Engineering of Photo-rechargeable Nanoswimmers using Multicomponent Heterojunctions

Informazioni relative al progetto

PhotoSwim

ID dell’accordo di sovvenzione: 101076680

DOI

10.3030/101076680

Data della firma CE 28 Novembre 2022

Data di avvio 1 Maggio 2023

Data di completamento 30 Aprile 2028

Finanziato da

• European Research Council (ERC)

Costo totale

€ 1 500 000,00

Contributo UE

€ 1 500 000,00

Coordinato da

FUNDACIO INSTITUT CATALA D'INVESTIGACIO QUIMICA
Spain

Periodic Reporting for period 1 - PhotoSwim (Engineering of Photo-rechargeable Nanoswimmers using Multicomponent Heterojunctions)

Periodo di rendicontazione: 2023-05-01 al 2025-10-31

Sintesi del contesto e degli obiettivi generali del progetto

Inspired by nature, researchers can design tiny devices that take up energy from their surroundings and transform it into motion, mimicking natural microswimmers. However, current photoactive nanoswimmers require constant energy input to keep their functionalities, which limits their applicability in specific environments (e.g. turbid samples, biological media). The ERC-funded PhotoSwim project addresses this key challenge by proposing a new generation of light-rechargeable nanoswimmers. The central idea is to create hybrid nanoswimmers consisting not only of photocatalytic but also luminescent materials. These materials will enable the photoactivated swimmers to store and emit sufficient energy to keep working in the absence of constant light irradiation and exhibit long-term luminescence for tracking purposes. Researchers will investigate how to programme the nanoswimmer motion activation in the dark by modulating the energy/charge transfer among components, making them suitable for operation in complex, variable environments.

The overall objective of the PhotoSwim project is to design a new class of hybrid nanoswimmers that combine light harvesting and energy storage within a single microscale system, enabling them to operate autonomously upon a pre-charging step. This approach will establish fundamental principles for energy transfer and delayed activation at the nanoscale, while opening new opportunities for future applications in environmental remediation, light-driven technologies, and antimicrobial resistance.

Lavoro eseguito dall’inizio del progetto fino alla fine del periodo coperto dalla relazione e principali risultati finora ottenuti

Over the first 24 months, the project has advanced the development of light-responsive nanoswimmers capable of continous motion after removal of the illumination source. We designed and fabricated hybrid nanoswimmers that combine energy conversion and storage, enabling motion beyond direct light exposure.

Synthesis protocols were established for creating photoresponsive nanoswimmers and coupling them with energy-storing components through surface and interface engineering. We implemented characterization tools to assess motion under various conditions, with a focus on post-illumination propulsion and minimizing thermal artifacts.

Proof-of-concept applications, including selective oxidations and antimicrobial activity, confirmed the functional potential of these systems. We also introduced confined microenvironments and structured illumination platforms that support programmable control and collective dynamics, laying the groundwork for future autonomous and responsive materials.

Progressi oltre lo stato dell’arte e potenziale impatto previsto (incluso l’impatto socioeconomico e le implicazioni sociali più ampie del progetto fino ad ora)

The PhotoSwim project is exploring new strategies in light-driven micro/nanoroswimmers aimed at enabling motion beyond periods of direct illumination. By combining light-responsive and energy-storing components, the project investigates the possibility of more autonomous and energy-efficient systems. This approach represents a promising direction for designing the next-generation of photorechargeable systems, with potential implications for targeted environmental and therapeutical applications. Continued research is focused on improving the uniformity of the hybrid samples, validating long-term performance, and identifying future application pathways.