New methods for determining molecular conformation by solid state nuclear magnetic resonance spectroscopy

Informations projet

N° de convention de subvention: FMBI960917

Projet clôturé

Date de début 1 Août 1996

Date de fin 31 Juillet 1998

Financé au titre de

• Specific research and technological development programme in the field of the training and mobility of researchers, 1994-1998

Coût total Aucune donnée

Contribution de l’UE Aucune donnée

Coordonné par

ECOLE NORMALE SUPERIEURE DE LYON
France

Objectif

The principle problem involved in the determination of molecular structural information by NMR spectroscopy is that of overcoming the extreme complexity of the spectra obtained from abundant spins. I propose to develop multi-dimensional solid state NMR techniques to simplify dramatically the spectrum. The techniques are based on proton detected dipolar local fields. Techniques of this kind are currently limited by the efficiency of multiple pulse homonuclear dipolar decoupling schemes, and I propose to introduce improved pulse sequences which will extend the use of these techniques to the accurate measurement of larger and larger internuclear distances, thereby allowing application to the determination of structural parameters in complex oriented phases such as liquid crystals and lipids. The proposed formalisms and techniques should also have implications for improving the sensitivity and resolution of solid state NMR through their application in other areas such as cross polarization and heteronuclear decoupling. The ideas presented represent a significant step towards the determination of molecular structures in solids by NMR.

Champ scientifique (EuroSciVoc)

CORDIS classe les projets avec EuroSciVoc, une taxonomie multilingue des domaines scientifiques, grâce à un processus semi-automatique basé sur des techniques TLN. Voir: https://op.europa.eu/en/web/eu-vocabularies/euroscivoc.

• sciences naturelles › sciences biologiques › biochimie › biomolécule › lipides
• sciences naturelles › sciences physiques › optique › spectroscopie › spectrométrie d’absorption
• ingénierie et technologie › ingénierie des materiaux › cristal liquide

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Programme(s)

• FP4-TMR - Specific research and technological development programme in the field of the training and mobility of researchers, 1994-1998

Thème(s)

• 0302 - Post-doctoral research training grants
• TC04 - Instrumental Techniques, Analysis and Sensors

Appel à propositions

Données non disponibles

Régime de financement

RGI -

Coordinateur

ECOLE NORMALE SUPERIEURE DE LYON

• Contribution de l’UE: Aucune donnée
• Adresse: AllTe d'Italie 46 ; 69364 LYON ; France
• Coût total: Aucune donnée

Participants (1)

Not available

Italie

• Contribution de l’UE: Aucune donnée
• Coût total: Aucune donnée