Descripción del proyecto
Un estudio aspira a desvelar por qué el hidrógeno causa la rotura de los metales resistentes
El hidrógeno es un elemento fundamental en la transición hacia las energías limpias. Los métodos de almacenamiento y transporte seguros y rentables son esenciales pero complicados, puesto que los metales cambian su resistencia cuando entran en contacto con el hidrógeno. El proyecto TRITIME, financiado con fondos europeos, aspira a lograr una mejor comprensión de cómo y por qué la ductilidad metálica se reduce debido a la absorción de hidrógeno utilizando métodos que incluyen el tritio, un isótopo del hidrógeno. TRITIME realizará pruebas mecánicas en muestras que contengan solo algunos defectos cristalinos para aislar y observar mejor este fenómeno, que se denomina «fragilidad producida por el hidrógeno».
Objetivo
Hydrogen is an indispensable element in the energy transition and expected to be key for decarburization of the European society. Hydrogen embrittlement – recognized and in focus of materials science since almost 150 years – still causes catastrophic failure until today. It is well-understood that all mechanisms of hydrogen embrittlement materialize at the scale of individual defects, such as dislocations, grain- and phase-boundaries. But we are still missing a correlative measurement of the mechanical behaviour of individual defects and the local hydrogen content, which is urgently needed to assess the occurrence, importance and magnitude of mechanisms playing a role during hydrogen embrittlement. In aid of this, TRITIME for the first time facilitates the isolation, observation and quantification of hydrogen embrittlement mechanisms by TRITIum based microMEchanics. The mechanisms of hydrogen embrittlement will be isolated by small scale mechanical testing on samples containing only a few crystal defects. The defect properties are observed and measured by in situ micromechanical experiments in the scanning electron microscope and at synchrotron beamlines. Simultaneously, TRITIME will monitor the local hydrogen content by observing the decay of tritium with high spatial resolution, for which a unique tool will be developed. In addition, post mortem analysis using atom probe tomography and secondary ion mass spectroscopy take advantage of the reduced mobility of tritium. TRITIME will provide unprecedented insights into the local hydrogen content of newly formed slip bands, mobile and immobile dislocations and fracture surfaces. Consequently, if successful, TRITIME will obtain a mechanism-based, quantitative understanding of HEDE, HELP and their interplay. In doing so, TRITIME sets the base for a mechanism-based optimization of microstructures used in distribution and storage of hydrogen and, therefore, is an indispensable tool towards Europe`s hydrogen society.
Ámbito científico
Programa(s)
- HORIZON.1.1 - European Research Council (ERC) Main Programme
Régimen de financiación
HORIZON-AG - HORIZON Action Grant Budget-BasedInstitución de acogida
76131 Karlsruhe
Alemania