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Hydrated Electrons from iRradiated metal-free semicOnductors for Per- and poly-FluoroAlkyl Substances degradation in water

Project description

A new approach to clean water

Per- and poly-fluoroalkyl substances (PFAS) are synthetic chemicals used in many industries, but they have become a serious environmental problem. They are resistant to breakdown and are commonly found in water near industrial areas, posing significant health risks, including cancer. Current water treatment methods struggle to remove PFAS completely, leaving contaminated sites across Europe. A solution is urgently needed to protect both drinking water and the environment. Supported by the Marie Skłodowska-Curie Actions programme, the HERO4PFAS project is developing low-cost materials that use UV light to produce hydrated electrons capable of breaking down PFAS. This new technology aims to create efficient and affordable water treatment systems that can fully eliminate these harmful chemicals.

Objective

Per- and poly-fluoroalkyl substances (PFAS) are a group of man-made chemicals produced for several applications, ubiquitous in water bodies close to industrialised regions, and with recognized associated issues to human health (e.g. carcinogenicity). Being among the most recalcitrant class of emerging contaminants, an efficient water treatment able to degrade PFAS will represent an outstanding technology, not only for the recovery of already contaminated sites (impressively spread in Europe), but also for drinking- and waste-water treatment plants. The project proposal, “Hydrated Electrons from iRradiated metal-free semicOnductors for PFAS degradation in water (HERO4PFAS)”, focuses on the development and investigation of wide band gap semiconductors able to photo-produce hydrated electrons under ultraviolet (UV) light to eliminate PFAS from water. The main goal will be to evolve from the state-of-the-art homogeneous advanced reduction processes (ARPs) towards heterogeneous systems to be employed in real cases. Since very expensive materials are required to photo-produce hydrated electrons (e.g. diamond-carbon), in this project low-cost photocatalysts based on hexagonal boron nitride will be prepared, and their ability in the degradation of PFAS studied under different conditions (type of irradiation, pH, dissolved oxygen). Systems based on heterogeneous UV-ARP will be implemented for the removal of PFAS from retentate streams of advanced membrane filtration systems and coupled with advanced oxidation processes in a holistic treatment train able to reach the complete PFAS mineralization. HERO4PFAS will fill the gap between PFAS degradation and the development of a cost-efficient heterogeneous photo-ARP.
With the support of my supervisor (Prof. Minella) at University of Turin, I will diversify my individual competences to materials science and UV-ARP chemistry, boosting my career as future expert on photocatalysis and water treatment technology.

Keywords

Programme(s)

Topic(s)

Funding Scheme

HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

(opens in new window) HORIZON-MSCA-2023-PF-01

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Coordinator

UNIVERSITA DEGLI STUDI DI TORINO
Net EU contribution
€ 172 750,08
Address
VIA GIUSEPPE VERDI 8
10124 Torino
Italy
Region
Nord-Ovest Piemonte Torino
Activity type
Higher or Secondary Education Establishments
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Total cost
No data