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Silyl and stannylcupration of acetylenes

Objective



The aim of this project is to study some reactions of metallo- metallat of multiple bonds with a great synthetic interest.
The reaction of some acetylenes carrying a silyl or stannyl group with silyl or stannylcuprates will lead to systems containing two or even three metals on the double bond, which makes it a very inte- resting sinthon. From these compounds we will try to introduce different electrophiles selectively on every end of the double bond.
Finally we will apply Knochel's reaction to our substrate in order to obtein C + 1 chains from the original structures.

Call for proposal

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Coordinator

UNIVERSIDAD DE VALLADOLID
EU contribution
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Address
S/N,C/ Dr. Mergelina S/N
47011 VALLADOLID
Spain

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Total cost
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Participants (1)