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Synthesis characterisation and catalytic activity of hg-na clusters entrapped within the zeolitic cages infaujasite strucutre

Objetivo



In the present application we propose the synthesis of Hg-Na clusters entrapped within zeolite cages in faujasite structures prepared by reduction of Hg- Na exchanged zeolite Y or X with the appropriate reductor (i e alkali-metal vapor alkali-azide. n-butyl-lithium or sodium disolved in liquid ammonia or amines ) . The obtained solids are going to be characterised by ESR Vis-U.V. and MAS-NMR spectroscopies and the environment around the Hg into the clusters formed within the zeolite is going to be studied by EXAFS. The stability of the Hg- Na is going to be studied by microcalorimetry and ESR spectroscopy by adsorption O2. Finally the catalitic activity in side-chain alkylation of toluene with ethylene and butene isomerisation are going to be measure in a flow reactor. These catalysts could extend the basicities availables for base catalys reactions to the superbasicity range (pKa>35).

Ámbito científico (EuroSciVoc)

Programa(s)

Tema(s)

Convocatoria de propuestas

Datos no disponibles

Régimen de financiación

RGI - Research grants (individual fellowships)

Coordinador

UNIVERSIDAD POLITECNICA DE VALENCIA
Aportación de la UE
Sin datos
Dirección
S/N,Avenida de los Naranjos S/N
46022 VALENCIA
España
Coste total
Sin datos