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Contenido archivado el 2024-04-30

Isolation and characterization of main-group metal-alkene coordination complexes

Objetivo



In the frame work of an earlier EC-research project we investigated the syntheses and structures of various main-group (ansa)-metallocene complexes. Especially the investigations on a novel group of metallocene complexes, anionic alkalimetallocenes, have been rewarding.
In the course of our research we isolated a hitherto unseen complex of a main-group metal with a neutral alkene functionality. Such metal-alkene coordination complexes are generally accepted to be intermediates in the nucleophilic addition of polar organometallic compounds to alkenes. These results call for a more advanced investigation of main-group metal-alkene coordination. In the hereby requested continuation of our EC-project we will investigate the coordination chemistry of neutral alkenes and Group I/II metallocenes, using all available techniques like high-pressure IR spectroscopy, calculational methods, NMR and X-ray diffraction. The results of the proposed research will not only be of academic interest but will also be significant for a deeper understanding of alkene polymerization catalyses.

Ámbito científico (EuroSciVoc)

Programa(s)

Tema(s)

Convocatoria de propuestas

Datos no disponibles

Régimen de financiación

RGI - Research grants (individual fellowships)

Coordinador

UNIVERSITAET KONSTANZ
Aportación de la UE
Sin datos
Dirección
Universitaetstrasse 10
78457 KONSTANZ
Alemania
Coste total
Sin datos

Participantes (1)