Objective
In the present application we propose the synthesis of Hg-Na clusters entrapped within zeolite cages in faujasite structures prepared by reduction of Hg- Na exchanged zeolite Y or X with the appropriate reductor (i e alkali-metal vapor alkali-azide. n-butyl-lithium or sodium disolved in liquid ammonia or amines ) . The obtained solids are going to be characterised by ESR Vis-U.V. and MAS-NMR spectroscopies and the environment around the Hg into the clusters formed within the zeolite is going to be studied by EXAFS. The stability of the Hg- Na is going to be studied by microcalorimetry and ESR spectroscopy by adsorption O2. Finally the catalitic activity in side-chain alkylation of toluene with ethylene and butene isomerisation are going to be measure in a flow reactor. These catalysts could extend the basicities availables for base catalys reactions to the superbasicity range (pKa>35).
Fields of science (EuroSciVoc)
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
- natural sciences chemical sciences inorganic chemistry alkali metals
- natural sciences chemical sciences inorganic chemistry inorganic compounds
- natural sciences chemical sciences organic chemistry aliphatic compounds
- natural sciences chemical sciences organic chemistry amines
- natural sciences physical sciences optics spectroscopy
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Coordinator
46022 VALENCIA
Spain
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