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Contenido archivado el 2024-05-14

Silyl and stannylcupration of acetylenes

Objetivo



The aim of this project is to study some reactions of metallo- metallat of multiple bonds with a great synthetic interest.
The reaction of some acetylenes carrying a silyl or stannyl group with silyl or stannylcuprates will lead to systems containing two or even three metals on the double bond, which makes it a very inte- resting sinthon. From these compounds we will try to introduce different electrophiles selectively on every end of the double bond.
Finally we will apply Knochel's reaction to our substrate in order to obtein C + 1 chains from the original structures.

Ámbito científico (EuroSciVoc)

Programa(s)

Tema(s)

Convocatoria de propuestas

Datos no disponibles

Régimen de financiación

RGI - Research grants (individual fellowships)

Coordinador

UNIVERSIDAD DE VALLADOLID
Aportación de la UE
Sin datos
Dirección
S/N,C/ Dr. Mergelina S/N
47011 VALLADOLID
España
Coste total
Sin datos

Participantes (1)