Nyulászi, Joost M. Bakker, Tibor Höltzl, Sandra M. Lang
Pubblicato in: Physical Chemistry Chemical Physics, Numero 26, 2024, Pagina/e 24126-24134, ISSN 1463-9076
Editore: Royal Society of Chemistry
DOI: 10.1039/d4cp02651a

Unveiling the role of C60-supported vanadium single atoms for catalytic overall water splitting

Autori: Mengyang Li, Tao Yang, Joost M. Bakker, Ewald Janssens, Gao-Lei Hou
Pubblicato in: Cell Reports Physical Science, Numero 2022, Vol 3, Numero 6, 2022, Pagina/e 100910, ISSN 2666-3864
Editore: Cell Press
DOI: 10.1016/j.xcrp.2022.100910

Electrochemical Cell for <i>Operando</i> Grazing-Incidence X-ray Absorption Spectroscopic Studies of Low-Loaded Electrodes

Autori: Maximilian Winzely, Adam H. Clark, Justus S. Diercks, Olga Safonova, Peter Rüttimann, Paul M. Leidinger, Sumant Phadke, Thomas J. Schmidt, Juan Herranz
Pubblicato in: Analytical Chemistry, Numero 96, 2024, Pagina/e 20454-20464, ISSN 0003-2700
Editore: American Chemical Society
DOI: 10.1021/acs.analchem.4c04233

IR spectroscopic characterization of the co-adsorption of CO2 and H2 onto cationic Cun+ clusters.

Autori: Olga V. Lushchikova; Máté Szalay; Hossein Tahmasbi; Ludo B. F. Juurlink; Jörg Meyer; Tibor Höltzl; Joost M. Bakker
Pubblicato in: Physical Chemistry Chemical Physics, Numero 2021, 23, 2021, Pagina/e 26661-26673, ISSN 1463-9076
Editore: Royal Society of Chemistry
DOI: 10.1039/d1cp03119h

Co_3−<i>x</i>Fe_<i>x</i>O₄ inverse opals with tunable catalytic activity for high-performance overall water splitting

Autori: Thi Hong Trang Nguyen; Zviadi Zarkua; Chinnabathini Vana Chinnappa; Wenjian Hu; Sreeprasanth Pulinthanathu Sree; Didier Grandjean; Deepak Pant; Ewald Janssens
Pubblicato in: Nanoscale, Numero 2023, Vol 15, 2023, Pagina/e 10306-10318, ISSN 2040-3372
Editore: Royal Society of Chemistry
DOI: 10.1039/d2nr07300e

Screening of transition metal doped copper clusters for CO 2 activation

Autori: Máté Szalay, Dániel Buzsáki, Júlia Barabás, Endre Faragó, Ewald Janssens, László Nyulászi, Tibor Höltzl
Pubblicato in: Physical Chemistry Chemical Physics, Numero 2021, 23, 2021, Pagina/e 21738-21747, ISSN 1463-9076
Editore: Royal Society of Chemistry
DOI: 10.1039/d1cp02220b

Gas phase deposition of well-defined bimetallic gold-silver clusters for photocatalytic applications

Autori: Vana Chinnappa Chinnabathini; Fons Dingenen; Rituraj Borah; Imran Abbas; Johan van der Tol; Zviadi Zarkua; Francesco D'Acapito; Thi Hong Trang Nguyen; Peter Lievens; Didier Grandjean; Sammy W. Verbruggen; Ewald Janssens
Pubblicato in: Nanoscale, Numero 2023, 15, 2023, Pagina/e 6696-6708, ISSN 2040-3372
Editore: Royal Chemical Society
DOI: 10.1039/d2nr07287d

Electrochemical restructuring of H₂O₂ activated copper selenide for CO₂ reduction

Autori: Wenjian Hu, Deema Balalta, Zhiyuan Chen, Imran Abbas, Jia Song, Balázs Barhács, Márton Guba, Tibor Höltzl, Francesco D'Acapito, Thomas Altantzis, Jan Vaes, Sara Bals, Didier Grandjean, Deepak Pant, Ewald Janssens
Pubblicato in: Nanoscale, Numero 17, 2025, Pagina/e 17075-17085, ISSN 2040-3364
Editore: Royal Society of Chemistry
DOI: 10.1039/d5nr02511g

Palladium Nanocluster Modification of Mesoporous Copper Oxide Shifts Its Selectivity to C ₂₊ Products in CO ₂

Autori: Thi Hong Trang Nguyen, Jing Shen, Chandani Singh, Dimitra Papamichail, Vana Chinnappa Chinnabathini, Alessia Bardazzi, Deepak Pant, Didier Grandjean, Ewald Janssens
Pubblicato in: ChemSusChem, Numero 18, 2025, Pagina/e 13, ISSN 1864-5631
Editore: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/cssc.202501482

Boundary Conditions for Promotion versus Poisoning in Copper–Gallium-Based CO₂-to-Methanol Hydrogenation Catalysts

Autori: Jan L. Alfke, María Tejeda-Serrano, Sumant Phadke, Andrei Tereshchenko, Terry Z. H. Gani, Lukas Rochlitz, Seraphine B. X. Y. Zhang, Lin Lin, Christophe Copéret, Olga V. Safonova
Pubblicato in: ACS Catalysis, Numero 14, 2024, Pagina/e 9166-9175, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.4c01985

Scalable synthesis of Cu-cluster catalysts via spark ablation for the electrochemical conversion of CO2 to acetaldehyde

Autori: Cedric David Koolen, Jack Kirk Pedersen, Bernardus Zijlstra, Maximilian Winzely, Jie Zhang, Tobias V. Pfeiffer, Wilbert Vrijburg, Mo Li, Ayush Agarwal, Zohreh Akbari, Yasemen Kuddusi, Juan Herranz, Olga V. Safonova, Andreas Schmidt-Ott, Wen Luo, Andreas Zuettel
Pubblicato in: Nature Synthesis, Numero 4, 2025, Pagina/e 336-346, ISSN 2731-0582
Editore: Springer Nature
DOI: 10.1038/s44160-024-00705-3

Monitoring the Activation of a AuCu Aerogel CO₂-Reduction Electrocatalyst via <i>Operando</i> XAS

Autori: Maximilian Winzely, Adam H. Clark, Deema Balalta, Piyush Chauhan, Paul M. Leidinger, Meriem Fikry, Tym de Wild, Maximilian Georgi, Alexander Eychmüller, Sara Bals, Thomas J. Schmidt, Juan Herranz
Pubblicato in: Langmuir, Numero 41, 2025, Pagina/e 11026-11036, ISSN 0743-7463
Editore: American Chemical Society
DOI: 10.1021/acs.langmuir.5c00662

Stable mass-selected AuTiO_<i>x</i> nanoparticles for CO oxidation

Autori: Rikke Egeberg Tankard, Filippo Romeggio, Stefan Kei Akazawa, Alexander Krabbe, Olivia Fjord Sloth, Niklas Mørch Secher, Sofie Colding-Fagerholt, Stig Helveg, Richard Palmer, Christian Danvad Damsgaard, Jakob Kibsgaard, Ib Chorkendorff
Pubblicato in: Physical Chemistry Chemical Physics, Numero 26, 2024, Pagina/e 9253-9263, ISSN 1463-9076
Editore: Royal Society of Chemistry
DOI: 10.1039/d4cp00211c

Gold Nanoparticles for CO2 Electroreduction: An Optimum Defined by Size and Shape

Autori: Esperanza Sedano Varo, Rikke Egeberg Tankard, Joakim Kryger-Baggesen, Joerg Jinschek, Stig Helveg, Ib Chorkendorff, Christian Danvad Damsgaard, and Jakob Kibsgaard
Pubblicato in: Journal of the American Chemical Society, Numero Vol. 146, Numero 3, 2024, Pagina/e 2015-2023, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.3c10610

An experimental perspective on nanoparticle electrochemistry

Autori: Esperanza Sedano Varo, Rikke Egeberg Tankard, Julius Lucas Needham, Esteban Gioria, Filippo Romeggio, Ib Chorkendorff, Christian Danvad Damsgaard, Jakob Kibsgaard
Pubblicato in: Physical Chemistry Chemical Physics, Numero 26, 2024, Pagina/e 17456-17466, ISSN 1463-9076
Editore: Royal Society of Chemistry
DOI: 10.1039/d4cp00889h

Bipolar membrane 3D microlattice electrode assembly design for zero-gap bicarbonate (CO2) electrolysis

Autori: Ramato Ashu Tufa, Babak Rezaei, Wenjian Hu, Debabrata Chanda, Ben Jacobs, Sergio Santoro, Efrem Curcio, Deepak Pant, Stephan Sylvest Keller
Pubblicato in: Chemical Engineering Journal Advances, Numero 24, 2025, Pagina/e 100865, ISSN 2666-8211
Editore: Elsevier BV
DOI: 10.1016/j.ceja.2025.100865

The influence of magnetic field on the cluster growth in a magnetron sputtering gas aggregation source

Autori: Joao Coroa, Giuseppe Sanzone, Tibor Höltzl, Hailin Sun, Ewald Janssens, Jinlong Yin
Pubblicato in: Surface and Coatings Technology, Numero 500, 2025, Pagina/e 131892, ISSN 0257-8972
Editore: Elsevier BV
DOI: 10.1016/j.surfcoat.2025.131892

Spectroscopic investigation of size-dependent CO₂ binding on cationic copper clusters: analysis of the CO₂ asymmetric stretch

Autori: A. M. Reider, M. Szalay, J. Reichegger, J. Barabás, M. Schmidt, M. Kappe, T. Höltzl, P. Scheier, O. V. Lushchikova
Pubblicato in: Physical Chemistry Chemical Physics, Numero 26, 2024, Pagina/e 20355-20364, ISSN 1463-9076
Editore: Royal Society of Chemistry
DOI: 10.1039/d4cp01797h

High pressure microreactor for minute amounts of catalyst on planar supports: A case study of CO2 hydrogenation over Pd0.25Zn0.75Ox nanoclusters

Autori: Imran Abbas, Filippo Romeggio, Kacper Pilarczyk, Simon Kuhn, Christian Danvad Damsgaard, Jakob Kibsgaard, Peter Lievens, Didier Grandjean, Ewald Janssens
Pubblicato in: Chemical Engineering Journal, Numero 503, 2025, Pagina/e 158127, ISSN 1385-8947
Editore: Elsevier BV
DOI: 10.1016/j.cej.2024.158127

Tuning the degree of CO2 activation by carbon doping Cun− (n = 3–10) clusters: an IR spectroscopic study

Autori: Olga V. Lushchikova, Máté Szalay, Tibor Höltzl, Joost M. Bakker
Pubblicato in: Faraday Discussions, Numero 2023, Vol 242, 2022, Pagina/e 252-268, ISSN 1359-6640
Editore: Royal Society of Chemistry
DOI: 10.1039/d2fd00128d

Nanostructuring copper thin film electrodes for CO₂ electroreduction to C₂₊ products

Autori: Dimitra Papamichail, Filippo Franceschini, Imran Abbas, Deema Balalta, Trang Thi Hong Nguyen, Deepak Pant, Sara Bals, Irene Taurino, Ewald Janssens, Didier Grandjean, Peter Lievens
Pubblicato in: Nanoscale, Numero 17, 2025, Pagina/e 17745-17757, ISSN 2040-3364
Editore: Royal Society of Chemistry
DOI: 10.1039/d5nr01514f

C2 product formation in the CO2 electroreduction on boron-doped graphene anchored copper clusters

Autori: Tibor Höltzl; Ewald Janssens; Balázs Barhács
Pubblicato in: Physical Chemistry Chemical Physics, Numero 2022, 24, 2022, Pagina/e 21417-21426, ISSN 1463-9076
Editore: Royal Society of Chemistry
DOI: 10.33774/chemrxiv-2021-l969j

Multistep CO2 Activation and Dissociation Mechanisms on PdxPt4–x Clusters in the Gas Phase

Autori: Renata Sechi, Tibor Höltzl
Pubblicato in: Journal of Physical Chemistry A, Numero 2023, Vol 127, Numero 21, 2023, Pagina/e 4596-4608, ISSN 1089-5639
Editore: American Chemical Society
DOI: 10.1021/acs.jpca.2c08333

Room-Temperature Deposition of δ-Ni₅Ga₃ Thin Films and Nanoparticles via Magnetron Sputtering

Autori: Filippo Romeggio, Rasmus Bischoff, Clara B. Møller, Victor L. Jensen, Esteban Gioria, Rikke Egeberg Tankard, Rasmus S. Nielsen, Ole Hansen, Ib Chorkendorff, Jakob Kibsgaard, Christian D. Damsgaard
Pubblicato in: ACS Omega, Numero 9, 2024, Pagina/e 49759-49766, ISSN 2470-1343
Editore: American Chemical Society
DOI: 10.1021/acsomega.4c08405

Mechanistic insights into methanol production on Ni5Ga3 thin films: An in situ XPS and DFT study

Autori: Robin Y. Engel, Filippo Romeggio, Vivianne K. Ocampo-Restrepo, Jonathan F. Schouenborg, Emanuel R. Billeter, Markus Soldemo, David Degerman, Fernando García-Martínez, Jakob Kibsgaard, Ib Chorkendorf
Pubblicato in: Applied Catalysis B: Environment and Energy, Numero 381, 2025, Pagina/e 125798, ISSN 0926-3373
Editore: Elsevier BV
DOI: 10.1016/j.apcatb.2025.125798

Colloidal Fe nanocrystals for CH ₄ decomposition: role of the support

Autori: Esteban Gioria, Filippo Romeggio, Ruben Bueno Villoro, Ilenia Giarnieri, Patricia Benito, Ib Chorkendorff, Christian D. Damsgaard
Pubblicato in: Journal of Materials Chemistry A, Numero 13, 2025, Pagina/e 27136-27151, ISSN 2050-7488
Editore: Royal Society of Chemistry
DOI: 10.1039/d5ta03667d

Other (2)

Scalable synthesis of Cu(-Ag) oxide clusters via spark ablation for the highly selective electrochemical conversion of CO2 to acetaldehyde

Autori: Cedric Koolen, Jack Pedersen, Bernardus Zijlstra, Maximilian Winzely, Jie Zhang, Tobias Pfeiffer, Wilbert Vrijburg, Mo Li, Ayush Agarwal, Zohreh Akbari, Yasemen Kuddusi, Juan Herranz, Olga Safonova, Andreas Schmidt-Ott, Wen Luo, Andreas Züttel
Pubblicato in: Research Square, 2025, ISSN 2693-5015
Editore: Research Square
DOI: 10.21203/rs.3.rs-3791391/v1

Quantum chemical and microkinetic study of H2 dissociation on Cu4 cluster in the gas phase

Autori: Tibor Höltzl, Máté Szalay
Pubblicato in: ChemRxiv, 2023
Editore: Cambridge University Press
DOI: 10.26434/chemrxiv-2023-90s5n

Diritti di proprietà intellettuale

Registered design (1)

Mask and loading stage

Numero candidatura/pubblicazione: RCD UANT0038EM01
Data: 2024-09-27
Candidato/i: UNIVERSITEIT ANTWERPEN